锂单离子导电固态聚合物电解质

张恒; 郑丽萍; 聂进; 黄学杰; 周志彬

doi:10.7536/PC131233

化学进展 ›› 2014, Vol. 26 ›› Issue (06) :1005-1020 DOI: 10.7536/PC131233

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锂单离子导电固态聚合物电解质

作者信息 +

Single Lithium-Ion Conducting Solid Polymer Electrolytes

Zhang Heng¹, Zheng Liping¹, Nie Jin¹, Huang Xuejie², Zhou Zhibin*¹

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摘要

锂单离子导电固态聚合物电解质是一类锂离子迁移数接近1的锂离子导体，可以有效避免阴离子移动产生浓差极化，从而提高锂电池的容量以及循环性能，成为近年来固态聚合物电解质的研究热点。本文综述了锂单离子导电固态聚合物电解质的研究进展，重点关注了电导率和锂离子迁移数较高的体系，并简要评述了锂单离子导电固态聚合物电解质所面临的挑战以及发展前景。

Abstract

Single lithium-ion conductors (SLICs), which have anions covalently bonded to polymers or immobilized by anion acceptors, have been intensively studied. SLICs are generally accepted to have advantages over conventional salt-in-polymer electrolytes for application in lithium batteries due to the unity transference number and the absence of detrimental effect of anion polarization. By now, many types of SLICs have been reported, including organic polymers, organic-inorganic hybrid polymers and anion acceptors. In this paper, progresses in SLICs are reviewed, which mainly focused on their electrochemical properties, especially those with high ionic conductivity and high lithium-ion transference number. The current challenges and future perspectives in this field are also prospected.

Contents
1 Introduction
2 Organic polymer-based single lithium-ion con-ductors
2.1 Single lithium-ion conductors based on lithium salts of ionomer without ion conduction matrix
2.2 Single lithium-ion conductors based on lithium salts of ionomer with ion conduction matrix
3 Organic-inorganic hybrid polymers
3.1 The siloxane-based single lithium-ion conductors
3.2 The aluminate and borate-based hybrid polymers
4 Anion acceptor
4.1 Lewis acid-based anion acceptor
4.2 Calixarene and their derivatives
5 Conclusions and outlook

Graphical abstract

关键词

锂电池 / 固态聚合物电解质 / 锂单离子导体 / 锂离子迁移数

Key words

lithium battery / solid polymer electrolyte / single lithium-ion conductor / lithium-ion transference number

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张恒, 郑丽萍, 聂进, 黄学杰, 周志彬. 锂单离子导电固态聚合物电解质[J]. 化学进展, 2014, 26(06): 1005-1020 DOI:10.7536/PC131233

Zhang Heng, Zheng Liping, Nie Jin, Huang Xuejie, Zhou Zhibin. Single Lithium-Ion Conducting Solid Polymer Electrolytes[J]. Progress in Chemistry, 2014, 26(06): 1005-1020 DOI:10.7536/PC131233

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