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基于纤维素的气凝胶材料
Aerogel Materials Based on Cellulose
纤维素是自然界中储量最为丰富的一种天然高分子。作为继无机气凝胶和合成聚合物气凝胶之后的第三代气凝胶，纤维素基气凝胶材料兼具绿色可再生的纤维素材料和多孔气凝胶材料两者的优点，成为纤维素材料研究与应用中的一个热点。本文梳理了纤维素基气凝胶材料的发展脉络，综述了纤维素基气凝胶材料的研究进展。重点对纤维素基气凝胶的制备方法进行了总结，包括基于含水溶剂和无水溶剂的纤维素直接溶解法及源自植物纤维素和细菌纤维素的纤维素纳米纤维的水相分散法。介绍了纤维素基气凝胶力学性能的提高和功能性开发的最新研究结果。最后对纤维素基气凝胶材料的发展前景和研究方向进行了展望。
Cellulose, as the most abundant biopolymer in nature, has attracted extensive interest from both academia and industry in recent years due to its specific properties such as biocompatibility, biodegradability, thermal and chemical stability. Nowadays, cellulose aerogel, which possesses extremely low density, large open pores, and a high specific surface area, has become one of topical polymer materials that are based on this sustainable resource. The combination of the advantages and characteristics of the renewable biopolymer and highly porous material has made cellulose aerogel as the new generation succeeding the inorganic and synthetic polymer-based aerogel. In this review, recent research progress in cellulose aerogel materials is summarized based on about 70 relevant papers. The preparation of cellulose aerogel materials is mainly focused on the dissolving solvents of cellulose, including hydrous and anhydrous systems, and aqueous dispersion media of cellulose nanofibers, which are separated from native lignocellulose biomass and bacterial cellulose. The recent development to enhance the mechanical properties of cellulose aerogel by improving the strength of solid network via addition of inorganic components, is described, along with that to introduce functionality (hydrophobicity, superoleophobicity, electrical and magnetic properties, etc.) in cellulose aerogel. Finally, a perspective on the cellulose aerogel materials and the research directions in the future is briefly discussed.
Contents
1 Introduction
2 Preparation of cellulose aerogels
2.1 Dissolution of cellulose by non-derivative solvents
2.2 Dispersion of cellulose nanofibers in water
3 Modification of cellulose aerogels
3.1 Enhancement of mechanical properties
3.2 Modification of hydrophobicity and oleophobicity
3.3 Electrical and magnetic functionalization
3.4 Loading of active compounds on aerogels
4 Perspective
cellulose
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