中文 |
English |
Email Alert
静电纺丝技术在锂离子动力电池中的应用
Application of Electrospinning Technique in Power Lithium-Ion Batteries
锂离子动力电池，作为动力源，要求其具有较高的比容量、倍率性能、热稳定性及优异的循环性能。静电纺丝技术是一种新型纳米纤维制备技术，因其制备的纳米纤维膜具有比表面积大和孔隙率高等特点，近年来在锂离子电池领域得到了广泛应用，有望成为大幅改善锂离子动力电池性能的关键技术。基于锂离子动力电池的特性，当前静电纺丝技术主要用于制备高孔隙率的纳米纤维膜、高分子共混膜及无机-高分子复合膜等隔膜材料以提高隔膜的机械性能和热稳定性；此外，静电纺丝技术还被用于改善磷酸铁锂等聚阴离子型正极材料及石墨负极材料的电化学性能。本文还针对上述研究中存在的问题，提出了未来静电纺丝技术在锂离子动力电池中应用的可改进的研究方案。
As a power source, the power lithium-ion battery requires high capacity density, high rate capacity, good thermal stability as well as excellent cyclic stability. Electrospinning technique (EST), as a novel solution of preparing nanofibers, has been applied in lithium-ion batteries, such as separators with high surface area and porosity, to greatly enhance the electrochemical performance of power lithium-ion batteries. EST is mainly used for the preparation of high porosity nanofiber membrane, polymer blending membrane and inorganic-polymer composite membrane in order to improve the mechanical properties and thermal stabilities of separators. In addition, the obtained nanofiber materials using EST at cathodes or anodes can enhance the electrochemical performance. At last, the existing problems and the corresponding improvements of the regarding studies are pointed out.
Contents
1 Introduction
2 Electrospinning technique
3 Application of electrospinning technique in power lithium-ion battery
3.1 Cathode materials
3.2 Anode materials
3.3 Separators
4 Perspectives
静电纺丝
electrospinning
[1] Wagemaker M, Mulder M F. Acc. Chem. Res., 2013, 46(5): 1206.
[2] Liu N, Wu H, McDowell M T, Yao Y, Wang C M, Cui Y. Nano Lett., 2012, 12: 3315.
[3] Zhong Y J, Li J T, Wu Z G, Guo X D, Zhong B H, Sun S G. J. Power Sources, 2013, 234: 217.
[4] Ding J, Kongz Y, Yang J R. J. Electrochem. Soc., 2012, 159, (8): A1198.
[5] Taylor G. Proc. R. Soc. Lond. Ser. A: Math. Phys. Sci., 1964, 280(1382): 383.
[6] Huang Z M, Zhang Y Z, Kotaki M, Ramakrishna S. Combust. Sci. Technol., 2003, 63(15): 2223.
[7] 吴大城(Wu D C), 杜仲良(Du Z L), 高绪珊(Gao X S). 纳米纤维(Nanofibers). 北京: 化学工业出版社(Beijing: Chemical Industry Press), 2001. 42.
[8] 薛聪(Xue C), 胡影影(Hu Y Y), 黄争鸣(Huang Z M). 高分子通报(Chinese Polymer Bulletin), 2009, (6): 38.
[9] Tompson C J, Chase G G, Yarin A L. Polymer, 2007, 48(23): 6913.
[10] Smit E, Buttner U, Sanerson R D. Polymer, 2005, 46(8): 2419.
[11] 宋叶萍(Song Y P), 熊杰(Xiong J), 谢军军(Xie J J), 霍鹏飞(Huo P F), 王永攀(Wang Y P), 孙芳(Sun F). 纺织学报(Journal of Textile Research), 2009, 30(7): 6.
[12] Shin Y M, Hohman M M, Brenner M P, Rutledge G C. Polymer, 2001, 42(25): 09955.
[13] Andersson A S, Kalska B, Haggstrom L, Thomas J O. Solid State Ionics, 2000, 130(1/2): 41.
[14] Tarascon J M, Armand M. Nature, 2001, 414(15): 359.
[15] Yang J L, Kang X C, Hu L, Gong X, He D P, Peng T, Mu S C. J. Alloys Compd., 2013, 572(25): 158.
[16] Gui Y, Zhao X L, Guo R S. J. Alloys Compd., 2010, 490(1/2): 236.
[17] Yang R, Song X P, Zhao M S, Wang F. J. Alloys Compd., 2009, 468(1/2): 365.
[18] 曹寅(Cao Y), 王子港(Wang Z G), 杨晖(Yang H). 功能材料(Journal of Functional Materials), 2011, 42(3): 448.
[19] Wang Y, Sun B, Jinsoo P, Woo K, Wang G X. J. Alloys Compd., 2011, 509(3): 1040.
[20] Liu Y Y, Cao C B. Electrochim. Acta, 2010, 55(16): 4694.
[21] Yang J L, Kang X C, He D P, Peng T, Hu L, Mu S C. J. Power Sources, DOI: 10.1016/j.jpowsour.2013.05.088.
[22] 张豪杰(Zhang H J), 王开学(Wang K X), 陈接胜(Chen J S). 高等学校化学学报(Chemical Journal of Chinese Universities), 2011, 32(3): 641.
[23] 李泓(Li H), 李晶泽(Li J Z), 师丽红(Shi L H), 朱广言(Zhu G Y), 陈锓(Chen Q), 卢威(Lu W), 黄学杰(Huang X J), 陈立泉(Chen L Q). 电化学(Electrochemistry), 2000, 6(2): 131.
[24] 田春霞(Tian C X). 稀有金属(Chinese Journal of Rare Metals), 2002, 26(5): 397.
[25] Toprakci O, Ji L, Lin Z, Toprakci H A K, Zhang X. J. Power Sources, 2011, 196(18): 7692.
[26] Toprakci O, Toprakci H A K, Ji L, Lin Z, Gu R, Zhang X. J. Renewable Sustainable Energy, 2012, 4(1): 013121.
[27] Toprakci O, Toprakci H A K, Ji L, Xu G, Lin Z, Zhang X. ACS Appl. Mater. Interfaces, 2012, 4(3): 1273.
[28] Hagen R V, Lorrmann H, Möller K C, Mathur S. Adv. Energy Mater., 2012, 2(5): 553.
[29] Zhang S, Li Y, Xu G, Li S, Lu Y, Toprakci O, Zhang X. Soft Nanoscience Letters, 2012, 2(3): 54.
[30] Zhang S, Lin Z, Ji L, Li Y, Xu G, Xue L, Li S, Lu Y, Toprakci O, Zhang X. J. Mater. Chem., 2012, 22(29): 14661.
[31] Zhang S, Li Y, Xu G, Li S, Lu Y, Toprakci O, Zhang X. J. Power Sources, 2012, 213: 10.
[32] Yoshio M, Wang H, Fukuda K, Hara Y, Adachi Y. J. Electrochem. Soc., 2000, 147(4): 1245.
[33] 赵智泉(Zhao Z Q), 刘庆雷(Liu Q L), 黄大成(Huang D C), 周凤羽(Zhou F Y), 刘元超(Liu Y C), 张荻(Zhang D). 机械功能材料(Materials for Mechanical Engineering), 2012, 36(9): 1.
[34] 段博超(Duan B C), 王维坤(Wang W K), 赵海雷(Zhao H L), 王安邦(Wang A B), 余仲宝(Yu Z B), 杨欲生(Yang Y S). 稀有金属材料与工程(Rare Metal Materials and Engineering), 2012, 41(2): 93.
[35] Obrovac M N, Christensen L. Electrochem. Solid-State Lett., 2004, 7(5): A93.
[36] Ji L, Zhang X. Carbon, 2009, 47(14): 3219.
[37] Ji L, Zhang X. Energy Environ. Sci., 2010, 3(1): 124.
[38] Hwang T H, Lee Y M, Kong B S, Seo J S, Choi J W. Nano Lett., 2012, 12(2): 802.
[39] Bonino C A, Ji L, Lin Z, Toprakci O, Zhang X, Khan S A. ACS Appl. Mater. Interfaces, 2011, 3(7): 2534.
[40] Zhang X, Kumar P S, Aravindan V, Liu H H, Sundaramurthy J, Mhaisalkar S G, Duong H M, Ramakrishna S, Madhavi S. J. Phys. Chem. C, 2012, 116(28): 14780.
[41] Ji L, Toprakci O, Alcoutlabi M, Yao Y, Li Y, Zhang S, Guo B, Lin Z, Zhang X. ACS Appl. Mater. Interfaces, 2012, 4(5): 2672.
[42] 彭久云(Peng J Y), 曾照强(Zeng Z Q), 苗赫濯(Miao H Z). 电源技术(Chinese Journal of Power Sources), 2002, 26(6): 452.
[43] Guo B K, Li Y, Yao Y F, Lin Z, Ji L, Xu G, Liang Y, Shi Q, Zhang X. Solid State Ionics, 2011, 204/205: 61.
[44] Gao K, Hu X G, Dai C S, Yi T F. Mater. Sci. Eng., B, 2006, 131(1/3): 100.
[45] Subramania A, Kalyana S N T, Sathyia P A R, Kumar G A. J. Membr. Sci., 2007, 294(1/2): 8.
[46] 盛晓颖(Sheng X Y), 张学俊(Zhang X J), 刘婷(Liu T). 化工新型材料(New Chemical Materials), 2011, 39(5): 18.
[47] Hwang K, Kwon B, Byun H. J. Membr. Sci., 2011, 378(1/2): 111.
[48] Hao J L, Lei G T, Li Z H, Wu L J, Xiao Q Z, Wang L. J. Membr. Sci., 2013, 428: 11.
[49] Qi W, Lu C, Chen P, Han L, Yu Q, Xu R Q. Mater. Lett., 2012, 66(1): 239.
[50] Jianga G, Maedab S, Yanga H, Saitob Y, Tanasea S, Sakaia T. J. Power Sources, 2005, 141(1): 143.
[51] Kim Y J, Ahn C H, Lee M B, Choi M S. Mater. Chem. Phys., 2011, 127(1/2): 137.
[52] Jung H R, Ju D H, Lee W J, Zhang X, Kotek R. Electrochim. Acta, 2009, 53(13): 3630.
[53] Jeong H S, Choi E S, Lee S Y, Kim J H. J. Membr. Sci., 2012, 415/416: 513.
[54] Zaccaria M, Gualandi C, Fabiani D, Focaret M L, Croce F. Journal of Nanomaterials, 2012, 216012.
[55] Liang Y Z, Ji L, Guo B K, Lin Z, Yao Y, Li Y, Alcoutlabi M, Qiu Y, Zhang X. J. Power Sources, 2011, 196(1): 436.
[56] Lalia B S, Samad Y A, Hashaikeh R. J. Solid State Electrochem., 2013, 17(3): 575.
[57] Ratna D, Divekar S, Patchaiappan S, Samui A B, Chakraborty B C. Polym. Int., 2007, 56(7): 900.
[58] Shubha N, Prasanth R, Hoon H H, Srinivasan M. Mater. Res. Bull., 2013, 48(2): 526.
[59] Jiang Z, Carroll B, Abraham K M. Electrochim. Acta, 1997, 42(17): 2667.
[60] Abbrent S, Pletstil J, Hlavata D, Lindgren J, Tegenfeldt J, Wendsjö A. Polymer, 2001, 42(4): 1407.
[61] Zhong Z, Cao Q, Jing B, Wang X, Li X, Deng H. Mater. Sci. Eng., B, 2012, 177(1): 86.
[62] Gopalan A I, Santhosh P, Manesh K M, Nho J H, Kim S H, Hwang C G, Lee K P. J. Membr. Sci., 2008, 325(2): 683.
[63] Xiao Q, Li Z, Gao D, Zhang H. J. Membr. Sci., 2009, 326(2): 260.
[64] Raghavan P, Zhao X H, Shin C, Baek D H, Choi J W, Manuel J, Heo M Y, Ahn J H, Nah C. J. Power Sources, 2010, 195(18): 6088.
[65] Ding Y H, Zhang P, Long Z L, Jiang Y, Xu F, Di W. J. Membr. Sci., 2009, 329(1/2): 56.
[66] Wu N, Cao Q, Wang X Y, Chen Q. J. Power Sources, 2011, 196(22): 9751.
[67] Alcoutlabi M, Lee H, Watson J V, Zhang X. J. Membr. Sci., 2013, 48(6): 2690.
[68] Zhu Y S, Xiao S Y, Shi Y, Yang Y Q, Wu Y P. J. Mater. Chem. A. 2013, 1: 7790.
/
| 〈 |
|
〉 |
PDF
(1121KB)
