核壳结构纳米材料的创制及在催化化学中的应用

李雷; 李彦兴; 姚瑶; 姚良宏; 季伟捷; 区泽棠

doi:10.7536/PC121251

化学进展 ›› 2013, Vol. 25 ›› Issue (10) :1681-1690 DOI: 10.7536/PC121251

综述与评论

扫码查看或转发全文

核壳结构纳米材料的创制及在催化化学中的应用

^1,2

^1,3

作者信息 +

Progress and Prospective in Fabrication and Application of Core-Shell Structured Nanomaterials in Catalytic Chemistry

Li Lei^1,2, Li Yanxing^1,3, Yao Yao¹, Yao Lianghong^1,3, Ji Weijie¹, Au Chak-Tong³

Author information +

文章历史 +

摘要

核壳结构纳米材料因其独特的结构及其多功能性,引起人们的广泛关注,具有广阔的应用前景。本文综述了近年来核壳结构纳米材料的创制,包括金属@金属,金属@氧化物,金属@碳材料,金属@高聚物,金属@分子筛等及其在不同催化过程中的催化行为,强调了特定的组装结构和表面电子性质对催化性能及稳定性的影响。依据具体实例对具有yolk/shell型核壳结构纳米反应器在催化反应中的作用与功能进行了评述。本文最后对核壳结构纳米材料在可控合成以及不同催化过程中的可能应用进行了展望与总结。

Abstract

Owning to their unique structures and multi-functionalities, the core-shell structured nanomaterials are receiving great attention in recent years, and being widely used in various catalytic processes. The purpose of this review is to highlight the recent achievements in fabrication and application of core-shell nanostructures (i.e., metal core@metal shell, metal core@oxide shell, metal core@carbon shell, metal core@polymer, and metal core@zeolite shell) in catalytic chemistry. The influences of assembled structures and resulting electronic properties on catalytic performance as well as catalyst durability are discussed. In view of the new research findings, the concept of nanoreactor with the yolk/shell structure and its role in catalytic reactions are outlined. At the end of the article, a summary and outlook of these novel materials with respect to controlled synthesis and potential applications are provided.

Contents
1 Introduction
2 Progress in fabrication and application of core-shell structured nanomaterials in catalysis
2.1 Metal core@metal shell nanomaterials
2.2 Metal core@oxide shell nanomaterials
2.3 Metal core@carbon shell nanomaterials
2.4 Metal core@polymer shell nanomaterials
2.5 Metal core@zeolite shell nanomaterials
2.6 Yolk/shell structure nanomaterials

关键词

核壳结构 / 纳米材料 / 催化化学

Key words

core-shell structure / nanomaterials / catalytic chemistry

引用本文

引用格式 ▾

李雷, 李彦兴, 姚瑶, 姚良宏, 季伟捷, 区泽棠. 核壳结构纳米材料的创制及在催化化学中的应用[J]. 化学进展, 2013, 25(10): 1681-1690 DOI:10.7536/PC121251

Li Lei, Li Yanxing, Yao Yao, Yao Lianghong, Ji Weijie, Au Chak-Tong. Progress and Prospective in Fabrication and Application of Core-Shell Structured Nanomaterials in Catalytic Chemistry[J]. Progress in Chemistry, 2013, 25(10): 1681-1690 DOI:10.7536/PC121251

登录浏览全文

4963

注册一个新账户忘记密码

参考文献

原文顺序 | 出版日期 | 本文引用

[1] Bell A T. Science, 2003, 299: 1688—1691
[2] 汪洋(Wang Y), 颜志鹏(Yan Z P), 陈丰秋(Chen F Q), 詹晓力(Zhan X L). 化学进展(Progress in Chemistry), 2008, 20: 1263—1269
[3] Reiss P, Protiere M, Li L. Small, 2009, 5: 154—168
[4] Guerrero-Martínez A, Pérez-Juste J, Liz-Marzán L. Adv. Mater., 2010, 22: 1182—1195
[5] Burns A, Ow H, Wiesner U. Chem. Soc. Rev., 2006, 35: 1028—1042
[6] Chi F, Guo Y N, Liu J, Liu Y, Huo Q. J. Phys. Chem. C, 2010, 114: 2519—2523
[7] Jun Y W, Choi J S, Cheon J. Chem. Commun., 2007, 12: 1203—1214
[8] Zhou S, Varughese B, Eichhorn B, Jackson G, McIlwrath K. Angew. Chem. Int. Ed., 2005, 44: 4539—4543
[9] Alayoglu S, Eichhorn B. J. Am. Chem. Soc., 2008, 130: 17479—17486
[10] Alayoglu S, Nilekar A, Mavrikakis M, Eichhorn. B. Nat. Mater., 2008, 7: 333—338
[11] Bagot P A J, Marquis E A, Smith G D W, Tsang S C E. Nat. Nanotechnol., 2011, 6: 302—307
[12] Zeng J, Yang J, Lee J, Zhou W. J. Phys. Chem. B, 2006, 110: 24606—24611
[13] Huang R, Wen Y H, Zhu Z Z, Sun S G. J. Phys. Chem. C, 2012, 15: 8664—8671
[14] Zhang X, Yan J, Han S, Shioyama H, Xu Q. J. Am. Chem. Soc., 2009, 131: 2778—2779
[15] Chen Y, Yang F, Dai Y, Wang W, Chen S. J. Phys. Chem. C, 2008, 112: 1645—1649
[16] Jun C, Park Y, Yeon Y, Choi J, Lee W, Ko S, Cheon J. Chem. Commun., 2006, 1619—1621
[17] Pachón L, Thathagar M, Hartl F, Rothenberg G. Phys. Chem. Chem. Phys., 2006, 8: 151—157
[18] Massard R, Uzio D, Thomazeau C, Pichon C, Rousset J, Bertolini J. J. Catal., 2007, 245 : 133—143
[19] Sárkány A, Geszti O, Sáfrán G. Appl. Catal. A, 2008, 350: 157—163
[20] Marx S, Baiker A. J. Phys. Chem. C, 2009, 113: 6191—6201
[21] Zhang W, Li L, Du Y, Wang X, Yang P. Catal. Lett., 2009, 127: 429—436
[22] Joo S H, Park J Y, Tsung C K, Yamada Y, Yang P D, Somorjai G A. Nat. Mater., 2009, 8: 126—131
[23] Yu K M K, Yeung C M Y, Thompsett D, Tsang S C. J. Phys. Chem. B, 2003, 107: 4515—4526
[24] Park J, Forman A, Tang W, Cheng J, Hu Y, Lin H, McFarland E. Small, 2008, 4: 1694—1697
[25] Forman A J, Park J N, Tang W, Hu Y S, Stucky G D, McFarland E W. ChemCatChem., 2010, 2: 1318—1324
[26] Takenaka S, Orita Y, Umebayashi H, Matsune H, Kishida M. Appl. Catal. A, 2008, 351: 189—194
[27] Takenaka S, Umebayashi H, Tanabe E, Matsune H, Kishida M. J. Catal., 2007, 245: 392—400
[28] Yeung C M Y, Tsang S C, Catal. Lett., 2009, 128: 349—355
[29] Yeung C M Y, Tsang S C, J. Phys. Chem. C, 2009, 113: 6074—6087
[30] Cargnello M, Wieder N L, Montini T, Gorte R J, Fornasiero P. J. Am. Chem. Soc., 2010, 132: 1402—1409
[31] Zhang J, Li L, Huang X, Li G. J. Mater. Chem., 2012, 22: 10480—10487
[32] Zhang N, Fu X, Xu Y J, J. Mater. Chem., 2011, 21: 8152—8158
[33] Lu J, Fu B, Kung M C, Xiao G, Elam J W, Kung H H, Stair P C. Science, 2012, 335: 1205—1208
[34] Montini T, Condo A, Hickey N, Lovey F, De Rogatis L, Fornasiero P, Graziani M. Appl. Catal. B: Environ., 2007, 73: 84—97
[35] D'addato S, Grillo V, Altieri S, Frabboni S, Rossi F, Valeri S. J. Phys. Chem. C, 2011, 115: 14044—14049
[36] Bian Z, Zhu J, Cao F, Lu Y, Li H. Chem. Commun., 2009, 3789—3791
[37] Nair A S, Pradeep T, MacLaren I, J. Mater. Chem., 2004, 14: 857—862
[38] Oldfield G, Ung T, Mulvaney P. Adv. Mater., 2000, 12: 1519—1522
[39] Deng Y, Qi D, Deng C, Zhang X, Zhao D. J. Am. Chem. Soc., 2008, 130: 28—29
[40] Yang H, Chong Y, Li X, Ge H, Fan W, Wang J. J. Mater. Chem., 2012, 22: 9069—9076
[41] Barmatova M, Ivanchikova I, Kholdeeva O, Shmakov A, Zaikovskii V, Mel'gunov M. Catal. Lett., 2009, 127: 75—82
[42] Ng Y H, Ikeda S, Harada T, Higashida S, Sakata T, Mori H, Matsumura M. Adv. Mater., 2007, 19: 597—601
[43] Ikeda S, Ishino S, Harada T, Okamoto N, Sakata T, Mori H, Kuwabata S, Torimoto T, Matsumura M. Angew. Chem. Int. Ed., 2006, 45: 7063—7066
[44] Ng Y H, Ikeda S, Morita Y, Harada T, Ikeue K, Matsumura M. J. Phys. Chem. C, 2009, 113: 12799—12805
[45] Ng Y H, Ikeda S, Harada T, Sakata T, Mori H, Takaoka A, Matsumura M. Langmuir, 2008, 24: 6307—6312
[46] Harada T, Ikeda S, Ng Y H, Sakata T, Mori H, Matsumura M. Adv. Funct. Mater., 2008, 18: 2190—2196
[47] Song C, Du J, Zhao J, Feng S, Du G, Zhu Z. Chem. Mater., 2009, 21: 1524—1530
[48] Yu G, Sun B, Pei Y, Xie S, Yan S, Qiao M, Fan K, Zhang X, Zong B. J. Am. Chem. Soc., 2010, 132: 935—937
[49] 唐新德 (Tang X D), 张其震 (Zhang Q Z). 化学进展 (Progress in Chemistry), 2003, 15: 129—134
[50] Du Y, Zhang W, Wang X, Yang P. Catal. Lett., 2006, 107: 177—183
[51] Yang P, Zhang W, Du Y, Wang X. J. Mol. Catal. A: Chem., 2006, 260: 4—10
[52] Sun L, Ca D, Cox J. J. Solid. State. Electrochem., 2005, 9: 816—822
[53] Huang W, Kuhn J N, Tsung C K, Zhang Y, Habas S E, Yang P, Somorjai G A. Nano. Lett., 2008, 8: 2027—2034
[54] Toshima N. Macromol. Symp., 2008, 270: 27—39
[55] Xuan S, Wang Y, Yu J, Leung K. Langmuir, 2009, 25: 11835—11843
[56] Vande C R, Alfers A, Meeldijk J, Martinez-Viviente E, Pregosin P, Gebbink R, van Koten G. J. Am. Chem. Soc., 2006, 128: 12700—12713
[57] Graeser M, Pippel E, Greiner A, Wendorff J. Macromolecules, 2007, 40: 6032—6039
[58] Lu Y, Mei Y, Drechsler M, Ballauff M. Angew. Chem. Int. Ed., 2006, 45: 813—816
[59] Mei Y, Lu Y, Polzer F, Ballauff M, Drechsler M. Chem. Mater., 2007, 19: 1062—1069
[60] Lu Y, Mei Y, Ballauff M, Drechsler M. J. Phys. Chem. B, 2006, 110: 3930—3937
[61] Lu Y, Proch S, Schrinner M, Drechsler M, Kempe R, Ballauff M. J. Mater. Chem., 2009, 19: 3955—3961
[62] Zhang J, Zhang W, Wang Y, Zhang M. Adv. Synth. Catal., 2008, 350: 2065—2076
[63] Wen F, Zhang W, Wei G, Wang Y, Zhang J, Zhang M, Shi L. Chem. Mater., 2008, 20: 2144—2150
[64] Zheng P, Zhang W. J. Catal., 2007, 250: 324—330
[65] Wei G, Zhang W, Wen F, Wang Y, Zhang M. J. Phys. Chem. C, 2008, 112: 10827—10832
[66] Miyamoto M, Kamei T, Nishiyama N, Egashira Y, Ueyama K. Adv. Mater., 2005, 17: 1985—1988
[67] Nishiyama N, Miyamoto M, Egashira Y, Ueyama K. Chem. Commun., 2001, 1746—1747
[68] Nishiyama N, Ichioka K, Park D, Egashira Y, Ueyama K, Gora L, Zhu W, Kapteijn F, Moulijns J. Ind. Eng. Chem. Res., 2004, 43: 1211—1215
[69] Bao J, He J, Zhang Y, Yoneyama Y, Tsubaki N. Angew. Chem. Int. Ed., 2008, 47: 353—356
[70] He J, Liu Z, Yoneyama Y, Nishiyama N, Tsubaki N. Chem-Eur. J., 2006, 12: 8296—8304
[71] He J, Yoneyama Y, Xu B, Nishiyama N, Tsubaki N. Langmuir, 2005, 21: 1699—1702
[72] Li X, He J, Meng M, Yoneyama Y, Tsubaki N. J. Catal., 2009, 265: 26—34
[73] Yang G, He J, Yoneyama Y, Tan Y, Han Y, Tsubaki N. Appl. Catal. A, 2007, 329: 99—105
[74] Yang G, He J, Yoneyama Y, Tan Y, Han Y, Vitidsant T, Tsubaki N. Energy. Fuels, 2008, 22: 1463—1468
[75] Yang G, Tan Y, Han Y, Qiu J, Tsubaki N. Catal. Commun., 2008, 9: 2520—2524
[76] Yoneyama Y, He J, Morii Y, Azuma S, Tsubaki N. Catal. Today, 2005, 104: 37—40
[77] Sun B, Yu G, Lin J, Xu K, Pei Y, Yan S, Qiao M, Fan K, Zhang X, Zong B, Catal. Sci. Technol., 2012, 2: 1625—1629
[78] Ren N, Yang Y, Shen J, Zhang Y, Xu H, Gao Z, Tang Y. J. Catal., 2007, 251: 182—188
[79] Ren N, Yang Y, Zhang Y, Wang Q, Tang Y. J. Catal., 2007, 246: 215—222
[80] Khan E A, Hu E P, Lai Z P. Microporous. Mesoporous. Mater., 2009, 118: 210—217
[81] Van V D, Miyamoto M, Nishiyama N, Egashira Y, Ueyama K. J. Catal., 2006, 243: 389—394
[82] 孔德金(Kong D J), 童伟益(Tong W Y), 郑均林(Zheng J L), 刘志城(Liu Z C), 邹薇(Zou W), 祁晓岚(Qi X L), 房鼎业(Fang D Y). 化学通报(Chemistry), 2008, 71: 249—255
[83] Lu Y, Zhao Y, Yu L L, Shi C, Hu M, Xu Y, Wen L, Yu S. Adv. Mater., 2010, 22: 1407—1411
[84] Yuan X, Archer J. Adv. Mater., 2006, 18: 2325—2329
[85] Kim J, Kim H, Lee N, Kim T, Kim H, Yu T, Song I, Moon W, Hyeon T. Angew. Chem. Int. Ed., 2008, 47: 8438—8441
[86] Zhu Y F, Shi J L, Shen W H, Dong X P, Feng J W, Ruan M L, Li Y S. Angew. Chem. Int. Ed., 2005, 44: 5083—5087
[87] Gao J, Liang G, Zhang B, Kuang Y, Zhang X, Xu B. J. Am. Chem. Soc., 2007, 129: 1428—1433
[88] Kamata K, Lu Y, Xia Y N. J. Am. Chem. Soc., 2003, 125: 2384—2385
[89] Wu X, Xu D. J. Am. Chem. Soc., 2009, 131: 2774—2775
[90] Wu S H, Tseng C T, Lin Y S, Lin C H, Hung Y, Mou C Y. J. Mater. Chem., 2011, 21: 789—794
[91] Arnal P, Comotti M, Schüth F, Angew. Chem. Int. Ed., 2006, 45: 8224—8227
[92] Güttel R, Paul M, Ferdi S, Chem. Commun., 2010, 46: 895—897
[93] Huang X, Guo C, Zuo J, Zheng N, Stucky G D. Small, 2009, 5: 361—365
[94] Yin Y D, Rioux R M, Erdonmez C K, Hughes S, Somorjai G A, Alivisatos A P. Science, 2004, 304: 711—714
[95] Sun Y, Wiley B, Li Z Y, Xia Y N. J. Am. Chem. Soc., 2004, 126 : 9399—9406
[96] Park J C, Bang J U, Lee J, Ko C H, Song H. J. Mater. Chem., 2010, 20: 1239—1246
[97] Lee J, Park J C, Bang J U, Song H. Chem. Mater., 2008, 20: 5839—5844
[98] Lee J, Park J C, Song H. Adv. Mater., 2008, 20: 1523—1528
[99] Chen Y, Chen H, Guo L, He Q, Chen F, Zhou J, Feng J, Shi J. ACS Nano, 2010, 4: 529—539
[100] Chen D, Li L, Tang F, Qi S. Adv. Mater., 2009, 21: 3804—3807
[101] Fang X, Chen C, Liu Z, Liu P, Zheng N. Nanoscale, 2011, 3: 1632—1639
[102] Zhang T, Ge J, Hu Y, Zhang Q, Aloni S, Yin Y. Angew. Chem. Int. Ed., 2008, 47: 5806—5811
[103] Li Y X, Liu S Q, Yao L H, Ji W J, Au C T. Catal. Commun., 2010, 11: 368—372
[104] Yao L H, Li Y X, Zhao J, Ji W J, Au C T. Catal. Today, 2010, 158: 401—408
[105] Yao L H, Shi T B, Li Y X, Zhao J, Ji W J, Au C T. Catal. Today, 2011, 164: 112—119
[106] Li Y X, Yao L H, Liu S Q, Zhao J, Ji W J, Au C T. Catal. Today, 2011, 160: 79—86
[107] Li Y X, Yao L H, Song Y Y, Liu S Q, Zhao J, Ji W J, Au C T. Chem. Commun., 2010, 46: 5298—5300
[108] Li L, He S C, Song Y Y, Zhao J, Ji W J, Au C T. J. Catal., 2012, 288: 54—64
[109] Li L, Lu P, Yao Y, Ji W J. Catal. Commun., 2012, 26: 72—77
[110] Li L, Sun B, Fei Z Y, Yao Y, Zhao J, Ji W J, Au C T. ChemCatChem, 2013, DOI:10.1002/cctc.201300537
[111] Park J C, Lee H J, Jung H S, Kim M, Kim H J, Park K H, Song H. ChemCatChem., 2011, 3: 755—760
[112] Kim S H, Yin Y D, Alivisatos A P, Somorjai G A, Yates J T. J. Am. Chem. Soc., 2007, 129: 9510—9513

PDF (1682KB)

4753

访问

被引

详细

导航

Received	Published	Revised
2012-12-01	2013-11-12	2013-04-01
Online Date
2013-07-18

摘要

Abstract

关键词

Key words

中图分类号

引用本文

参考文献