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苯并[1,2-b：4,5-b’]二噻吩的结构修饰及在有机光伏材料中的应用
Structural Modification of Benzo [1,2-b：4,5-b’] dithiophene and Application in Organic Photovoltaic Materials
近年来，苯并[1，2-b：4，5-b’]二噻吩吩（benzo[1，2-b：4，5-b’]dithiophene，BDT）作为构筑给体-受体结构有机半导体材料的优良电子给体，受到越来越多的重视，已广泛应用于场效应晶体管和有机光伏电池等领域。BDT类有机共轭材料具有优良的能级结构，同时又具有较高的载流子迁移率，目前报道的基于BDT的有机共轭聚合物的最高光电转换效率达到9.2% （单节光伏器件的最高效率），显示了其在有机太阳能电池领域巨大的应用前景。本文从BDT的结构修饰出发，系统地综述了基于BDT的有机光伏材料的最新研究进展，重点讨论BDT类光伏材料能级结构和聚集态形貌对光电性能的影响。
In recent years, benzo[1,2-b:4,5-b']dithiophene (BDT) has been receiving considerable attentions as the excellent electron-donating unit for constructing donor-acceptor structured organic semiconductors.It has been widely used in organic thin film transistors and organic photovoltaics. BDT-based conjugated polymeric materials possess favorable energy levels and band gaps, along with high carrier mobilities. Power conversion efficiencies of up to 9.2%(the best value reported for single junction organic solar cells) have been achieved for OPVs using BDT-based polymers, demonstrating their potential applications in the organic solar cells. In this paper, beginning with the structural modification of BDT, the latest research advances of organic photovoltaic materials based on BDT are reviewed, and the influence of energy levels and morphology on optoelectronic properties is intensively discussed.
Contents
1 Introduction
2 BDT-based copolymers
2.1 4, 8-Position connect with alkyl and alkoxy group
2.2 4, 8-Position connect with alkyne and aromatic group
2.3 Conjugate plane expansion
3 BDT-based small molecules
4 Conclusions and outlook
苯并[1,2-b：4,5-b’]二噻吩
benzo[1,2-b：4,5-b’]dithiophene
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