混晶TiO2光催化剂的制备及机理研究

解英娟; 吴志娇; 张晓; 马佩军; 朴玲钰

doi:10.7536/PC140124

化学进展 ›› 2014, Vol. 26 ›› Issue (07) :1120-1131 DOI: 10.7536/PC140124

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混晶TiO₂光催化剂的制备及机理研究

^1,2

⁴

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Synthesis and Photocatalytic Mechanisms of the Mixed-Phase TiO₂ Photocatalysts

Xie Yingjuan^1,2, Wu Zhijiao¹, Zhang Xiao³, Ma Peijun⁴, Piao Lingyu*¹

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摘要

本文总结了混晶TiO₂光催化剂的各种制备方法，并将其分为两大类：一类是原位生成混晶，如水热法、溶剂热法、溶胶-凝胶法、微乳液-水热联用方法等；另一类是对两种晶型TiO₂材料进行物理混合或对锐钛矿进行高温煅烧，如溶剂混合-煅烧法、高温煅烧法等。其中，后者操作简单易行、对设备要求不高，但获得的混晶TiO₂易产生硬团聚，严重影响其光催化性能；在实际应用中前者制备的TiO₂材料更具优势。同时，本文还对混晶TiO₂光催化机理的研究历程进行了总结，并对其中存在的争议进行了评述。最后，展望了混晶TiO₂光催化剂在环境和能源领域中的应用。

Abstract

This review summarizes the preparation methods of mixed-phase TiO₂ photocatalysts. Two main lines of fabrication have been followed: one is preparation of mixed-phase TiO₂ in situ (e. g. hydrothermal method, solvothermal method, sol-gel method and microemulsion-mediated hydrothermal method, etc.), and the other is physical mixing of different phases of TiO₂ or calcinations under high temperature (e. g. solvent mixing and calcination treatment, calcination under high temperature, etc.). The latter has fewer requirements on the equipments, but the produced TiO₂ nanoparticles tend to be aggregates, which affects the photocatalytic performance of TiO₂ materials seriously. The former has more advantages in practical applications. At the same time, this review summarizes and remarks the researches on photocatalytic mechanisms of the mixed-phase TiO₂. Furthermore, the applications of the mixed-phase TiO₂ photocatalysts in environmental and energy fields are also prospected.

Contents
1 Introduction
2 Synthesis of the mixed-phase TiO₂ photocatalysts
2.1 Phases of TiO₂
2.2 Methods of preparing the mixed-phase TiO₂ photocatalysts and their influencing factors
3 Mechanisms of the enhanced photocatalytic activities by the mixed-phase TiO₂ photocatalysts
4 Conclusion and outlook

Graphical abstract

关键词

TiO₂ / 混晶 / 混晶比 / 光催化机理

Key words

TiO₂ / mixed-phase / ratio of mixed-phase / photocatalytic mechanisms

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解英娟, 吴志娇, 张晓, 马佩军, 朴玲钰. 混晶TiO₂光催化剂的制备及机理研究[J]. 化学进展, 2014, 26(07): 1120-1131 DOI:10.7536/PC140124

Xie Yingjuan, Wu Zhijiao, Zhang Xiao, Ma Peijun, Piao Lingyu. Synthesis and Photocatalytic Mechanisms of the Mixed-Phase TiO₂ Photocatalysts[J]. Progress in Chemistry, 2014, 26(07): 1120-1131 DOI:10.7536/PC140124

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