1,8-位修饰杂芴类有机光电功能材料的合成与应用

曹锦珠; 王志祥; 陈润锋; 李欢欢; 郑超; 黄维

doi:10.7536/PC121241

化学进展 ›› 2013, Vol. 25 ›› Issue (08) :1350-1361 DOI: 10.7536/PC121241

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1,8-位修饰杂芴类有机光电功能材料的合成与应用

^1,2

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Synthesis and Applications of 1,8-Functionalized Heterofluorenes for Organic Electronics

Cao Jinzhu¹, Wang Zhixiang¹, Chen Runfeng*^1,2, Li Huanhuan¹, Zheng Chao¹, Huang Wei*²

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摘要

以氧、硫、硅、氮、磷等杂原子取代芴中sp³杂化的碳原子所形成的杂芴,不仅可以通过杂原子和π共轭体系间的相互作用有效地调控材料的电子结构,而且可以影响芴不同位置的修饰,从而得到了广泛关注。本文详细分析了1,8-位修饰杂芴的分子结构特点和光电特性,根据不同的杂原子分类论述了相关材料的合成方法和原理,综述了1,8-位修饰杂芴类材料在磷光主体材料、电致发光材料、太阳能电池材料以及有机配体材料等方面的应用进展,展望了其在有机光电材料方面的应用前景和发展趋势。

Abstract

Heterofluorenes, achieved by substituting the sp³-hybridized carbon of fluorene with oxygen, sulfur, silicon, nitrogen, phosphor etc., are a series of very interesting optoelectronic materials. They have not only many highly effective ways to modify the electronic structures and properties through the particular interactions between the heteroatom and the π-conjugated system, but also show different modification properties at different substitution positions due to the influence of the heteroatoms. 1,8-Functionalization inspires new properties from widely used materials although the synthesis is always difficult. Owing to the wide spread progress of heterofluorenes and the 1,8-functionalization strategy, 1,8-functionalized heterofluorenes have received increasing attention in organic optical and electronic materials and devices recently. Herein, we summarized the basic principles of the molecular design, material synthesis, structure-property relations, and optoelectronic device applications of 1,8-functionalized heterofluorenes. The different synthetic methods of various 1,8-functionalized heterofluorenes are reviewed and presented according to different effects of different heteroatoms. Besides, the applications of 1,8-functionalized heterofluorenes as host materials for phosphorescent organic light emitting diodes, as electroluminescent materials for organic light emitting diodes, as photovoltaic materials for solar cells, and as functional ligands for organic metals are discussed in detail. Finally, the existing key problems and the future development of 1,8-functionalized heterofluorenes are also outlined and suggested. Contents
1 Introduction
2 Synthesis of 1,8-functionalized heterofluorenes
2.1 Direct synthetic methods
2.2 Indirect synthetic methods
3 Applications of 1,8-functionalized heterofluorenes
3.1 Organic electroluminescent materials
3.2 Photovoltaic materials
3.3 Ligands
4 Conclusion and outlook

关键词

芴 / 杂芴 / 1,8-位修饰 / 合成 / 有机光电功能材料

Key words

fluorene / heterofluorene / 1,8-functionalization / synthesis / organic optoelectronic materials

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曹锦珠, 王志祥, 陈润锋, 李欢欢, 郑超, 黄维. 1,8-位修饰杂芴类有机光电功能材料的合成与应用[J]. 化学进展, 2013, 25(08): 1350-1361 DOI:10.7536/PC121241

Cao Jinzhu, Wang Zhixiang, Chen Runfeng, Li Huanhuan, Zheng Chao, Huang Wei. Synthesis and Applications of 1,8-Functionalized Heterofluorenes for Organic Electronics[J]. Progress in Chemistry, 2013, 25(08): 1350-1361 DOI:10.7536/PC121241

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Received	Published	Revised
2012-12-01	2013-08-25	2013-03-01
Online Date
2013-06-13

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