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表面增强拉曼光谱在定量分析中的应用
Quantitative Analysis of Surface-Enhanced Raman Spectroscopy
表面增强拉曼光谱(SERS)作为一种快速、灵敏的检测方法, 在很多领域有着广泛的应用前景。随着SERS技术的发展, SERS研究工作不再限于物质的定性检测, 更多地定位于样品中一种或多种成分的定量分析。本文详细介绍了三类SERS增强基底的制备, 包括传统固相基底、金属胶体溶液和基于纳米制造的等离子体共振纳米结构以及它们在定量分析中的优缺点;从分子取向、激发波长、内标(internal standard)和数据分析4个方面论述如何提高SERS定量分析时的灵敏度和可靠性。本文综述了SERS在定量分析中的应用, 简要分析其存在的问题并对其未来的发展进行展望。
As a promising analytical technique in recent years, surface-enhanced Raman spectroscopy (SERS) has received extensive attention due to its low limit of detection, high sensitivity and high specificity. Despite its tremendous potential, SERS was not widely applied in quantitative analysis of chemical and biological samples in the past years. However, the explosive development of nanotechnology and nano-fabrication has assisted the development of SERS as a quantitative analysis tool. As the enhancement of Raman scattering strongly depends on nanoscale surface morphology of the enhancing surface and can be easily influenced by other factors in an experiment, it is still a challenge to obtain reliable results comparable to those obtained from state-of-the-art analysis methods. The fabrication of three kinds of enhancing media including traditional solid substrates, colloidal nanoparticles and plasmonic nanostructures based on nano-fabrication and their respective advantages and drawbacks for quantitative SERS detection are summerized in this review. Furthermore, how to improve the sensitivity and reliability is investigated in aspects of molecular orientation, excitation wavelength, internal standard and data analysis. Meanwhile, several successful cases of quantitative SERS detection are presented. Finally, applications and prospects of its future researches are proposed. Contents
1 Introduction
2 Enhancing media
2.1 Preparation of enhancing media
2.2 Surface modification of enhancing media
2.3 Improve the sensitivity and reliability
3 Experimental factors
3.1 Molecular orientation
3.2 Excitation wavelength
3.3 Internal standard
3.4 Data analyzing
4 Examples of quantitative SERS
4.1 Direct detection
4.2 Indirect detection
5 Conclusions and outlook
surface-enhanced Raman spectroscopy
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