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乙醇电催化氧化
Electrocatalytic Oxidation of Ethanol
乙醇作为典型的可再生绿色环保型能源，具有易储存和携带、较高的能量密度、易生产等优点而备受关注。本文详细介绍了近年来国内外乙醇电催化氧化研究的重要进展，着重叙述了乙醇电催化氧化的反应机理，不同催化剂材料对乙醇电氧化的优缺点，进一步探讨了影响乙醇电氧化反应活性和选择性的因素，总结了提高乙醇电氧化活性和选择性的策略，最后，对其今后可能的研究方向进行了展望。
As a typically renewable environmental fuel, ethanol has numerous advantages, including easy to storage and production, and high energy density. Therefore, it attracts an extensive attention. In this review we detailedly introduced the significant progress on ethanol electrocatalytic oxidation in recent years. The thermodynamics process, reaction mechanism of ethanol electrooxidation, and the advantages and disadvantages of different electrocatalysts are emphatically described. Furthermore, the factors affecting the reaction activity and selectivity of ethanol electrooxidation, such as support, size, structure, alloy and additive, are discussed. Also, the strategy to enhance activity and selectivity of ethanol electrooxidation is summarized. In the end, we prospect the future of possible research direction of ethanol electrooxidation.
Contents
1 Introduction
2 Thermodynamics process and reaction mechanism of ethanol electrooxidation
2.1 Thermodynamics process
2.2 Reaction mechanism
3 Different kinds of electrocatalysts
3.1 Binary electrocatalysts
3.2 Ternary electrocatalysts
4 Factors affecting ethanol electrooxidation
4.1 Support effect
4.2 Size effect
4.3 Structure effect
4.4 Alloy effect
4.5 Additive effect
5 The strategy to enhance activity and selectivity of ethanol electrooxidation
6 Conclusions and outlook
乙醇燃料电池
direct ethanol fuel cell
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