卤代有机污染物的光化学降解

张峰振; 吴超飞; 胡芸; 韦朝海

doi:10.7536/PC131134

化学进展 ›› 2014, Vol. 26 ›› Issue (06) :1079-1098 DOI: 10.7536/PC131134

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卤代有机污染物的光化学降解

张峰振, 吴超飞, 胡芸, 韦朝海*

作者信息 +

Photochemical Degradation of Halogenated Organic Contaminants

Zhang Fengzhen, Wu Chaofei, Hu Yun, Wei Chaohai*

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摘要

包括全氟或部分氟代化合物（PFCs）、氯代有机物（COCs）以及溴代有机物（BOCs）等的卤代有机污染物（halogenated organic contaminants，HOCs）排放到环境中会表现出持久性有机污染物的特征，因此涉及HOCs性质、光吸收与量子效应、材料与界面特性、环境条件等方面优化的光化学清除方法成为一个重要的研究方向。基于此，本文归纳分析了光激发催化剂产生活性物种如h_VB⁺、e_CB^-、 ·OH、e_aq^-等氧化或还原全氟辛酸、多氯联苯、多溴联苯醚的反应机理及直接光解机理，指出HOCs的光化学降解主要是通过其与活性物种之间电子转移或其激发态光致还原脱卤来实现，认为光催化材料和反应过程优化设计是影响光催化降解HOCs的重要因素。基于目前已经取得的研究发现与成果，从界面电子转移、材料能带信息、反应与分离集成化等方面提出本领域未来学术与技术层面值得深入探索的关键问题。

Abstract

Halogenated organic contaminants (HOCs), including perfluorinated or partially fluorinated chemicals (PFCs), chlorinated organic compounds (COCs) and brominated organic compounds (BOCs), show the characteristics of persistent organic pollutants after they are discharged into the environment. Optimized photochemical elimination methods, which involve the pollutant properties, light adsorption and quantum yield, interfacial interaction and environmental conditions, are promising techniques for controlling the potential risk of HOCs. The present review summarizes the mechanisms of photocatalytic degradation of perfluorooctanoic acid (PFOA), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) by photo-generated radical species (eg, h_VB⁺, e_CB^-, ·OH, e_aq^-) on photocatalyst as well as the mechanisms of direct photolysis. The photochemical degradation of HOCs can be achieved through the electron transfer between HOCs and reactive radical species or photo-induced reduction from the excited state of HOCs. Optimazation designs of photocatalyst and reaction process are important factors for the photocatalytic degradation of HOCs. Based on the currently achieved research results, some key issuses for the future are proposed from some aspects such as the interfacial electron transfer, the information of band structure, and the integration of reaction and separation.

Contents
1 Introduction
2 The mechanisms of photochemical degradation of HOCs
2.1 The photocatalytic degradation of HOCs
2.2 The direct photolysis of HOCs
3 Influencing factors on photocatalytic degradation of HOCs
3.1 Effect of photocatalytic materials
3.2 Effect of reaction condition
4 Conclusions

Graphical abstract

关键词

卤代有机污染物 / 光催化 / 直接光解 / 羟基自由基 / 水合电子

Key words

halogenated organic contaminants / photocatalysis / direct photolysis / hydroxyl radical / hydrated electron

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张峰振, 吴超飞, 胡芸, 韦朝海. 卤代有机污染物的光化学降解[J]. 化学进展, 2014, 26(06): 1079-1098 DOI:10.7536/PC131134

Zhang Fengzhen, Wu Chaofei, Hu Yun, Wei Chaohai. Photochemical Degradation of Halogenated Organic Contaminants[J]. Progress in Chemistry, 2014, 26(06): 1079-1098 DOI:10.7536/PC131134

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