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载金或银纳米粒子智能杂化微凝胶的合成、性能及其应用
Synthesis, Properties and Applications of Gold or Silver Nanoparticles Loaded Intelligent Hybrid Microgels
载金或银等贵金属纳米粒子（NMNPs）智能杂化微凝胶是一类结合了NMNPs和智能微凝胶两者独特性能的先进功能材料，其最大特点是可通过外界刺激来调节NMNPs的多种性能，或通过测定其性能变化来感知外界刺激。本文从形态结构的角度将已报道的载金或银纳米粒子智能杂化微凝胶分为四类：无规充填型、核壳结构型、表面覆盖型和夹层结构型，分别介绍了它们各自的特点和主要的合成方法。综述了这类智能杂化微凝胶的结构与组成的主要表征方法，以及它们的刺激响应性、可调的局域表面等离子体共振光学性能、表面电场增强效应与荧光性能等。评述了载金或银纳米粒子智能杂化微凝胶在智能微反应器、微传感器、表面增强拉曼光谱基底、药物输送载体和生物成像等方面的应用研究进展。最后，对该类微凝胶的研究方向和发展前景作了展望。
The noble metal nanoparticles (NMNPs) including gold or silver nanoparticles loaded intelligent hybrid microgels are the advanced functional materials which combine the unique properties of both the NMNPs and intelligent microgels. Their prominent characteristic is that a variety of properties of the loaded NMNPs within the microgels can be tuned by external stimulus, or the external stimulus can be sensed by determining the change of their properties. Based on their morphological structure, the reported gold or silver nanoparticles loaded intelligent hybrid microgels are classified into four types in this paper, including randomly filling type, core-shell structure type, surface covering type and sandwich structure type. Their respective features and main synthesis methods are introduced. Additionally, the characterization methods of their structure and composition, their stimulus responsiveness, tunable localized surface plasmon resonance, surface enhancement effect and fluorescence property are reviewed. The application research progress of the intelligent hybrid microgels in smart microreactor, microsensor, the substrate of surface enhanced Raman scattering, drug delivery carrier and biological imaging are also presented. Finally, their research direction and development outlook are commented.
Contents
1 Introduction
2 Synthesis methods of AuNP or AgNP loaded intelligent hybrid microgels
2.1 Randomly filling type
2.2 Core-shell structure type
2.3 Surface covering type
2.4 Sandwich structure type
3 The structure, composition and their characterization methods of AuNP or AgNP loaded intelligent hybrid microgels
3.1 The morphological structure and its characterization methods
3.2 The surface pattern and its characterization methods
3.3 The content of the loaded AuNP or AgNP within the intelligent hybrid microgels and its analysis methods
3.4 The hydrodynamic diameter of the intelligent hybrid microgels and its measuring method
3.5 The interaction between the NMNPs and the macromolecular chains within the microgels and its characterization methods
4 Properties of AuNP or AgNP loaded intelligent hybrid microgels
4.1 Stimulus responsive property
4.2 Tunable localized surface plasmon resonance optical property
4.3 Tunable surface electric field enhancement effect
4.4 Tunable fluorescence property
4.5 Photothermal effect and light stimulus responsive property
5 Applications of AuNP or AgNP loaded intelligent hybrid microgels
5.1 Smart microreactor
5.2 The substrate of surface enhanced Raman scattering
5.3 Microsensor
5.4 Drug controlled release and photothermal therapy
5.5 Biological imaging
6 Conclusions and outlooks
智能杂化微凝胶
intelligent hybrid microgels
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