中文 |
English |
Email Alert
质子交换膜燃料电池有序化膜电极
刘锋1,2, 王诚*2, 张剑波3, 兰爱东*1, 李建秋3, 欧阳明高3
化学进展 ›› 2014, Vol. 26 ›› Issue (11) :1763-1771
质子交换膜燃料电池有序化膜电极
刘锋1,2, 王诚*2, 张剑波3, 兰爱东*1, 李建秋3, 欧阳明高3
化学进展 ›› 2014, Vol. 26 ›› Issue (11) :1763-1771
质子交换膜燃料电池有序化膜电极
Ordered Membrane Electrode Assembly of Proton Exchange Membrane Fuel Cell
质子交换膜燃料电池的核心部件——膜电极经历了两代传统制备方法后,已经进入第三代有序化膜电极发展阶段.有序化膜电极包括质子导体有序化膜电极和电子导体有序化膜电极两大类,而电子导体有序化膜电极包括催化剂材料有序化膜电极和催化剂载体材料有序化膜电极.有序化膜电极具有良好的电子、质子、水和气体等多相物质传输通道,从而可以大大降低膜电极中Pt载量、提升燃料电池的发电性能和延长燃料电池寿命.本文整理了近几年有关有序化膜电极的研究报道,梳理了有序化膜电极研究进展,归纳比较了各种有序化膜电极制备方法的优缺点,对未来高性能、低成本和长寿命的膜电极制备技术开发具有指导意义.
After two traditional manufacturing methods of key component——membrane electrode assemblies (MEA), the third generation ordered MEA has attracted great research interests in proton exchange membrane fuel cell. Ordered MEA could be divided into two kinds: MEA based on ordered proton transportation materials (e.g.nanowires, nanotubes, nanofibers of Nafion or other proton transportation materials) and MEA based on ordered electron transportation materials. However, ordered electron transportation MEA includes MEA based on ordered catalyst (e.g.Pt nanowires or other metal catalyst nanowires) and MEA based on ordered catalyst support such as carbon nanotube and carbon nanofibers. Electrode structure ordering is critical for decreasing Pt loading of the MEA, improving power performance and durability of fuel cell due to good multiphase mass transmission channels(e.g.proton, electron, gas and water transmission channels). Ordered MEAs and their manufacturing methods are reviwed in the paper based on the latest research literatures and patents recent years, and their characteristics and difference are analyzed in detail, which has guiding significance for high performance, low cost and longlife MEA.
Contents
1 Introduction
2 Previous attempts of the ordered MEA
2.1 Introduce of ordered catalyst support
2.2 Introduce of catalyst nanowire
2.3 Introduce of high proton transportation nanofiber
3 The third generation ordered MEA
3.1 MEA based on ordered catalyst support
3.2 MEA based on ordered catalyst
3.3 MEA based on ordered proton transportation materials
4 Conclusion and outlook
质子交换膜燃料电池
proton exchange membrane fuel cell(PEMFC)
[1] 衣宝廉(Yi B L). 燃料电池——原理·技术·应用(Fuel Cell——Principle, Technology and Application). 北京: 化学工业出版社(Beijing: Chemical Industry Press), 2003.
[2] U. S. DRIVE Partnership. Fuel Cell Technical Team Roadmap, (2013-06).-06-01]. http://energy.gov/sites/prod/files/2014/02/f8/fctt_roadmap_june2013.pdf.
[3] 舒婷(Shu T). 华南理工大学博士论文(Doctoral Dissertation of South China University of Technology), 2013.
[4] Srinivasan S, Ticianelli E A, Derouin C R, Redondo A. J. Power Sources, 1988, 22(3/4): 359.
[5] Ticianelli E A, Derouin C R, Redondo A, Srinivasan S. J. Electrochem. Soc., 1988, 135(9): 2209.
[6] Ticianelli E, Derouin C, Srinivasan S. J. Electroanal. Chem. Interfacial Electrochem., 1988, 251(2): 275.
[7] Lindstrom R W. US 4647359, 1987.
[8] Sompalli B, Gasteiger H, Mathias M F, Scozzafava M. US 6524736-A, 2000.
[9] Fukuda K, Tani M, Kaji H, Inai S, Muro T, Watanabe S, Tada T, Inoue M. US 6847518-B2, 2005.
[10] Yan S G, Yan S. US 6933003, 2002.
[11] Yan SG, Doyle J C. US 7955758-B2, 2004.
[12] Zhou J, Zhou X. Journal of Applied Physics, 2013, 113(23): 234901.
[13] Mezalira D Z, Bron M. Journal of Power Sources, 2013, 231: 113.
[14] Wang C, Waje M, Wang X, Tang J M, Haddon R C, Yan Y S. Nano Lett., 2004, 4(2): 345.
[15] Lee S W, Kim B, Chen S, Shao-Horn Y, Hammond P T. J. Am. Chem. Soc., 2009, 131(2): 671.
[16] Wang Q, Wang X, Chai Z, Hu W. Chem. Soc. Rev., 2013, 42(23): 8821.
[17] Waje M M, Li W Z, Chen Z W, Yan Y S. ECS Transactions, 2006, 3 (1): 677.
[18] Waje M M, Li W Z, Chen Z W, Yan Y S. ECS Transactions, 2006, 3 (1): 285.
[19] Zhu W, Ku D, Zheng J P, Liang Z, Wang B, Zhang C, Walsh S, Au G, Plichta E J. Electrochimica Acta, 2010, 55(7): 2555.
[20] Zhu W, Zheng J P, Liang R, Wang B, Zhang C, Au G, Plichta E J. Journal of the Electrochemical Society, 2009, 156(9): B1099.
[21] Zhu W, Zeng C, Zheng J P, Liang R, Zhang C, Wang B. Electrochemical and Solid-State Letters, 2011, 14(8): B81.
[22] Kannan A M, Veedu V P, Munukutla L, Ghasemi-Nejhad M N. Electrochemical and Solid-State Letters, 2007, 10(3): B47.
[23] Zhang C, Yu H, Li Y, Gao Y, Zhao Y, Song W, Shao Z, Yi B. ChemSusChem, 2013, 6(4): 659.
[24] Wang R, Higgins D C, Hoque M A, Lee D, Hassan F, Chen Z. Scientific Reports, 2013, 3: 2431.
[25] Yao X, Su K, Sui S, Mao L, He A, Zhang J, Du S. International Journal of Hydrogen Energy, 2013, 38(28): 12374.
[26] Su K, Sui S, Yao X, Wei Z, Zhang J, Du S. International Journal of Hydrogen Energy, 2014, 39(7): 3397.
[27] Su K, Yao X, Sui S, Wei Z, Zhang J, Du S. International Journal of Hydrogen Energy, 2014, 39(7): 3219.
[28] Liang H, Cao X, Zhou F, Cui C, Zhang W, Yu S. Advanced Materials, 2011, 23(12): 1467.
[29] Kim H J, Kim Y S, Seo M H, Choi S M, Kim W B. Electrochemistry Communications, 2009, 11(2): 446.
[30] Shimizu W, Okada K, Fujita Y, Zhao S, Murakami Y. Journal of Power Sources, 2012, 205: 24.
[31] Alia S M, Jensen K, Contreras C, Garzon F, Pivovar B, Yan Y. ACS Catalysis, 2013, 3(3): 358.
[32] Alia S M, Jensen K O, Pivovar B S, Yan Y. ACS Catalysis, 2012, 2(5): 858.
[33] Yan Y, Chen Z, Wisan Y, Jungwei C. US 2009220835-A1, 2009.
[34] Alexandrovichserov A, Kwak C, Lee S, Alexey A, Lee S H, Alessandro V A, Guo C. US 2007212592-A1, 2007.
[35] Niu C, Bock L A, Chow C Y H, Empedocles S A, Parce J W, Bock L, Chow C, Empedocles S, Parce J, Bork L A, Empidochris S A, Joe C Y H, New C. US 2006188774-A1, 2008
[36] Choi J, Lee K M, Wycisk R, Pintauro P N, Mather P T. ECS Transactions, 2008, 16(2): 1433.
[37] Choi J, Lee K M, Wycisk R, Pintauro P N, Mather P T. Macromolecules, 2008, 41(13): 4569.
[38] Choi J, Lee K M, Wycisk R, Pintauro P N, Mather P T. Journal of Materials Chemistry, 2010, 20(30): 6282.
[39] Tamura T, Kawakami H. Nano Letters, 2010, 10(4): 1324.
[40] Nah C, Kwak S K, Kim N, Lyu M Y, Hwang B S, Akle B, Leo D J. Key Engineering Materials, 2007, 334/335: 1001.
[41] Chen H, Snyder J D, Elabd Y A. Macromolecules, 2008, 41(1): 128.
[42] Chen L, Tao H L, Li J R, Pan M. International Journal of Energy Research, 2013, 37(8): 879.
[43] Yamamoto D, Munakata H, Kanamura K. Journal of the Electrochemical Society, 2008, 155(3): B303.
[44] Li W, Wang X, Chen Z, Waje M, Yan Y. Langmuir, 2005, 21(21): 9386.
[45] Caillard A, Charles C, Boswell R, Brault P. Journal of Physics D: Applied Physics, 2008, 41(18): 185307.
[46] Middelman E. Fuel Cells Bulletin, 2002, 2002(11): 9.
[47] Hussain M M, Song D, Liu Z S, Xie Z. Journal of Power Sources, 2011, 196(10): 4533.
[48] Du C Y, Cheng X Q, Yang T, Yin G P, Shi P F. Electrochemistry Communications, 2005, 7(12): 1411.
[49] Du C Y, Yang T, Shi P F, Yin G P, Cheng X Q. Electrochimica Acta, 2006, 51(23): 4934.
[50] Chisaka M, Daiguji H. Electrochemistry Communications, 2006, 8(8): 1304.
[51] Hatanka T, Nakanishi H, Matsumoto S, Morimoto Y. ECS Transactions, 2006, 3 (1): 277.
[52] Tian Z Q, Lim S H, Poh C K, Tang Z, Xia Z, Luo Z, Shen P K, Chua D, Feng Y P, Shen Z, Lin J. Advanced Energy Materials, 2011, 1(6): 1205.
[53] Zhang W, Chen J, Minett A I, Swiegers G F, Too C O, Wallace G G. Chemical Communications, 2010, 46(26): 4824.
[54] Murata S, Imanishi M, Hasegawa S, Namba R. Journal of Power Sources, 2014, 253: 104.
[55] Zhang W, Minett A I, Gao M, Zhao J, Razal J M, Wallace G G, Romeo T, Chen J. Advanced Energy Materials, 2011, 1(4): 671.
[56] Zheng M, Li P, Fu G, Chen Y, Zhou Y, Tang Y, Lu T. Applied Catalysis B: Environmental, 2013, 129: 394.
[57] Yang J, Liu D. Carbon, 2007, 45(14): 2845.
[58] Rao S M, Xing Y. Journal of Power Sources, 2008, 185(2): 1094.
[59] Lv H, Ma J, Qiao J, Wang J, Yang D, Zhang C, Zheng J. CN 101515648, 2009.
[60] Meng Y, Jiang Z, Yu X. CN 102157741, 2011.
[61] Sun G. CN 102881925-A, 2013.
[62] Debe M K, Hendricks S M, Vernstrom G D, Meyers M, Brostrom M, Stephens M, Chan Q, Willey J, Hamden M, Mittelsteadt C K, Capuano C B, Ayers K E, Anderson E B. Journal of the Electrochemical Society, 2012, 159(6): K165.
[63] Debe M K, Atanasoski R T, Steinbach A J. The Electrochemical Society Transactions, 2011, 41 (1): 937.
[64] Ziegler R J, Thomas J H, Debe M K, Haugen G M, Steinbach A J, Debe K, Haugen M, Steinbach J, Thomas H, Ziegler J. US 5879827-A, 1999.
[65] Debe M K, Ziegler R J, Hendricks S M, Debe M, Ziegler R, Henfricks S. US 2008020923-A1, 2008.
[66] Debe M K, Schmoeckel A K, Vernstrom G D, Atanasoski R. Journal of Power Sources, 2006, 161(2): 1002.
[67] 张敏(Zhang M), 李经建(Li J J), 潘牧(Pan M), 徐东升(Xu D S). 物理化学学报(Acta Physico-Chimica Sinica), 2011, (7): 1685.
[68] Du S. Journal of Power Sources, 2010, 195(1): 289.
[69] Du S, Millington B, Pollet B G. International Journal of Hydrogen Energy, 2011, 36(7): 4386.
[70] Du S, Pollet B G. International Journal of Hydrogen Energy, 2012, 37(23): 17892.
[71] Pan C, Wu H, Wang C, Wang B, Zhang L, Cheng Z, Hu P, Pan W, Zhou Z, Yang X, Zhu J. Advanced Materials, 2008, 20(9): 1644.
[72] Lu Z, Pan C F, Jing Z. Chinese Physics Letters, 2008, 25(8): 3056.
[73] Pan C F, Zhang L, Zhu J, Luo J, Cheng Z D, Wang C. Nanotechnology, 2007, 18: 0153021.
[74] 潘曹峰(Pan C F). 清华大学博士论文(Doctoral Dissertation of Tsinghua University), 2010.
[75] Dong B, Gwee L, Salas-De La Cruz D, Winey K I, Elabd Y A. Nano Letters, 2010, 10(9): 3785.
[76] Debe M K. 3M, (2011-05-10).-06-01]. http://www.hydrogen.energy.gov/pdfs/review11/fc001_debe_2011_o.pdf.
/
| 〈 |
|
〉 |
PDF
(883KB)
