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纳米粒子参与的鲁米诺化学发光及其分析应用
Nanoparticle-Involved Luminol Chemiluminescence and Its Analytical Applications
化学发光的基础理论和分析应用已经有多年的研究历史,但化学发光的研究多局限于分子和离子水平。纳米粒子由于其量子尺寸效应、表面能高以及比表面积大,因而常作为氧化还原反应的催化剂来放大反应信号。近年来,纳米粒子直接或者间接参与的化学发光拓展了化学发光的理论和应用研究范畴,己发现纳米粒子能够作为催化剂、还原剂、微尺度反应平台和能量接受体等参与化学发光反应。本文详细介绍了纳米粒子参与的鲁米诺化学发光体系,并重点评述了部分纳米粒子参与的鲁米诺化学发光与高效液相色谱、毛细管电泳等分离技术联用实例。纳米粒子作为一种新型化学发光响应单元,可提高鲁米诺化学发光反应的效率,对开发新的鲁米诺化学发光反应体系具有重要意义,已有关于金、铂、银、合金、半导体、磁性等纳米粒子参与的鲁米诺化学发光报道。除应用于环境、药品及食品等分析领域外,其在免疫分析方面也表现出巨大的应用潜力。最后,提出了纳米粒子参与鲁米诺化学发光体系研究目前存在的问题,并对其未来的发展方向进行了展望。
The theory and applications of chemiluminescence (CL) have been investigated for many years, but the study of CL was limited to the molecular and ion systems. Nanoparticles (NPs) have quantum size effects, high surface energy, and large surface area, which dramatically change their density states and the spatial scale of their electronic motion. The redox reactions can be strongly catalyzed by NPs, which is promising for the signal amplification of CL. In the recent years, NP-involved CL became one of the most attractive developments, in which NPs can participate in CL reactions as catalyst,reductant, nanosized reaction platform, and energy acceptor. In this review, the NP-involved luminol CL system and its coupling with separation technology such as high performance liquid chromatography (HPLC), capillary electrophoresis (CE) are described. NPs as a novel response unit of CL system are very important for increasing the luminescent efficiency of luminol reaction and developing new luminol CL system. Different kinds of NPs have been reported to participate luminol CL reaction, including gold (AuNPs), platinum (PtNPs), silver (AgNPs), bimetallic NPs, semiconductor NPs, and magnetic (MNPs). The NP-involved luminol CL is not only widely applied in the environmental, pharmaceutical and food analysis, but also shows great potential in immunoassay. Furthermore, some critical challenges and their possible solutions in the study of NP-involved luminol CL are briefly discussed. Contents
1 Introduction
2 AuNPs-catalyzed luminol CL
2.1 AuNPs-catalyzed luminol-H2O2 CL
2.2 AuNPs-catalyzed luminol-ferricyanide CL
2.3 AuNPs-catalyzed luminol-periodate CL
2.4 AuNPs-catalyzed luminol-AgNO3 CL
2.5 AuNPs-catalyzed other luminol CL
3 PtNPs involved luminol CL
4 AgNPs involved luminol CL
5 Other nanoparticles-involved luminol CL
5.1 Bimetallic nanoparticles-involved luminol CL
5.2 Semiconductor nanoparticles-involved luminol CL
5.3 Magnetic nanoparticles-involved luminol CL
6 Separation technology coupling with nanoparticles-involved luminol CL detection
6.1 Coupling with HPLC
6.2 Coupling with CE
7 Conclusion and outlook
纳米粒子
nanoparticles
[1] DE Dios A S, Diaz-Garcia M E. Anal. Chim. Acta, 2010, 666: 1-22
[2] Lines M G. J. Alloys Compd., 2008, 449: 242-245
[3] Stone V, Nowack B, Baun A, van den Brink N, Kammer F, Dusinska M, Handy R, Hankin S, Hassellöv M, Joner E, Fernandes T F. Sci. Total Environ., 2010, 408: 1745-1754
[4] Wardencki W, Zygmunt B. Anal. Chim. Acta, 1991, 255: 1-13
[5] Mendenhall G D. Angew. Chem. Int. Ed., 1990, 29: 362-373
[6] Beck S, Koster H. Anal. Chem., 1990, 62: 2258-2270
[7] Steele R W. Clin. Infect. Dis., 1991, 13: 918-925
[8] Wang X, Lin J M, Liu M L, Cheng X L. Trends Anal. Chem., 2009, 28: 75-87
[9] Lu C, Qu F, Lin J M, Yamada M. Anal. Chim. Acta, 2002, 474: 107-114
[10] Lu C, Lin J M. Catal. Today, 2004, 90: 343-347
[11] Liang S X, Zhao L X, Zhang B T, Lin J M. J. Phys. Chem. A, 2008, 112: 618-623
[12] Marquette C A, Blum L J. Anal. Bioanal. Chem., 2006, 385: 546-554
[13] Yamaguchi M, Yoshida H, Nohta H. J. Chromatogr. A, 2002, 950: 1-19
[14] Isacsson U, Wettermark G. Anal. Chim. Acta, 1974, 68: 339-362
[15] White E H, Bursey M M. J. Am. Chem. Soc., 1964, 86: 941-942
[16] Lin J M, Yamada M. Anal. Chem., 2000, 72: 1148-1155
[17] Lu C, Song G, Lin J M. Trends Anal. Chem., 2006, 25: 985-995
[18] Lin J M, Yamada M. Trends Anal. Chem., 2003, 22: 99-107
[19] Giokas D L, Vlessidis A G, Tsogas G Z, Evmiridis N P. Trends Anal. Chem., 2010, 29: 1113-1126
[20] Zhang Z F, Cui H, Lai C Z, Liu L J. Anal. Chem., 2005, 77: 3324-3329
[21] Wang L, Yang P, Li Y X, Chen H, Li M, Luo F. Talanta, 2007, 72: 1066-1072
[22] Lan D, Li B, Zhang Z J. Biosens. Bioelectron., 2008, 24: 934-938
[23] Li Q Q, Liu F, Lu C, Lin J M. J. Phys. Chem. C, 2011, 115: 10964-10970
[24] Chen Q S, Bai S L, Lu C. Talanta, 2012, 89: 142-148
[25] Lu C, Li Q Q, Chen S, Zhao L, Zheng Z. Talanta, 2011, 85: 476-481
[26] Yang X Y, GuoY S, Bi S, Zhang S S. Biosens. Bioelectron., 2009, 24: 2707-2711
[27] Yang X Y, Guo Y S, Wang A G. Anal. Chim. Acta, 2010, 666: 91-96
[28] Li Q Q, Zhang L J, Li J, Lu C. Trends Anal. Chem., 2011, 30: 401-413
[29] Duan C F, Cui H, Zhang Z F, Liu B, Guo J Z, Wang W. J. Phys. Chem. C, 2007, 111: 4561-4566
[30] Li S F, Li X Z, Xu J, Wei X. Talanta, 2008, 75: 32-37
[31] Zisimopoulos E G, Tsogas G Z, Giokas D L, Kapakoglou N I, Vlessidis A G. Talanta, 2009, 79: 893-899
[32] Koutsoulis N P, Giokas D L, Vlessidis A G, Tsogas G Z. Anal. Chim. Acta, 2010, 669: 45-52
[33] Cao Z J, Lau C, Lu J Z. Analyst, 2004, 129: 1262-1266
[34] Cui H, Guo J Z, Li N, Liu L J. J. Phys. Chem. C, 2008, 112: 11319-11323
[35] Duan C F, Yu Y Q, Cui H. Analyst, 2008, 133: 1250-1255
[36] Boro R C, Kaushal J, Nangia Y, Wangoo N, Bhasinc A, Raman Suri C. Analyst, 2011, 136: 2125-2130
[37] Du J X, Quan J, WangY D. Talanta, 2012, 90: 117-122
[38] Safavi A, Absalan G, Bamdad F. Anal. Chim. Acta, 2008, 610: 243-248
[39] Xu S L, Cui H. Luminescence, 2007, 22: 77-87
[40] Niazov T, Shlyahovsky B, Willner I. J. Am. Chem. Soc., 2007, 129: 6374-6375
[41] Gorman B A, Francis P S, Dunstan D E, Barnett N W. Chem. Commun., 2007, 395-397
[42] Guo J Z, Cui H, Zhou W, Wang W. J. Photochem. Photobiol., A, 2008, 193: 89-96
[43] Chen H, Gao F, He R, Cui D X. J. Colloid Interface Sci., 2007, 315: 158-163
[44] Li Y H, Li Y K, Yang Y. Appl. Spectrosc., 2011, 65: 376-381
[45] Li N, Gu J, Cui H. J. Photochem. Photobiol. A, 2010, 215: 185-190
[46] Liu W, Kou J, Jiang X L, Zhang Z J, Qi H L. J. Lumin., 2012, 132: 1048-1054
[47] 寇娟(Kou J), 刘伟(Liu W), 王瑞平(Wang D P), 章竹君(Zhang Z J). 分析试验室(Chin. J. Anal. Lab.), 2012, 31: 1-5
[48] Liu C, Li B X. Anal. Bioanal. Chem., 2011, 401: 229-235
[49] Li S F, Sun H M, Wang D, Hong J G, Tao S J, Yu H Y, Wang X H, Wei X W. Luminescence, 2012, 27: 211-216
[50] Chen X L, Wang C, Tan X M, Wang J. Anal. Chim. Acta, 2011, 689: 92-96
[51] Haghighi B, Bozorgzadeh S. Microchem. J., 2010, 95: 192-197
[52] Lee I, Han SW, Kim K. Chem. Commun., 2001, 1782-1783
[53] Ibanez F J, Zamborini F P. ACS Nano, 2008, 2: 1543-1552
[54] Li S F, Zhang X M, Yao Z J, Yu R, Huang F, Wei X W. J. Phys. Chem. C, 2009, 113: 15586-15596
[55] Li N, Wang W, Tian D Y, Cui H. Chem. Commun., 2010, 1520-1522
[56] Li S F, Tao S J, Wang F F, Hong J G, Wei X W. Microchim. Acta, 2010, 169: 73-78
[57] Huang X Y, Li L, Qian H F, Dong C, Ren J. Angew. Chem. Int. Ed., 2006, 45: 5140-5143
[58] Li S F, Zhang X M, Du W X, Ni Y H, Wei X W. J. Phys. Chem. C, 2009, 113: 1046-1051
[59] Wu J, Fu X C, Xie C G, Yang M, Fang W, Gao S. Sens. Actuators B, 2011, 160: 511-516
[60] Chen W, Hong L, Liu A L, Liu J Q, Lin X H, Xia X H. Talanta, 2012, 99: 643-648
[61] He S H, Shi W B, Zhang X D, Li J, Huang Y. Talanta, 2010, 82: 377-383
[62] Shi W B, Wang H, Huang Y M. Luminescence, 2011, 26: 547-552
[63] Rezaei B, Ensafi A A, Zarei L, Kameli P. Luminescence, 2012, 27: 390-397
[64] Li N, Guo J Z, Yu Y Q, Yu Y, Cui H, Mao L, Lin Y. Anal. Chim. Acta, 2009, 645: 48-55
[65] Li Q Q, Shang F, Lu C, Zheng Z, Lin J M. J. Chromatogr. A, 2011, 1218: 9064-9070
[66] Zhang Q L, Wu L, Lv C, Zhang X Y. J. Chromatogr. A, 2012, 1242: 84-91
[67] Zhao S L, Niu T X, Song Y R, Liu Y M. Electrophoresis, 2009, 30: 1059-1065
[68] Zhao S L, Lan X H, Liu Y M. Electrophoresis, 2009, 30: 2676-2680
[69] Liu Q C, Wu J Q, Tian J, Zhang C L, Gao J J, Latep N, Ge Y, Qin W D. Talanta, 2012, 97: 193-198
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