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核壳结构金属-有机骨架的研究
Synthesis of Core-Shell Metal-Organic Frameworks
核壳结构（core-shell）金属-有机骨架（metal-organic frameworks，MOFs）是多功能MOFs复合材料中最为典型的一类构型，是由MOFs材料和另一种材料（如MOFs、碳材料、无机化合物、有机聚合物等）组装形成的核壳结构，其中MOFs既可作核，亦可作壳。因结合了核层和壳层两种材料，核壳结构MOFs展现出了优于核层或者壳层的独特性能，例如结构稳定、选择性分离、气体吸附等，为MOFs材料实现工业化应用带来了新的潜力。本文综述了近年来核壳结构MOFs材料的研究进展，介绍了各类构型核壳结构MOFs材料（例如MOF@MOF、MOF@carbon、metal oxide@MOF、polymer@MOF等）的合成方法及应用研究，并对其今后的发展进行了展望。
Core-shell metal-organic frameworks (MOFs) composed of MOFs as core (or shell) and another material, such as MOFs, carbon, inorganic compounds and organic polymers, as shell (or core), are a typical class of multifunctional MOFs composites. Because of the combination of the properties of core and shell materials, core-shell MOFs have better performances, such as increasing framework stability, selective separation and gas sorption, than the core or shell materials. Therefore, core-shell MOFs have high potentials for industrial applications. In this paper, the research progress of core-shell MOFs in recent years is reviewed. Synthesis methods and applications of variously structural core-shell MOFs, such as MOF@MOF, MOF@carbon, metal oxide@MOF, and polymer@MOF are introduced. Besides, the future development of core-shell MOFs is prospected.
Contents
1 Introduction
2 Synthesis methods and applications of variously structural core-shell MOFs
2.1 MOF@MOF
2.2 Core-shell structures of MOFs with carbon
2.3 Core-shell structures of MOFs with inorganic compounds
2.4 Core-shell structures of MOFs with organic polymers
3 Conclusion and outlook
金属-有机骨架
metal-organic frameworks (MOFs)
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