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功能化纳米Fe3O4磁性材料的制备及其对水中重金属离子的去除
谭丽莎, 孙明洋, 胡运俊, 程丽华, 徐新华*
化学进展 ›› 2013, Vol. 25 ›› Issue (12) :2147-2158
功能化纳米Fe3O4磁性材料的制备及其对水中重金属离子的去除
谭丽莎, 孙明洋, 胡运俊, 程丽华, 徐新华*
化学进展 ›› 2013, Vol. 25 ›› Issue (12) :2147-2158
功能化纳米Fe3O4磁性材料的制备及其对水中重金属离子的去除
Heavy Metal Removal from Aqueous Solution by Functional Magnetic Fe3O4 Nanoparticles
重金属污染是目前最为严峻的环境污染问题之一。利用新颖、高效、易分离再生的功能化磁性纳米材料去除水中的重金属，已越来越受到研究者的关注。本文综述了国内外功能化纳米Fe3O4磁性材料的制备方法及其对水中重金属离子去除的研究进展，重点阐述了针对不同重金属离子去除的纳米Fe3O4磁性材料氨基化（—NH2）、巯基化（—SH）、羧基化（—COOH）及其他功能化的表面修饰材料、修饰方法及其应用，并比较了目前应用于水中重金属离子去除的功能化纳米Fe3O4磁性材料制备方法的优缺点，简要讨论了功能化纳米Fe3O4磁性材料对重金属离子去除的影响因素以及机理。最后，对功能化纳米Fe3O4磁性材料去除水中重金属离子研究的未来发展方向进行了展望。
Contamination of natural water with heavy metals is a significant global issue. Heavy metals removal from aqueous solution by functional magnetic Fe3O4 nanoparticles, characterized in low cost, high efficiency, easiness of separation and regeneration, has received increasing attention in recent years. In this work, the advances on heavy metals removal by functional magnetic Fe3O4 nanoparticles are reviewed. The surface modification materials, synthesis methods, including amino-functionalization, thiol-functionalization, carboxy-functionalization and other functionalizations, and application of functional magnetic Fe3O4 nanoparticles applied for heavy metals removal are elaborated. The advantages and disadvantages of synthesis of functional magnetic Fe3O4 nanoparticles are further compared, and the influencing factors and mechanisms of heavy metals removal by functional magnetic Fe3O4 nanoparticles are briefly discussed. Finally, the suggestions on further study of heavy metals removal by functional magnetic Fe3O4 nanoparticles are presented.
Contents
1 Introduction
2 Synthesis and application of functional magnetic Fe3O4 nanoparticles for heavy metals removal from wastewater
2.1 Amino-functionalization
2.2 Thiol-functionalization
2.3 Carboxy-functionalization
2.4 Other functionalizations
3 Influencing factors of heavy metals removal by functional magnetic Fe3O4 nanoparticles
3.1 pH
3.2 Natural organic matter
3.3 Ionic strength
3.4 Competitive ions
3.5 Particle size
4 Mechanisms of heavy metals removal by functional magnetic Fe3O4 nanoparticles
5 Outlook
Fe3O4
[1] 胡国飞(Hu G F), 孟祥和(Meng X H). 重金属废水处理(Heavy Metal Wastewater Treament). 北京: 化学工业出版社(Beijing: Chemistry Industry Press), 2000. 17—51
[2] Wang L X, Li J C, Jiang Q, Zhao L J. Dalton Trans., 2012, 41(15): 4544—4551
[3] Miyaji F, Masuda S, Suyama Y. J. Ceram. Soc. Jpn., 2010, 118(1383): 1062—1066
[4] Meena A K, Rajagopal C, Kiran, Mishra G K. J. Sci. Ind. Res., 2010, 69(6): 449—453
[5] Jacques R A, Lima E C, Dias S, Mazzocato A C, Pavan F A. Sep. Purif. Technol., 2007, 57(1): 193—198
[6] 王靖宇(Wang J Y), 刘敬勇(Liu J Y), 裴媛媛(Pei Y Y), 蔡华梅(Cai H M), 黄曼雯(Huang M W), 蓝静(Lan J). 安徽农学通报(Anhui Agricultural Science Bulletin), 2011, (16): 128—130
[7] Anirudhan T S, Sreekumari S S. J. Environ. Sci. China, 2011, 23(12): 1989—1998
[8] Demirbas A. J. Hazard. Mater., 2008, 157(2/3): 220—229
[9] Masciangioli T M, Zhang W X. Environ. Sci. Technol., 2003, 225(Part 1): U952
[10] Teja A S, Koh P Y. Prog. Gryst. Growth Ch., 2009, 55(1/2): 22—45
[11] Carpenter E E. J. Magn. Magn. Mater., 2001, 225(1/2): 17—20
[12] Lv X S, Xu J, Jiang G M, Tang J, Xu X H. J. Colloid Interface Sci., 2012, 369: 460—469
[13] Lv X S, Hu Y J, Tang J, Sheng T T, Jiang G M, Xu X H. Chem. Eng. J., 2013, 218: 55—64
[14] Hou J A, Lu R J, Sun M Y, Baig S A, Tang T M, Cheng L H, Xu X H. J. Hazard. Mater., 2012, 217: 224—230
[15] Sun M Y, Hou J A, Tang T M, Lu R J, Cheng L H, Xu X H. Fuel Process. Technol., 2012, 104: 160—166
[16] Fu H, Lv X S, Yang Y P, Xu X H. Desalin. Water Treat., 2012, 39(1/3): 103—111
[17] Wang J H, Zheng S R, Shao Y, Liu J L, Xu Z Y, Zhu D Q. J. Colloid Interface Sci., 2010, 349(1): 293—299
[18] Zhang J, Zhai S, Li S, Xiao Z, Song Y, An Q, Tian G. Chem. Eng. J., 2013, 215/216: 461—471
[19] 熊雷(Xiong L), 姜宏伟(Jiang H W), 王迪珍(Wang D Z). 材料导报(Materials Review), 2008, (5): 31—34
[20] 赵永纲(Zhao Y G), 沈昊宇(Shen H Y), 李勍(Li Q), 夏清华(Xia Q H). 化学学报(Acta Chimica Sinica), 2009, (13): 1509—1514
[21] 赵永纲(Zhao Y G), 沈昊宇(Shen H Y), 茅旗峰(Mao Q F), 阎红强(Yan H Q), 夏清华(Xia Q H). 科学通报(Chinese Science Bulletin), 2010, (12): 1099—1106
[22] 龚红霞(Gong H X), 胡培珠(Hu P Z), 姜梦芸(Jiang M Y), 黄晓玲(Huang X L), 沈涛(Shen T), 葛伟伟(Ge W W), 潘胜东(Pan S D), 沈昊宇(Shen H Y). 化学学报(Acta Chimica Sinica), 2011, (22): 2673—2681
[23] Singh S, Barick K C, Bahadur D. J. Hazard. Mater., 2011, 192(3): 1539—1547
[24] Hao Y M, Chen M, Hu Z B. J. Hazard. Mater., 2010, 184(1/3): 392—399
[25] Tan Y Q, Chen M, Hao Y M. Chem. Eng. J., 2012, 191: 104—111
[26] 程昌敬(Chen C J), 吴莉莉(Wu L L), 刘东(Liu D). 西南民族大学学报(自然科学版)(Journal of Southwest University for Nationalities (Natrual Science Edition)), 2011, (3): 441—446
[27] Huang S H, Chen D H. J. Hazard. Mater., 2009, 163(1): 174—179
[28] 李鹏飞(Li P F), 杨良嵘(Yang L R), 李文松(Li W S), 黄寅斌(Huang Y B), 王娟(Wang J), 孔鹏(Kong P), 徐林(Xu L), 刘会洲(Liu H Z). 过程工程学报(The Chinese Journal of Process Engineering), 2011, (4): 554—560
[29] Horak D. J. Polym. Sci., Part A: Polym. Chem., 2001, 39(21): 3707—3715
[30] Wang W C, Zhang Q, Zhang B B, Li D N, Dong X Q, Zhang L, Chang J. Chin. Sci. Bull., 2008, 53(8): 1165—1170
[31] Ma Z Y, Guan Y P, Liu H Z. J. Polym. Sci., Part A: Polym. Chem., 2005, 43(15): 3433—3439
[32] 周利民(Zhou L M), 王一平(Wang Y P), 刘峙嵘(Liu S R), 黄群武(Huang Q W). 核技术(Nuclear Techniques)., 2007(9): 768—772
[33] Zhang F, Lan J, Zhao Z S, Yang Y, Tan R Q, Song W J. J. Polym. Sci., Part A: Polym. Chem., 2005, 43(15): 3433—3439
[34] Zhang F W, Zhu Z Z, Dong Z P, Cui Z K, Wang H B, Hu W Q, Zhao P, Wang P, Wei S Y, Li R, Ma J T. Microchem. J., 2011, 98(2): 328—333
[35] 翟云会(Zhai Y H), 阮晓芳(Ruan X F), 王振(Wang Z), 翁姣(Weng J). 光谱实验室(Chinese Journal of Spectroscopy Laboratory), 2011, (4): 2042—2046
[36] Li G L, Zhao Z S, Liu J Y, Jiang G B. J. Hazard, Mater., 2011, 192(1): 277—283
[37] Zhang C, Sui J H, Li J, Tang Y L, Cai W. Chem. Eng. J., 2012, 210: 45—52
[38] Dong J, Xu Z H, Wang F. Appl. Surf. Sci., 2008, 254(11): 3522—3530
[39] Huang C Z, Hu B. Spectrochim. Acta, 2008, 63(3): 437—444
[40] 洪帆(Hong F). 华中科技大学硕士论文(Master Dissertation of Huazhong University of Science and Technology), 2008
[41] Yantasee W, Warner C L, Sangvanich T, Addleman R S, Carter T G, Wiacek R J, Fryxell G E, Timchalk C, Warner M G. Environ. Sci. Technol., 2007, 41(14): 5114—5119
[42] Pan S D, Shen H Y, Xu Q H, Luo J, Hu M Q. J. Colloid Interface Sci., 2012, 365(1): 204—212
[43] 周利民(Zhou L M), 刘峙嵘(Liu S R), 黄群武(Huang Q W). 高分子材料科学与工程(Polymer Materials Science & Engineering), 2010, (4): 78—81
[44] Scharfe R R, Sastri V S, Chakraba C L. Anal. Chem., 1973, 45(2): 413—415
[45] Batterham G J, Munksgaard N C, Parry D L. J. Anal. At. Spectrom., 1997, 12(11): 1277—1280
[46] Black F J, Bruland K W, Flegal A R. Anal. Chim. Acta, 2007, 598(2): 318—333
[47] Girginova P I, Daniel-Da-Silva A L, Lopes C B, Figueira P, Otero M, Amaral V S, Pereira E, Trindade T. J. Colloid Interface Sci., 2010, 345(2): 234—240
[48] Kang T W, Moon J, Oh S, Hong S R, Chah S, Yi J H. Chem. Commun., 2005, (18): 2360—2362
[49] Rossi L M, Silva F P, Vono L, Kiyohara P K, Duarte E L, Itri R, Landers R, Machado G. Green Chem., 2007, 9(4): 379—385
[50] Liu A M, Hidajat K, Kawi S, Zhao D Y. Chem. Commun., 2000, (13): 1145—1146
[51] Shin S, Jang J. Chem. Commun. 2007, (41): 4230—4232
[52] Parham H, Zargar B, Shiralipour R. J. Hazard. Mater., 2012, 205: 94—100
[53] Varma A J, Deshpande S V, Kennedy J F. Carbohyd. Polym., 2004, 55(1): 77—93
[54] 刘煌(Liu H). 浙江工商大学硕士论文(Master Dissertation of Zhejiang Gongshang University), 2012
[55] Feng Z G, Zhu S, de Godoi D R M, Samia A C S, Scherson D. Anal. Chem., 2012, 84(8): 3764—3770
[56] 王朝辉(Wang C H), 杨芳(Yang F). 化学工程师(Chemical Engineer), 2012, (7): 15—19
[57] Hu H B, Wang Z H, Pan L. J. Alloys Compd., 2010, 492(1/2): 656—661
[58] Fan F L, Qin Z, Bai J, Rong W D, Fan F Y, Tian W, Wu X L, Wang Y, Zhao L. J. Environ. Radioactiv., 2012, 106: 40—46
[59] Ozmen M, Can K, Arslan G, Tor A, Cengeloglu Y, Ersoz M. Desalination, 2010, 254(1/3): 162—169
[60] Liu J F, Zhao Z S, Jiang G B. Environ. Sci. Technol., 2008, 42(18): 6949—6954
[61] Yang S T, Zong P F, Ren X M, Wang Q, Wang X K. ACS Appl. Mater. Inter., 2012, 4(12): 6891—6900
[62] Feng L Y, Cao M H, Ma X Y, Zhu Y S, Hu C W. J. Hazard. Mater., 2012, 217: 439—446
[63] Jin Y J, Liu F, Tong M P, Hou Y L. J. Hazard. Mater., 2012, 227: 461—468
[64] Wang Z, Wu D, Wu G, Yang N, Wu A. J. Hazard. Mater., 2013, 244/245: 621—627
[65] 黄文(Huang W), 周梅芳(Zhou M F). 环境工程学报(Chinese Journal of Environmental Engineering), 2012, (4): 1251—1256
[66] Chang Y C, Chen D H. J. Colloid Interface Sci., 2005, 283(2): 446—451
[67] 潘才元(Pan C Y). 功能高分子(Functional Polymer). 北京: 科学出版社(Beijing: Science Press), 2006.3—15
[68] Amuda O S, Giwa A A, Bello I A. Biochem. Eng. J., 2007, 36(2): 174—181
[69] Hu J, Chen G H, Lo I. J. Environ. Eng. ASCE, 2006, 132(7): 709—715
[70] Deng S, Bai R B. Environ. Sci. Technol., 2003, 37(24): 5799—5805
[71] Rivero-Huguet M, Marshall W D. Chemosphere, 2009, 76(9): 1240—1248
[72] Yean S, Cong L, Yavuz C T, Mayo J T, Yu W W, Kan A T, Colvin V L, Tomson M B. J. Mater. Res., 2005, 20(12): 3255—3264
[73] Tratnyek P G, Johnson R L. Nano Today, 2006, 1(2): 44—48
[74] Li L, Fan M H, Brown R C, Van Leeuwen J H, Wang J J, Wang W H, Song Y H, Zhang P Y. Crit. Rev. Env. Sci. Tec., 2006, 36(5): 405—431
[75] Banerjee S S, Chen D H. J. Hazard. Mater., 2007, 147(3): 792—799
[76] Hu X J, Wang J S, Liu Y G, Li X, Zeng G M, Bao Z L, Zeng X X, Chen A W, Long F. J. Hazard. Mater., 2011, 185(1): 306—314
[77] Deng S B, Ting Y P. Environ. Sci. Technol., 2005, 39(21): 8490—8496
[78] Chowdhury S R, Yanful E K. J. Environ. Manage., 2010, 91(11): 2238—2247
[79] Zhao Y G, Shen H Y, Pan S D, Hu M Q. J. Hazard. Mater., 2010, 182(1/3): 295—302
[80] Zhao Y G, Shen H Y, Pan S D, Hu M Q, Xia Q H. J. Mater. Sci., 2010, 45(19): 5291—5301
[81] Pearson R G. J. Am. Chem. Soc., 1963, 85: 3533—3539
[82] Badruddoza A, Tay A, Tan P Y, Hidajat K, Uddin M S. J. Hazard. Mater., 2011, 185(2/3): 1177—1186
[83] Zhang Q R, Pan B C, Zhang W M, Pan B J, Lv L, Wang X S, Wu J, Tao X C. J. Hazard. Mater., 2009, 170(2/3): 824—828
[84] Atia A A, Donia A M, Yousif A M. React. Funct. Polym., 2003, 56(1): 75—82
[85] Liang X F, Xu Y M, Sun G H, Wang L, Sun Y, Qin X. Colloids Surf. A, 2009, 349(1/3): 61—68
[86] Shen Y F, Tang J, Nie Z H, Wang Y D, Ren Y, Zuo L. Sep. Purif. Technol., 2009, 68(3): 312—319
[87] Holsapple M P, Farland W H, Landry T D, Monteiro- Riviere N A, Carter J M, Walker N J, Thomas K V. Toxicol. Sci., 2005, 88(1): 12—17
[88] Borm P, Klaessig F C, Landry T D, Moudgil B, Pauluhn J, Thomas K, Trottier R, Wood S. Toxicol. Sci., 2006, 90(1): 23—32
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