中文 |
English |
Email Alert
基于对硝基苯酚还原模型反应的纳米金催化材料
Preparation and Catalytic Properties of Nano-Au Catalytic Materials Based on the Reduction of 4-Nitrophenol
硝基苯酚是工业和农业废水中常见的有机污染物之一。近年来，由于纳米金催化材料的优异催化性能，纳米金催化材料日益成为催化还原对硝基苯酚的一种高效、快速和环境友好的催化材料；合成高度分散、尺寸均一、稳定、易分离及可重复使用的纳米金催化材料是该领域的研究重点。本文以纳米金催化材料的整体结构为主线，归纳了纳米金催化材料的最新研究进展；重点讨论了纳米金催化材料的制备手段及其催化活性、稳定性、可回收性和可重复使用性；并对纳米金催化材料的发展方向和今后需解决的关键问题进行了展望。
Nitrophenols are one of the most common organic pollutants in industrial and agricultural wastewater. In recent years, due to the excellent catalytic properties of nano-Au catalytic materials, as highly efficient, fast and eco-friendly catalysts, nano-Au catalytic materials have been widely applied to the reduction of 4-nitrophenol. Correspondingly, synthesis of highly dispersed, size controllable, long-term and recycleable nano-Au catalytic materials is the main stream of this field. Based on the overall structure of the nano-Au catalytic materials, this review summarizes the latest progress on this direction, especially for the preparative methods, catalytic performance, stability, recyclability and reusability. Finally, the remaining problems and the future developing prospects are also proposed.
Contents
1 Introduction
2 Nano-Au catalyst and its catalytic performance
2.1 Polymer-based elastic nanocatalysts
2.2 Hollow spherical nanocatalysts
2.3 Core@shell structured nanocatalysts
2.4 Yolk@shell-like nanocatalysts
2.5 Other nanocatalysts
3 Conclusion and outlook
4-nitrophenol
[1] Lai T L, Yong K F, Yu J W, Chen J H, Shu Y Y, Wang C B. J. Hazard. Mater., 2011, 185: 366.
[2] Li J, Kuang D, Feng Y, Zhang F, Xu Z, Liu M. J. Hazard. Mater., 2012, 201/202: 250.
[3] 周桂林(Zhou G L), 魏梦颖(Wei M Y), 费丽莎(Fei L S), 吴茂(Wu M), 曹媛媛(Cao Y Y), 周新星(Zhou X X), 谢红梅(Xie H M). 水处理技术(Technology of Water Treatment), 2012, 38(2): 52.
[4] 王韬(Wang T), 李鑫钢(Li X G), 杜启云(Du Q Y). 化工进展(Chemical Industry and Engineering Progress), 2008, 27(2): 231.
[5] 史玲(Shi L), 黄廷林(Huang T L), 白雪莲(Bai X L). 水处理技术(Water Treatment Technology), 2011, 37(4): 49.
[6] Wang A J, Cheng H Y, Liang B, Ren N Q, Cui D, Lin N, Kim B H, Rabaey K. Environ. Sci. Technol., 2011, 45: 10186.
[7] Du Y, Chen H, Chen R, Xu N. Appl. Catal. A, 2004, 277: 259.
[8] 姜元国(Jiang Y G), 陈日志(Chen R Z), 邢卫红(Xing W H). 化工进展(Chemical Industry and Engineering Progress), 2011, 30(2): 309.
[9] Larsson E M, Langhammer C, Zoric I, Kasemo B. Science, 2009, 326: 1091.
[10] Alayoglu S, Nilekar A U, Mavrikakis M, Eichhorn B. Nat. Mater., 2008, 7: 333.
[11] Zhang F X, Han L, Israel L B, Daras J G, Maye M M, Ly N K, Zhong C J. Analyst., 2002, 127: 462.
[12] Link S, El-Sayed M A. J. Phys. Chem. B, 1999, 103: 8410.
[13] Noguez C, Garzon I L. Chem. Soc. Rev., 2009, 38: 757.
[14] Denkwitz Y, Makosch M, Geserick J, Hormann U, Selve S, Kaiser U, Husing N, Behm R J. Appl. Catal. B: Environmental, 2009, 91: 470.
[15] Sebastian D, Ruiz A G, Suelves I, Moliner R, Lazaro M J, Baglio V, Stassi A, Arico A S. Appl. Catal. B: Environmental, 2012, 115: 269.
[16] Zepeda T A, Hernandez A M, Lopez R G, Pawelec B. Appl. Catal. B: Environmental, 2010, 100: 450.
[17] Daniel M C, Astruc D. Chem. Res., 2004, 104: 293.
[18] Hayakawa K, Yoshimura T, Esumi K. Langmuir, 2003, 19: 5517.
[19] Kuroda K, Ishida T, Haruta M. J. Mol. Catal. A: Chem., 2009, 298: 7.
[20] Zeng J, Zhang Q, Chen J, Xia Y. Nano Lett., 2010, 10: 30.
[21] Herron N, Thorn D L. Adv. Mater., 1998, 10: 1173.
[22] Lee I, Morales R, Albiter M A, Zaera F. Proc. Natl. Acad. Sci. U. S. A., 2008, 105: 15241.
[23] Narayanan R, Tabor C, El-Sayed M A. Top. Catal., 2008, 48: 60.
[24] Zhao M, Sun L, Crooks R M. J. Am. Chem. Soc., 1998, 120: 4877.
[25] Enache D I, Edwards J K, Landon P, Solsona Espriu B, Carley A F, Herzing A A, Watanabe M, Kiely C J, Knight D W, Hutchings G J. Science, 2006, 311: 362.
[26] Tsunoyama H, Sakurai H, Tsukuda T. Chem. Phys. Lett., 2006, 429: 528.
[27] Hutchings G J. J. Catal., 1985, 96: 292.
[28] Haruta M, Kobayashi T, Sano H, Yamada N. Chem. Lett., 1987, 405.
[29] Guzman J, Gates B C, Nano Lett., 2001, 1: 689.
[30] Tabakova T, Boccuzzi F, Manzoli M, Andreeva D. Appl. Catal. A, 2003, 252: 385.
[31] Sinha A K, Seelan S, Tsubota S, Haruta M. Angew. Chem. Int. Ed., 2004, 43: 1546.
[32] Lee J, Park J C, Song H. Adv. Mater., 2008, 20(8): 1523.
[33] Hu N, Yin J Y, Tang Q, Chen Y. J. Polym. Sci. A: Polym. Chem., 2011, 49(17): 3826.
[34] Gajan D, Guillois K, Delichère P, Basset J M, Candy J P, Caps V, Copéret C, Lesage A, Emsley L. J. Am. Chem. Soc., 2009, 131: 14667.
[35] Wu X J, Xu D S. J. Am. Chem. Soc., 2009, 131: 2774.
[36] Tai Y, Yamaguchi W, Okada M, Ohashi F, Shimizu K, Satsuma A, Tajiri K, Kageyama H. J. Catal., 2010, 270: 234.
[37] Choi Y, Bae H S, Seo E, Jang S, Park K H, Kim B S. J. Mater. Chem., 2011, 21: 15431.
[38] Zhao G, Ling M, Hu H, Deng M, Xue Q, Lu Y. Green Chem., 2011, 13: 3088.
[39] Yang H, Nagai K J, Abe T, Homma H, Norimatsu T, Ramaraj R. ACS Appl. Mater. Interfaces, 2009, 1(9): 1860.
[40] Premkumar T E. Geckeler K. Chem-Asian J., 2010, 5(12): 2468.
[41] Gangula A, Podila R M R, Karanam L, Janardhana C, Rao A M. Langmuir, 2011, 27 (24): 15268.
[42] Huang H Z, Yang X R. Biomacromol., 2004, 5: 2340.
[43] Wu H, Zhuo L M, He Q, Liao X P, Shi B. Appl. Catal. A, 2009, 366: 44.
[44] Wu H, Huang X, Gao M M, Liao X P, Shi B. Green Chem., 2011, 13: 651.
[45] Lam E, Hrapovic S, Majid E, Chong J H, Luong J H. Nanoscale, 2012, 4: 997.
[46] Nemanashi M, Meijboom R. J. Colloid Interf. Sci., 2013, 389: 260.
[47] Wang M L, Jiang T T, Lu Y, Liu H J, Chen Y. J. Mater. Chem. A, 2013, 1: 5923.
[48] Sen I K, Maity K, Islam S S. Carbohydr. Polym., 2013, 91(2): 518.
[49] Rajesh S, Natalie S B, Jennifer S S. J. Macromol., 2008, 41(12): 4347.
[50] Yu Q Q, Dong Y Y, Liao W P, Jin M S, He T, Suo Z H. J. Fuel Chem. Technol., 2010, 38(2): 223.
[51] 李军波(Li J B), 李桂珍(Li G Z), 刘志飞(Liu Z F), 韩晨(Han C), 周惠云(Zhou H Y), 张军凯(Zhang J K). 应用化学(Chinese Journal of Applied Chemistry), 2012, 29(10): 1143.
[52] Zhang J M, Han D H, Zhang H J, Chaker M, Zhao Y, Ma D L. Chem. Commun., 2012, 48: 11510.
[53] Han D, Tong X, Boissiere O, Zhao Y. ACS Macro Lett., 2012, 1: 57.
[54] Zhu M Q, Wang L Q, Exarhos G J, Li A D Q. J. Am. Chem. Soc., 2004, 126: 2656.
[55] Liu X Y, Cheng F, Liu Y, Liu H J, Chen Y. J. Mater. Chem., 2010, 20: 360.
[56] Dong F P, Guo W P, Park S K, Ha C S. Chem. Commun., 2012, 48: 1108.
[57] Chen Z, Cui Z M, Cao C Y, He W D, Jiang L, Song W G. Langmuir, 2012, 28: 13452.
[58] Chen Z, Cui Z M, Niu F, Jiang L, Song W G. Chem. Commun., 2010, 46: 6524.
[59] Ji Q M, Hill J P, Ariga K. J. Mater. Chem. A, 2013, 1: 3600.
[60] Ji Q, Guo C, Yu X, Ochs C J, Hill J P, Caruso F, Nakazawa H, Ariga K. Small, 2012, 8: 2345.
[61] Manoharan Y, Ji Q, Yamazaki T, Shanmugavel C, Chen S, Ganesan S, Hill J P, Ariga K, Hanagata N. Int. J. Nanomed., 2012, 7: 3625.
[62] Abu-Reziq R, Alper H, Wang D, Post M L. J. Am. Chem. Soc., 2006, 128: 5279.
[63] Deng Y H, Cai Y, Sun Z K, Liu J, Liu C, Wei J, Li W, Liu C, Wang Y, Zhao D Y. J. Am. Chem. Soc., 2010, 132: 8466.
[64] Oliveira R L, Kiyohara P K, Rossi L M. Green Chem., 2010, 12: 144.
[65] Zhu Y, Shen J, Zhou K, Chen C, Yang X, Li C. J. Phy. Chem. C, 2011, 115: 1614.
[66] Zhu M, Wang C, Meng D, Diao G. J. Mater. Chem. A, 2013, 1: 2118.
[67] Mulfort K L, Hupp J T. J. Am. Chem. Soc., 2007, 129: 9604.
[68] Zhu M, Diao G. Nanoscale, 2011, 3: 2748.
[69] Polshettiwar V, Luque R, Fihri A, Zhu H, Bouhrara M, Basset J M. Chem. Rev., 2011, 111: 3036.
[70] Kim D, Lee N, Park M, Kim B Y, An K, Hyeon T. J. Am. Chem. Soc., 2009, 131: 454.
[71] Park H Y, Schadt M J, Wang L Y, Lim I S, Njoki P N, Kim S H, Jang M Y, Luo J, Zhong C J. Langmuir, 2007, 23: 9050.
[72] Yi C F, Xu Z S, Ford W T. Colloid Polym. Sci., 2004, 282: 1054.
[73] Antolini E, Gonzalez E R. Appl. Catal. A, 2009, 365(1): 1.
[74] Liu B, Zhang W, Yang F, Feng H, Yang X. J. Phys. Chem. C, 2011, 115: 15875.
[75] Wu S, Kaiser J, Guo X, Li L, Lu Y, Ballauff M. Ind. Eng. Chem. Res., 2012, 51: 5608.
[76] Xuan S, Wang Y X J, Yu J C, Leung K C F. Langmuir, 2009, 25: 11835.
[77] Contreras-Cáceres R, Abalde-Cela S, Guardia-Girós P, Fernández-Barbero A, Pérez-Juste J, Alvarez-Puebla R A, Liz-Marzán L M. Langmuir, 2011, 27: 4520.
[78] Chang Y C, Chen D H. J. Hazard. Mater., 2009, 165: 664.
[79] Chang Y C, Chen D H. J. Colloid Interf. Sci., 2005, 283: 446.
[80] Juang R S, Shao H J. Water Res., 2002, 36: 2999.
[81] Ng J C Y, Cheung W H, McKay G. J. Colloid Interf. Sci., 2002, 255: 64.
[82] Inoue K, Yoshizuka K, Ohto K. Anal. Chim. Acta, 1999, 388: 209.
[83] Zhang F W, Liu N, Zhao P, Sun J, Wang P, Ding W, Liu J T, Jin J, Ma J T. Appl. Surf. Sci., 2012, 263: 471.
[84] Kuroda K, Ishida T, Haruta M. J. Mol. Catal. A: Chemical, 2009, 298: 7.
[85] Gao Y, Ding X, Zheng Z, Cheng X, Peng Y. Chem. Commun., 2007, 3720.
[86] Lam E, Hrapovic S, Majid E, Chong J H, Luong J H T. Nanoscale, 2012, 4: 97.
[87] Marcelo G, Muñoz-Bonilla A, Fernández-García M. J. Phys. Chem. C, 2012, 116: 24717.
[88] Fei B, Qian B, Yang Z, Wang R, Liu W, Mak C, Xin J. Carbon, 2008, 46: 1795.
[89] Lee H, Dellatore S M, Miller W M, Messersmith P B. Science, 2007, 318: 426.
[90] Sureshkumar M, Siswanto D Y, Lee C K. J. Mater. Chem., 2010, 20: 6948.
[91] Black K C L, Black Z, Messersmith P B. Chem. Mater., 2011, 23: 1130.
[92] Zeng T, Zhang X L, Niu H Y, Ma Y R, Li W H, Cai Y Q. Appl. Catal. B: Environmental, 2013, 134/135: 26.
[93] Liu J, Sun Z K, Deng Y H, Zou Y, Li C Y, Guo X H, Xiong L Q, Gao Y, Li F Y, Zhao D Y. Angew. Chem. Int. Ed., 2009, 48: 5875.
[94] Lee H, Scherer N F, Messersmith P B. Proc. Natl. Acad. Sci. U. S. A., 2006, 103: 12999.
[95] Lee H, Lee Y, Statz A R, Rho J, Park T G, Messersmith P B. Adv. Mater., 2008, 20: 1619.
[96] Guo W C, Wang Q, Wang G, Yang M, Dong W J, Yu J. Chem-Asian J., 2013, 8(6): 1160.
[97] Zhu Y H, Shen J H, Zhou K F, Chen C, Yang X L, Li C Z. J. Phys. Chem. C, 2011, 115 (5): 1614.
[98] Zheng J M, Dong Y L, Wang W F, Ma Y H, Hu J, Chen X J, Chen X G. Nanoscale, 2013, 5: 4894.
[99] Du X, He J, Zhu J, Sun L, An S. Appl. Surf. Sci., 2012, 258: 2717.
[100] Ge J, Zhang Q, Zhang T, Yin Y. Angew. Chem., 2008, 120: 9056.
[101] Zhang Y, Liu S, Lu W, Wang L, Tian J, Sun X. Catal. Sci. Technol., 2011, 1: 1142.
[102] Liu B, Zhang D W, Wang J C, Chen C, Yang X L, Li C X. J. Phys. Chem. C, 2013, 117: 6363.
[103] Vestal C R, Zhang Z J. J. Am. Chem. Soc., 2002, 124: 14312.
[104] Wang Y, Teng X W, Wang J S, Yang H. Nano Lett., 2003, 3: 789.
[105] Yin Y Y, Chen M, Zhou S X, Wu L M. J. Mater. Chem., 2012, 22: 11245.
[106] Rahman Z U, Dong Y L, Su L, Ma Y H, Zhang H J, Chen X G. Chem. Eng. J., 2013, 222: 382.
[107] Wunder S, Polzer F, Lu Y, Mei Y, Ballauff M. J. Phys. Chem. C, 2010, 114 (19): 8814.
[108] Huang X, Liao X P, Shi B. Green Chem., 2011, 13: 2801.
[109] Zhou C J, Ren F, Wu W, Zhang S F, Xiao X H, Xu J X, Jiang C Z. J. Colloid Interf. Sci., 2012, 387(1): 47.
[110] Lai B H, Lin Y R, Chen D H. Chem. Eng. J., 2013, 223: 418.
[111] Huang H C, Barua S, Kay D B, Rege K, Simultaneous K. ACS Nano, 2009, 3: 2941.
[112] Liu Y C, Li M L, Chen G F. J. Mater. Chem. A, 2013, 1: 930.
[113] Zhang P, Shao C G, Li X H, Zhang M Y, Zhang X, Su C Y, Lu N, Wang K X, Liu Y C. Phys. Chem. Chem. Phys., 2013, 15: 10453.
[114] Xiao C F, Chen S M, Zhang L Y, Zhou S Q, Wu W T. Chem. Commun., 2012, 48: 11751.
[115] Yamamoto H, Yano H, Kouchi H, Obora Y, Arakawa R, Kawasaki H. Nanoscale, 2012, 4: 4148.
[116] Seo E, Kim J, Hong Y, Kim Y S, Lee D, Kim B S. J. Phys. Chem. C, 2013, 117: 11686.
[117] Nigra M M, Ha J M, Katz A. Catal. Sci. Technol., 2013, 3: 2976.
[118] Ke F, Zhu J F, Qiu L G, Jiang X. Chem. Commun., 2013, 49: 1267.
[119] Han L, Zhu C Z, Hu P, Dong S J. RSC Adv., 2013, 3: 12568.
[120] Chaudhuri R G, Paria S. Chem. Rev., 2012, 112: 2373.
[121] Lee I, Joo J B, Yin Y, Zaera F. Angew. Chem. Int. Ed., 2011, 50: 10208.
[122] Arnal P M, Comotti M, Schüth F. Angew. Chem. Int. Ed., 2006, 45: 8224.
[123] Lee J, Park J C, Song H. Adv. Mater., 2008, 20: 1523.
[124] Wang S N, Zhang M C, Zhang W Q. ACS Catal., 2011, 1(3): 207.
[125] Wu S H, Tseng C T, Lin Y S, Lin C H, Hung Y, Mou C Y. J. Mater. Chem., 2011, 21: 789.
[126] Wu X L, Tan L F, Chen D, He X L, Liu H Y, Meng X W, Tang F Q. Chem. Eur. J., 2012, 18: 15669.
[127] Guan B Y, Wang X, Xiao Y, Liu Y L, Huo Q S. Nanoscale, 2013, 5: 2469.
[128] Arnal P M, Comotti M, Schüth F. Angew. Chem. Int. Ed., 2006, 45: 8224.
[129] Wu S, Dzubiella J, Kaiser J, Drechsler M, Guo X H, Ballauff M, Lu Y. Angew. Chem. Int. Ed., 2012, 51(9): 2229.
[130] Liu B, Zhang W, Feng H L, Yang X L. Chem. Commun., 2011, 47: 11727.
[131] Lu W B, Ning R, Qin X Y, Zhang Y W, Chang G H, Liu S, Luo Y L, Sun X P. J. Hazard. Mater., 2011, 197: 320.
[132] Chen A, Qi J J, Zhao Q S, Li Y, Zhang G L, Zhang F B, Fan X B. RSC Adv., 2013, 3: 8973.
[133] Li J, Liu C Y, Liu Y. J. Mater. Chem., 2012, 22: 8426.
[134] MdRashid H, Bhattacharjee R R, Kotal A, Mandal T K. Langmuir, 2006, 22(17): 7141.
[135] Zhang Z Y, Shao C L, Zou P, Zhang P, Zhang M Y, Mu J B, Guo Z C, Li X H, Wang C H, Liu Y C. Chem. Commun., 2011, 47: 3906.
[136] Jin R X, Sun S L, Yang Y, Xing Y, Yu D H, Yu X D, Song S Y. Dalton Trans., 2013, 42: 7888.
/
| 〈 |
|
〉 |
PDF
(6827KB)
