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功能离子液体杂化固相纳米材料的制备及催化应用
Preparation and Catalytic Application of Task-Specific Ionic Liquid Hybrid Solid-Phase Nano Materials
离子液体是一种新颖的软功能材料，它既可以作为催化反应的绿色介质，也可以作为催化反应的活性组分，还可以作为一种客体的催化功能分子来修饰一些固相纳米材料。本文主要立足于多相催化材料的设计合成和应用的角度，结合近几年来一些新颖的固相纳米材料，系统地综述了功能离子液体对这些固相材料的杂化方法及其在催化应用中表现出的一些独特的催化性能。最后，对功能离子液体杂化固相纳米材料的研究现状进行了总结，并对将来可能的发展方向进行了展望。
Ionic liquids, as novel soft functional materials, can serve as green solvent and active center in catalytic reaction. Meanwhile, it can be used as a catalytically functional molecule to decorate other solid nano materials. In this paper, the concept toward task-specific ionic liquid (TSILs) hybrid solid nano materials and new catalytic performance are systematically reviewed from the perspective of design,synthesis and application of heterogeneous catalytic materials. Finally, we summarized state of the art and made an outlook about TSILs hybrid solid nano materials.
Contents
1 Introduction
2 TSILs hybrid silica-based inorganic materials
2.1 Confining TSILs by physical absorption
2.2 Anchoring TSILs by covalent attachment
3 TSILs hybrid magnetic nano materials
4 TSILs hybrid organic polymers
5 TSILs hybrid carbon-based nano materials
6 TSILs hybrid metal-organic frameworks (MOFs) materials
7 Conclusion and outlook
task-specific ionic liquid
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