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对流层大气过氧自由基实地测量的技术进展及其在化学机理研究中的应用
李晓倩1, 陆克定2, 魏永杰1, 唐孝炎*2
化学进展 ›› 2014, Vol. 26 ›› Issue (04) :682-694
对流层大气过氧自由基实地测量的技术进展及其在化学机理研究中的应用
李晓倩1, 陆克定2, 魏永杰1, 唐孝炎*2
化学进展 ›› 2014, Vol. 26 ›› Issue (04) :682-694
对流层大气过氧自由基实地测量的技术进展及其在化学机理研究中的应用
Technique Progress and Chemical Mechanism Research of Tropospheric Peroxy Radical in Field Measurement
大气过氧自由基化学是对流层大气化学的重要组成部分，对于理解大气氧化性、光化学臭氧和二次有机气溶胶生成等核心科学问题具有重要意义。基于实地测量，准确掌握大气过氧自由基的浓度水平、进行相关化学行为分析以及实测结果模拟分析一直是大气过氧自由基化学研究的重点和难点。本文总结了大气过氧自由基实地测量的技术方法，回顾了涉及大气过氧自由基的大型实地观测实验，分析了已有观测实验中大气过氧自由基的浓度水平和差异，归纳了实地测量数据在化学机理研究中的应用，讨论了模拟分析实地测量结果中的主要科学发现。最后，提出该领域中尚存在的问题及可能的重点研究方向。
Peroxy radical chemistry is the main component of tropospheric chemistry, which is critical for the understanding of essential tropospheric issues such as atmospheric cleansing capacity, photochemical ozone production and secondary organic aerosol formations. Field measurements of peroxy radical concentrations and related analysis with observation based model are the prominent steps to foster the current understanding of peroxy radical chemistry. This paper reviews the state of measurement techniques for peroxy radical, extensively revisits the previous field studies with direct measurements of peroxy radical, outlins the peroxy radical concentrations reported in previous field observations, summarizes the tests of photochemical mechanism with direct field measurement results and discusses the major scientific findings achieved so far. Finally, an outlook for the new directions in the study of atmospheric peroxy radical chemistry is proposed.
Contents
1 Introduction
2 Measurement techniques of tropospheric peroxy radical
2.1 Matrix isolation electron spin resonance spectroscopy
2.2 Laser-induced florescence
2.3 Chemical amplification
2.4 Calibrations
3 Field measurement of peroxy radical
3.1 Field campaigns including peroxy radical measurement
3.2 Diurnal profiles and concentration levels of peroxy radical observed
4 Application of peroxy radical measurements in atmospheric chemical mechanism research
4.1 Peroxy radical chemical mechanism in background region
4.2 The response relationship between peroxy radical and NOx
4.3 The response relationship between peroxy radical and VOCs
4.4 Assessment of atmospheric chemical mechanism
5 Conclusions and outlook
peroxy radical
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