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介孔沸石分子筛的制备
Synthesis of Mesoporous Zeolite
介孔沸石分子筛是一种含有丰富介孔的结晶沸石，它不同于介孔分子筛和微孔沸石的简单机械混合。它不仅具备微孔沸石高的热和水热稳定性、优异的选择性和活性，而且由于介孔的引入改善了其对大分子的吸附和扩散性能，逐渐成为多孔催化材料研究领域的热点。本文主要从模板法、后处理法和前驱体组装法等方法出发，介绍了介孔沸石分子筛最新的制备方法研究进展。通过对比不同制备方法的优缺点，指出各种方法的改进方向，以期寻求一种较优的合成策略，以满足现今催化领域日益苛刻的要求。
Mesoporous zeolite materials, which are defined as the crystalline zeolite materials containing a large amount of mesopores, are different from the simple mechanical mixture of microporous zeolites and mesoporous molecular sieves. It gradually becomes a hotspot in the field of porous catalytic materials because it not only has high heat and water thermal stability, significant shape selectivity and high activity, but also improves the adsorption and diffusion of large molecules due to the insertion of mesopores. On the basis of the synthesis methods including template method, post-processing method, precursor assembly method and so on, the research progress on the synthesis of mesoporous zeolite is introduced. By comparing the advantages and disadvantages of different preparation methods, the direction of the improvement of various methods is pointed out so as to seek a better synthetic strategy for meeting the ever more harsh requirements of catalysis today.
Contents
1 Introduction
2 Template method
2.1 Soft template
2.2 Hard template
3 Post-processing method
4 Precursor assembly method
5 Conclusion and outlook
mesoporous zeolite
[1] 高滋(Gao Z). 沸石催化与分离技术(Zeolite Catalysis and Separation Technology). 北京: 中国石化出版社(Beijing: China Petrochemical Press), 1999. 3.
[2] 徐如人(Xu R R), 庞文琴(Pang W Q). 分子筛与多孔材料化学(Chemistry of Zeolite and Porous Materials). 北京: 科学出版社(Beijing : Science Press), 2004. 34.
[3] Corma A. Chem. Rev., 1997, 97: 2373.
[4] Corma A. Chem. Rev., 1995, 95: 559.
[5] Corma A. J. Catal. . 2003, 216: 298.
[6] Tao Y S, Kanoh H, Abrams L, Kaneko K. Chem. Rev., 2006, 106: 896.
[7] Aguado J, Serrano D P, Escola J M, Rodríguez J M. Microp. Mesop. Mater., 2004, 75: 41.
[8] Davis M E, Saldarriaga C, Montes C. Zeolites, 1988, 8(5): 362.
[9] Corma A, Diaz-Cabanas M J, Rey F, Nicolopoulus S, Boulahya K. Chem. Commun., 2004, 1356.
[10] Kresge C T, Leonowicz M E, Roth W J, Vartuli J C, Beck J S. Nature, 1992, 359(6379): 710.
[11] Chen L H, Li X Y, Rooke J C, Zhang Y H, Yang X Y, Tang Y, Xiao F S, Su B L. J. Mater. Chem., 2012, 22: 17381.
[12] Davis M E. Nature, 2002, 417: 813.
[13] 王义(Wang Y), 李旭光(Li X G), 薛志元(Xue Z Y), 李全芝(Li Q Z). 化学进展(Progress in Chemistry), 2010, 22(2/3): 322.
[14] 宋春敏(Song C M), 阎子峰(Yan Z F). 分子催化(Journal of Molecular Catalysis), 2008, 22(3): 280.
[15] Yang X Y, Leonard A, Lemaire A, Tian G, Su B L. Chem. Commun., 2011, 47: 2763.
[16] Kloetstra K R, Zandbergen H W, Jansen J C, van Bekkum H. Microp. Mater., 1996, 6(5/6): 287.
[17] Karlsson A, Stöcker M, Schmidt R. Microp. Mesop. Mater., 1999, 27: 181.
[18] Colin S Cundy, Paul A Cox. Microp. Mesop. Mater., 2005, 82(1/2): 1.
[19] Xiao F S, Wang L F, Yin C Y, Lin K F, Di Y, Li J X, Xu R R, Su D S, Schlogl R, Yokoi T, Tatsumi T. Angew. Chem., 2006, 118(9): 3162.
[20] Wang L F, Zhang Z, Yin C Y, Shan Z C, Xiao F S. Microp. Mesop. Mater., 2010, 131: 58.
[21] Liu S Z, Cao X J, Li L S, Li C J, Ji Y Y, Xiao F S. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2008, 318: 269.
[22] Fu W Q, Zhang L, Tang T D, Ke Q P, Wang S, Hu J B, Fang G Y, Li J X, Xiao F S. J. Am. Chem. Soc., 2011, 133: 15346.
[23] Liu F J, Willhammar T, Wang L, Zhu L F, Sun Q, Meng X J, Carrillo-Cabrera W, Zou X D, Xiao F S. J. Am. Chem. Soc. . 2012, 134: 4557.
[24] Chen L, Zhu S Y, Wang Y M, He M Y. New J. Chem., 2010, 34: 2328.
[25] Gu F N, Wei F, Yang J Y, Lin N, Lin W G, Wang Y, Zhu J H. Chem. Mater., 2010, 22: 2442.
[26] Zhu H B, Liu Z C, Kong D J, Wang Y D, Xie Z K. J. Phys. Chem. C. 2008, 112: 17257.
[27] Choi M, Cho H S, Srivastava R, Venkatesan C, Choi D H, Ryoo R. Nat. Mater., 2006, 5: 718.
[28] Choi M, Srivastava R, Ryoo R. Chem. Commun., 2006, 4380.
[29] Srivastava R, Choi M, Ryoo R. Chem. Commun., 2006, 4489.
[30] Shetti V N, Kim J, Srivastava R, Choi M, Ryoo R. J. Catal., 2008, 254: 296.
[31] Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R. Nature, 2009, 461: 246.
[32] Na K, Choi M, Park W, Sakamoto Y, Terasaki O, Ryoo R. J. Am. Chem. Soc., 2010, 132: 4169.
[33] Na K, Jo C, Kim J, Cho K, Jung J, Seo Y, Messinger R J, Chmelka B F, Ryoo R. Science, 2011, 333: 328.
[34] Zhu H B, Liu Z C, Wang Y D, Kong D J, Yuan X H, Xie Z K. Chem. Mater., 2008, 20: 1134.
[35] Ren L M, Wu Q M, Yang C G, Zhu L F, Li C J, Zhang P L, Zhang H Y, Meng X J, Xiao F S. J. Am. Chem. Soc., 2012, 134: 15173.
[36] Jacobsen C J H, Houzvicka J, Schmidt I, Madsen C, Carlsson A. US 6565826, 2003.
[37] Wang L F, Yin C Y, Shan Z C, Liu S, Du Y C, Xiao F S. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2009, 126.
[38] Ryoo R, Joo S H, Jun S. J. Phys. Chem. B, 1999, 103: 7743.
[39] Schüth F. Angew. Chem. Int. Edit., 2003, 42: 3604.
[40] Yang H F, Zhao D Y. J. Mater. Chem., 2005, 15: 1217.
[41] Liang C D, Li Z J, Dai S. Angew. Chem. Int. Edit., 2008, 47: 3696.
[42] Yang Z X, Xia Y D, Mokaya R. Adv. Mater., 2004, 16(8): 727.
[43] Sakthivel A, Huang S, Chen W, Lan Z, Chen K, Kim T, Ryoo R, Chiang A S T, Liu S. Chem. Mater., 2004, 16: 3168.
[44] Fang Y M, Hu H Q. J. Am. Chem. Soc., 2006, 128: 10636.
[45] Sun C, Du J M, Liu J, Yang Y S, Ren N, Shen W, Xu H L, Tang Y. Chem. Commun., 2010, 46: 2671.
[46] Tao Y S, Kanoh H, Kaneko K. J. Am. Chem. Soc., 2003, 125: 6044.
[47] Tao Y S, Kanoh H, Kaneko K. J. Phys. Chem. B, 2003, 107: 10974.
[48] Wattankit C, Warakulwit C, Pantu P, Sunpetch B, Charoenpanich M, Limtrakul J. Can. J. Chem. Eng., 2012, 90: 873.
[49] Shu S, Husain S, Koros W J. Ind. Eng. Chem. Res., 2007, 46: 767.
[50] Wang J, Groen J C, Yue W B, Zhou W Z, Coppens M. Chem. Commun., 2007, 4653.
[51] Zhou J, Hua Z L, Shi J L, He Q J, Guo L M, Ruan M L. Chem. -Eur. J., 2009, 15: 12949.
[52] Zhou J, Hua Z L, Cui X Z, Ye Z Q, Cui F M, Shi J L. Chem. Commun., 2010, 46: 4994.
[53] 刘欣梅(Liu X M), 阎子峰(Yan Z F). 化学学报(Acta Chimica Sinica), 2000, 58(8): 1009.
[54] Liu X M, Yan Z F. Catal. Today, 2001, 68: 145.
[55] Chang X W, He L F, Liang H N, Liu X M, Yan Z F. Catal. Today, 2010, 158(3/4): 198.
[56] 何丽凤(He L F), 张占全(Zhang Z Q), 刘欣梅(Liu X M), 阎子峰(Yan Z F). 石油学报(石油加工)(Acta Petrolei Sinica (Petroleum Processing Section)), 2012, 28(zl): 13.
[57] 何丽凤(He L F). 中国石油大学(华东)硕士论文(Master Dissertation of China University of Petroleum (East China)), 2012.
[58] Groen J C, Jansen J C, Moulijn J A, Perez-Ramirez J. J. Phys. Chem. B, 2004, 108: 13062.
[59] Tian F P, Wu Y H, Shen Q C, Li X, Chen Y Y, Meng C G. Microp. Mesop. Mater., 2013, 173: 129.
[60] Groen J C, Peffer L A A, Moulijn J A, Perez-Ramirez J. Chem. -Eur. J. . 2005, 11: 4983.
[61] Groen J C, Bach T, Ziese U, Donk A M P, Jong K P D, Moulijn J A. J. Am. Chem. Soc., 2005, 31(127): 10792.
[62] Groen J C, Zhu W D, Brouwer S, Huynink S J, Kapteijn F, Moulijn J A, Perez-Ramirez J. J. Am. Chem. Soc., 2007, 129: 355.
[63] 许迪欧(Xu D O), 王润伟(Wang R W), 付伟伟(Fu W W), 王影(Wang Y), 张宗弢(Zhang Z T), 裘式纶(Qiu S L). 高等学校化学学报(Chemical Journal of Chinese Universities), 2011, 32: 1684.
[64] Yang H, Zhu G S, Zhang D L, Xu D O, Qiu S L. Microp. Mesop. Mater., 2007, 102: 95.
[65] Mrak M, Tušar N N, Logar N Z, Mali G, Kljaji D? A, Ar?on L, Launay F, Gedeon A, Kau?i? V. Microp. Mesop. Mater., 2006, 95: 76.
[66] Mazaj M, Logar N Z, Mali G, Tusar N N, Arcon L, Ristic A, Recnik A, Kaucic V. Microp. Mesop. Mater., 2007, 99: 3.
[67] Frunz L, Prins R, Pirngruber G D. Microp. Mesop. Mater., 2006, 88: 152.
[68] Xiao F S, Han Y, Yu Y, Meng X J, Yang M, Wu S. J. Am. Chem. Soc., 2002, 124 (6): 888.
[69] Moller K, Yilmaz B, Jacubinas R M, Muller U, Bein T. J. Am. Chem. Soc. . 2011, 133: 5284.
[70] Petushkov A, Merilis G, Larsen S C. Microp. Mesop. Mater., 2011, 143: 97.
[71] Zhao J J, Zhou J, Chen Y, He Q J, Ruan M L, Guo L M, Shi J L, Chen H R. J. Mater. Chem., 2009, 19: 7614.
[72] Liu Y, Zhang W, Pinnavala T J. J. Am. Chem. Soc., 2000, 122: 8791.
[73] Liu Y, Zhang W, Pinnavala T J. Angew. Chem. Int. Edit., 2001, 40(7): 1255.
[74] Liu Y, Pinnavala T J. J. Am. Chem. Soc., 2003, 125: 2376.
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