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全钒氧化还原液流电池电解液
Electrolyte for All-Vanadium Redox Flow Battery
近年来,全钒氧化还原液流电池(VRFB)作为一种新型的储能电池备受关注。作为VRFB的核心材料,电解液的制备及优化一直都是研究的热点。高浓度和高稳定性电解液的制备是钒电池的关键技术之一。电解液性能的提高有助于加速VRFB的商业化进程。本文综述了VRFB电解液的研究进展,重点介绍了电解液的制备方法和影响电解液稳定性的因素,简述了电解液中钒离子浓度的分析方法和钒离子的存在形式,最后对电解液的进一步研究和应用前景进行了展望。
In recent years, all-vanadium redox flow battery (VRFB) has been paid much attention as a new type of battery for energy storage. Researchers have been focusing much on production and optimization of vanadium electrolyte solutions used for the key materials in VRFB. Production of high concentration and stability electrolyte is one of key technologies referring to VRFB. Commercialization process can be accelerated with the performance improvement of vanadium electrolyte solutions. The research progress in VRFB electrolyte solutions is summarized in this paper. The preparation methods and influence factors of stability on vanadium electrolyte solutions are mainly introduced, and concentration analysis methods and existence forms of vanadium ions in vanadium electrolyte solutions are also discussed. Moreover, further research and prospects on vanadium electrolyte solutions are presented. Contents
1 Introduction
2 Production of vanadium electrolyte solutions
2.1 Chemical synthesis methods
2.2 Electrolytic synthesis methods
3 Concentration analysis of vanadium electrolyte solutions
4 Research on stability of vanadium ions in vanadium electrolyte solutions
4.1 Supporting electrolyte solutions
4.2 Temperature
4.3 Additives
5 Research on existence forms of vanadium ions in vanadium electrolyte solutions
6 Outlook
全钒氧化还原液流电池
all-vanadium redox flow battery
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