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石墨烯基铁氧化物磁性材料的制备及在水处理中的吸附性能
Synthesis and Adsorption of Graphene-Based Iron Oxide Magnetic Nanocomposites
石墨烯及其衍生物氧化石墨烯均有良好的物理和化学性质,其巨大的表面积和丰富的官能团使其成为良好的吸附材料。石墨烯基磁性材料则综合了石墨烯的吸附能力和磁性材料易分离的特性,是水处理过程中具有巨大应用潜力的吸附材料。本文在论述了石墨烯、氧化石墨烯及铁氧化物磁性材料对水体中的重金属离子、有机染料及含苯环的芳香类污染物的吸附富集性能的基础上,重点介绍了石墨烯基铁氧化物磁性材料的不同合成方法及复合材料在水处理中去除污染物的能力,探讨了复合材料在水处理中的应用前景。
The novel and unique physical and chemical properties of graphene and graphene oxide, in recent years have attracted more and more attention from scientific and professional communities. Owning to their high surface and abundant functional groups, it is possible for them to be the excellent adsorption materials in water treatment processes. However, they are not easy to separate from water matrix. To overcome the problem, so far, numerous graphene-based iron oxide magnetic nanocomposites have been successfully synthesized in various ways and showed desirable combination of adsorption and easy separation properties. Herein, we briefly introduce adsorption ability of graphene, graphene oxide and iron oxide magnetic materials for heavy metal ions, organic dyes and aromatic pollutants, and then highlight the synthesis methods and adsorption ability of graphene-based iron oxide magnetic nanocomposites. Especially, the potential applications in water treatment of these magnetic composites are discussed. Finally, a prospect for future research developments in this field is proposed. Contents
1 Introduction
2 Adsorption of graphene
3 Adsorption of grapheme oxide and modified graphene oxide
4 Adsorption of magnetic material——iron oxide
5 Synthesis and adsorption of graphene/Fe3O4 magnetic composite material
5.1 Synthesis of graphene/Fe3O4
5.2 Adsorption application of graphene/Fe3O4 in water treatment process
6 Conclusion and outlook
graphene
[1] Boehm H P, Clauss A, Fischer G O, Hofmann U. Z. Anorg. Allg. Chem., 1962, 316: 119-127
[2] Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A. Science, 2004, 306: 666-669
[3] Zhu Y, Murali S, Cai W, Li X, Suk J W, Potts J R, Ruoff R S. Adv. Mater., 2010, 22: 3906-3924
[4] Brodie B C. Philos. T. R. Soc. Lond., 1859, 149: 249-259
[5] Dreyer D R, Park S, Bielawski C W, Ruoff R S. Chem. Soc. Rev., 2010, 39: 228-240
[6] Green A A, Hersam M C. J. Phys. Chem. Lett., 2009, 1: 544-549
[7] Shao G L, Lu Y G, Wu F F, Yang C L, Zeng F L, Wu Q L. J. Mater. Sci., 2012, 47: 4400-4409
[8] Allen M J, Tung V C, Kaner R B. Chem. Rev., 2010, 110: 132-145
[9] Marcano D C, Kosynkin D V, Berlin J M, Sinitskii A, Sun Z, Slesarev A, Alemany L B, Lu W, Tour J M. ACS Nano, 2010, 4: 4806-4814
[10] Hong X, Zou K, DaSilva A M, Ahn C H, Zhu J. Solid State Commun., 2012, 152: 1365-1374
[11] Pei S, Cheng H M. Carbon, 2012, 50: 3210-3228
[12] Prezhdo O V, Kamat P V, Schatz G C. J. Phys. Chem. C, 2011, 115: 3195-3197
[13] Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958, 80: 1339-1339
[14] Huang X, Yin Z, Wu S, Qi X, He Q, Zhang Q, Yan Q, Boey F, Zhang H. Small, 2011, 7: 1876-1902
[15] Sun H, Yang Y, Huang Q. Integr. Ferroelectr., 2011, 128: 163-170
[16] Koo H Y, Lee H J, Go H A, Lee Y B, Bae T S, Kim J K, Choi W S. Chem-Eur. J., 2011, 17: 1214-1219
[17] Staudenmaier L. Ber. Dtsch. Chem. Ges., 1898, 31: 1481-1487
[18] Kim J, Cote L J, Kim F, Yuan W, Shull K R, Huang J. J. Am. Chem. Soc., 2010, 132: 8180-8186
[19] Buchsteiner A, Lerf A, Pieper J J. Phys. Chem. B, 2006, 110: 22328-22338
[20] Tung V C, Allen M J, Yang Y, Kaner R B. Nat. Nano, 2009, 4: 25-29
[21] 柏嵩(Bai S), 沈小平(Shen X P). 化学进展(Progress in Chemistry), 2010, 22: 2106-2118
[22] Qu J. J. Environ. Sci., 2008, 20: 1-13
[23] Babel S, Kurniawan T A. J. Hazard. Mater., 2003, 97: 219-243
[24] Stoller M D, Park S, Zhu Y, An J, Ruoff R S. Nano Lett., 2008, 8: 3498-3502
[25] Dong X, Cheng J, Li J, Wang Y. Anal. Chem., 2010, 82: 6208-6214
[26] Chen J, Zou J, Zeng J, Song X, Ji J, Wang Y, Ha J, Chen X. Anal. Chim. Acta, 2010, 678: 44-49
[27] Wu T, Cai X, Tan S, Li H, Liu J, Yang W. Chem. Eng. J., 2011, 173: 144-149
[28] Liu Q, Shi J, Zeng L, Wang T, Cai Y, Jiang G. J. Chromatogr. A, 2011, 1218: 197-204
[29] Zhang H, Lee H K. J. Chromatogr. A, 2011, 1218: 4509-4516
[30] Zhang H, Lee H K. Anal. Chim. Acta, 2012, 742(SI): 67-73. doi:10.1016/j. aca. 2012.03.016
[31] Wang P, Shi Q, Shi Y, Clark K K, Stucky G D, Keller A A. J. Am. Chem. Soc., 2009, 131: 182-188
[32] Wu Z S, Wang D W, Ren W, Zhao J, Zhou G, Li F, Cheng H M. Adv. Funct. Mater., 2010, 20: 3595-3602
[33] Li D, Muller M B, Gilje S, Kaner R B, Wallace G G. Nat. Nano, 2008, 3: 101-105
[34] Balapanuru J, Yang J X, Xiao S, Bao Q L, Jahan M, Polavarapu L, Wei J, Xu Q H, Loh K P. Angew. Chem. Int. Ed., 2010, 49: 6549-6553
[35] Dékány I, Krüger-Grasser R, Weiss A. Colloid Polym. Sci., 1998, 276: 570-576
[36] Seredych M, Bandosz T J. J. Phys. Chem. C, 2007, 111: 15596-15604
[37] Seredych M, Rossin J A, Bandosz T J. Carbon, 2011, 49: 4392-4402
[38] Slabaugh W H, Seiler B C. J. Phys. Chem., 1962, 66: 396-401
[39] Petit C, Bandosz T J. Adv. Funct. Mater., 2010, 20: 111-118
[40] Seredych M, Bandosz T J. J. Colloid Interf. Sci., 2008, 324: 25-35
[41] Aragon F, Cano Ruiz J, Macewan D M C. Nature, 1959, 183: 740-741
[42] Matsuo Y, Niwa T, Sugie Y. Carbon, 1999, 37: 897-901
[43] Matsuo Y, Miyabe T, Fukutsuka T, Sugie Y. Carbon, 2007, 45: 1005-1012
[44] Xu C, Wang X, Yang L, Wu Y. J. Solid State Chem., 2009, 182: 2486-2490
[45] Yang S T, Chang Y, Wang H, Liu G, Chen S, Wang Y, Liu Y, Cao A. J. Colloid Interf. Sci., 2010, 351: 122-127
[46] Yang S T, Chen S, Chang Y, Cao A, Liu Y, Wang H. J. Colloid Interf. Sci., 2011, 359: 24-29
[47] Zhao M, Liu P. Desalination, 2009, 249: 331-336
[48] Ramesha G K, Kumara A V, Muralidhara H B, Sampath S. J. Colloid Interf. Sci., 2011, 361: 270-277
[49] Sun L, Yu H W, Fugetsu B. J. Hazard. Mater., 2012, 203: 101-110
[50] Hartono T, Wang S, Ma Q, Zhu Z. J. Colloid Interf. Sci., 2009, 333: 114-119
[51] Gao W, Majumder M, Alemany L B, Narayanan T N, Ibarra M A, Pradhan B K, Ajayan P M. ACS Appl. Mater. Interfaces, 2011, 3: 1821-1826
[52] Zhao G, Jiang L, He Y, Li J, Dong H, Wang X, Hu W. Adv. Mater., 2011, 23: 3959-3963
[53] Zhao G, Li J, Wang X. Chem. Eng. J., 2011, 173: 185-190
[54] Luo Y B, Cheng J S, Ma Q, Feng Y Q, Li J H. Anal. Methods, 2011, 3: 92-98
[55] Hua M, Zhang S J, Pan B C, Zhang W M, Lv L, Zhang Q X. J. Hazard. Mater., 2012, 211: 317-331
[56] Hu J, Chen G, Lo I M C. Water Res., 2005, 39: 4528-4536
[57] Hu J, Lo I M C, Chen G. Sep. Purif. Technol., 2007, 56: 249-256
[58] Shen Y F, Tang J, Nie Z H, Wang Y D, Ren Y, Zuo L. Sep. Purif. Technol., 2009, 68: 312-319
[59] Khodabakhshi A, Amin M M, Mozaffari M. Iran. J. Environ. Healt., 2011, 8: 189-200
[60] Uheida A, Iglesias M, Fontàs C, Hidalgo M, Salvadó V, Zhang Y, Muhammed M. J. Colloid Interf. Sci., 2006, 301: 402-408
[61] Chen L, Xu Z, Dai H, Zhang S. J. Alloy. Compd., 2010, 497: 221-227
[62] Hu J, Shao D, Chen C, Sheng G, Li J, Wang X, Nagatsu M. J. Phys. Chem. B, 2010, 114: 6779-6785
[63] Yan J, Wei T, Qiao W, Shao B, Zhao Q, Zhang L, Fan Z. Electrochim. Acta, 2010, 55: 6973-6978
[64] Ai L H, Zhang C Y, Chen Z L. J. Hazard. Mater., 2011, 192: 1515-1524
[65] 于文广(Yu W G), 张同来(Zhang T L), 张建国(Zhang J G), 郭金玉(Guo J Y), 吴瑞凤(Wu R F). 化学进展(Progress in Chemistry), 2007, 19: 884-892
[66] 季俊红(Ji J H), 季生福(Ji F S), 杨伟(Yang W), 李成岳(Li C Y). 化学进展(Progress in Chemistry), 2010, 22: 1566-1574
[67] He F, Fan J, Ma D, Zhang L, Leung C, Chan H L. Carbon, 2010, 48: 3139-3144
[68] 张燚(Zhang Y), 陈彪(Chen B), 杨祖培(Yang Z P), 张智军(Zhang Z J). 物理化学学报(Acta Physico-Chimica Sinica), 2011, 27: 1261-1266
[69] Zhang Y, Chen B, Zhang L, Huang J, Chen F, Yang Z, Yao J, Zhang Z. Nanoscale, 2011, 3: 1446-1450
[70] Li Y, Chu J, Qi J, Li X. Appl. Surf. Sci., 2011, 257: 6059-6062
[71] Xie G Q, Xi P X, Liu H Y, Chen F J, Huang L, Shi Y J, Hou F P, Zeng Z Z, Shao C W, Wang J. J. Mater. Chem., 2012, 22: 1033-1039
[72] Zhan Y, Yang X, Meng F, Wei J, Zhao R, Liu X. J. Colloid Interf. Sci., 2011, 363: 98-104
[73] Zhan Y, Meng F, Yang X, Liu X. Colloid Surface A, 2011, 390: 112-119
[74] Yang X, Zhang X, Ma Y, Huang Y, Wang Y, Chen Y. J. Mater. Chem., 2009, 19: 2710-2714
[75] Kassaee M Z, Motamedi E, Majdi M. Chem. Eng. J., 2011, 172: 540-549
[76] Wu Q, Zhao G, Feng C, Wang C, Wang Z. J. Chromatogr. A, 2011, 1218: 7936-7942
[77] He H, Gao C. ACS Appl. Mater. Interfaces, 2010, 2: 3201-3210
[78] Sun H M, Cao L Y, Lu L H. Nano Res., 2011, 4: 550-562
[79] Su J, Cao M, Ren L, Hu C. J. Phys. Chem. C, 2011, 115: 14469-14477
[80] Cong H P, He J J, Lu Y, Yu S H. Small, 2010, 6: 169-173
[81] Shen J, Hu Y, Shi M, Li N, Ma H, Ye M. J. Phys. Chem. C, 2010, 114: 1498-1503
[82] Zhu J H, Wei S Y, Gu H B, Rapole S B, Wang Q, Luo Z P, Haldolaarachchige N, Young D P, Guo Z H. Environ. Sci. Technol., 2012, 46: 977-985
[83] Zhang M, Lei D, Yin X, Chen L, Li Q, Wang Y, Wang T. J. Mater. Chem., 2010, 20: 5538-5543
[84] Chandra V, Park J, Chun Y, Lee J W, Hwang I C, Kim K S. ACS Nano, 2010, 4: 3979-3986
[85] Liang J, Xu Y, Sui D, Zhang L, Huang Y, Ma Y, Li F, Chen Y. J. Phys. Chem. C, 2010, 114: 17465-17471
[86] Wang H, Robinson J T, Li X, Dai H. J. Am. Chem. Soc., 2009, 131: 9910-9911
[87] Dubin S, Gilje S, Wang K, Tung V C, Cha K, Hall A S, Farrar J, Varshneya R, Yang Y, Kaner R B. ACS Nano, 2010, 4: 3845-3852
[88] Deng H, Li X, Peng Q, Wang X, Chen J, Li Y. Angew. Chem. Ger. Ed., 2005, 117: 2842-2845
[89] 付佳(Fu J). 西安建筑科技大学硕士论文(Master Dissertation of Xi'an University of Architecture and Technology), 2007
[90] Geng Z G, Lin Y, Yu X X, Shen Q H, Ma L, Li Z Y, Pan N, Wang X P. J. Mater. Chem., 2012, 22: 3527-3535
[91] Luo Y B, Shi Z G, Gao Q A, Feng Y Q. J. Chromatogr. A, 2011, 1218: 1353-1358
[92] Zhao G Y, Song S J, Wang C, Wu Q H, Wang Z. Anal. Chim. Acta, 2011, 708: 155-159
[93] Wu Q, Zhao G, Feng C, Wang C, Wang Z. J. Chromatogr. A, 2011, 1218: 7936-7942
[94] Wu Q, Liu M, Ma X, Wang W, Wang C, Zang X, Wang Z. Microchimica Acta, 2012, 177: 23-30
[95] Yao Y J, Miao S D, Liu S Z, Ma L P, Sun H Q, Wang S B. Chem. Eng. J., 2012, 184: 326-332
[96] Wang C, Feng C, Gao Y, Ma X, Wu Q, Wang Z. Chem. Eng. J., 2011, 173: 92-97
[97] Afkhami A, Moosavi R. J. Hazard. Mater., 2010, 174: 398-403
[98] Wang W L, Xu J, Sun Z, Zhang X, Lu Y, Lai Y H. Macromolecules, 2006, 39: 7277-7285
[99] Qi X, Pu K Y, Zhou X, Li H, Liu B, Boey F, Huang W, Zhang H. Small, 2010, 6: 663-669
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