车用燃料电池耐久性研究

王诚; 王树博; 张剑波; 李建秋; 王建龙; 欧阳明高

doi:10.7536/PC140807

化学进展 ›› 2015, Vol. 27 ›› Issue (4) :424-435 DOI: 10.7536/PC140807

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车用燃料电池耐久性研究

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The Durability Research on the Proton Exchange Membrane Fuel Cell for Automobile Application

Wang Cheng*¹, Wang Shubo¹, Zhang Jianbo², Li Jianqiu², Wang Jianlong¹, Yang Minggao²

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摘要

经过世界范围内近十年的持续研发,车用燃料电池在能量效率、体积与质量功率密度、低温启动等功能特性方面已经取得了突破性进展,新一轮的燃料电池汽车产业化浪潮正在迫近。然而,燃料电池的耐久性仍没达到商业化目标,且耐久性问题涉及面广、挑战大,成为当前燃料电池汽车产业化的主要棘手问题,构成了车用燃料电池在车辆技术方面产业化的最后障碍。车用燃料电池的耐久性已经引起了世界各国研究人员的广泛关注,本文归纳分析了车用燃料电池催化剂及其载体、质子交换膜及电极离子导体、气体扩散层、金属双极板等关键材料及部件的性能衰减机制,以及梳理了应对性能衰减的新材料、新技术与系统控制策略等耐久性最新研究进展,最后对车用燃料电池失效机制及其缓解研究提出了新的方向,以期对认识和提升燃料电池耐久性具有指导和借鉴意义。

Abstract

Through over a decade continuous research and development all over the world, the performances of proton exchange membrane fuel cell (PEMFC) for automobile application, such as energy efficiency, power density and specific power of the stack, and the system with low-temperature startup, have achieved breakthrough progress. A new round of fuel cell automobile commercialization now has been approaching. However, the durability of the automobile PEMFC systems, which include massive scale of problems, hasnt met the commercialization target. The durability is the primary problem of vehicle fuel cell commercialization and become the ultimate obstacle of the fuel cell industrialization in the field of automobile application. The problem of durability for automobile PEMFC application has attracted lots of attention worldwide. In this paper, the degradation mechanics of key materials and components in the PEMFC, including catalyst, support material, proton exchange membrane, ionomer in catalyst layer, gas diffusion layer and metal bipolar plate, have been summarized and analyzed in detail. Meanwhile the mitigation strategies for the degradations are also summarized and some novel strategies for durability mitigation are proposed. This paper is instructive for the understanding and promotion of the durability for the PEMFC.

Contents
1 Introduction
2 The degradation of proton exchange membrane fuel cell
2.1 The degradation mechanism of Pt catalyst
2.2 The degradation mechanism of carbon support for catalyst
2.3 The degradation of proton exchange membrane and electrode ionomer
2.4 The degradation of gas diffusion layer
2.5 The degradation of metal bipolar plate
3 The mitigation strategy for degradation
3.1 The mitigation of Pt degradation
3.2 The mitigation of carbon degradation
3.3 The mitigation of proton exchange membrane degradation
3.4 The mitigation of gas diffusion layer degradation
3.5 The mitigation of bipolar plate degradation
4 Conclusion

Graphical abstract

关键词

氢能 / 电动汽车 / 燃料电池 / 耐久性 / 失效 / 缓解策略

Key words

hydrogen energy / electric automobile / fuel cell / durability / degradation / mitigation strategy

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王诚, 王树博, 张剑波, 李建秋, 王建龙, 欧阳明高. 车用燃料电池耐久性研究[J]. 化学进展, 2015, 27(4): 424-435 DOI:10.7536/PC140807

Wang Cheng, Wang Shubo, Zhang Jianbo, Li Jianqiu, Wang Jianlong, Yang Minggao. The Durability Research on the Proton Exchange Membrane Fuel Cell for Automobile Application[J]. Progress in Chemistry, 2015, 27(4): 424-435 DOI:10.7536/PC140807

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原文顺序 | 出版日期 | 本文引用

[1] (a)欧阳明高(OuYang M G). 内燃机学报(Transactions of CSICE), 2008, 26:107.;(b)Sung W, Song Y, Yu K, Lim T.SAE Int.J.Engines,2010,3(1): 768.; (c)Yokoyama T.California Air Resources Board ZEV Symposium, Sacramento C A, Sep., 2009.21.;(d)李建秋(Li J Q),方川(Fang C),徐梁飞(Xu L F).汽车安全与节能学报(Journal of Automotive Safety and Energy),2014,5(1):17.;(e)Jones D J. Global Change,Energy Issues and Regulation Policies.Netherlands:Springer,2013:161.;(f)The Fuel Cell Technical Team.Fuel Cell Technical Team Roadmap,Washington:DOE,June 2013.;(g)Matthew M.Polymer Electrolyte Fuel Cell Degradation.Dutch:Elsevier,2011.112.
[2] Pei P C, Chen H C. Applied Energy, 2014, 125: 60.
[3] Wilson M S, Garzon F H, Sickafus K E, Gottesfeld S. J. Electrochem. Soc., 1993, 140: 2872.
[4] Ferreira P J, la O’ G J, Shao-Horn Y, Morgan D, Makharia R, Kocha S, Gasteiger H A. J. Electrochem. Soc., 2005, 152: A2256.
[5] Shao Y, Yin G, Gao Y. J. Power Sources, 2007, 171: 558.
[6] Zhu W, Zheng J P, Liang R, Wang B, Zhang C, Au G, Plichta E J. J. Electrochem. Soc., 2009, 156 (9): B1099.
[7] Darling R M, Meyers J P. J. Electrochem. Soc., 2003, 150 (11): A1523.
[8] Darling R M, Meyers J P. J. Electrochem. Soc., 2005, 152 (1): A242.
[9] Pourbaix M. National Association of Corrosion Engineers, 1979. 453.
[10] Maass S, Finsterwalder F, Frank G, Hartmann R, Merten C. J. Power Sources, 2008, 176: 444.
[11] Makharia R, Kocha S S, Yu P T, Sweikart M A, Gu W, Wagner F T, Gasteiger H A. ECS Transactions, 2006, 1(8): 3.
[12] Liu Z Y, Zhang J L, Yu P T, Zhang J X, Makharia R, More K L, Stachc E A. J. Electrochem. Soc., 2010, 157 (6): B906.
[13] Kinoshita K, Bett J. Carbon, 1973, 11: 237.
[14] Roen L M, Paik C H, Jarvi T D. Electrochem. Solid-State Lett., 2004, 7 (1): A19.
[15] Li W, Lane A M. Electrochim. Acta, 2010, 55: 6926.
[16] Taniguchi A, Akita T, Yasuda K, Miyazaki Y. J. Power Sources, 2004, 130: 42.
[17] 王丽娜(Wang L N), 刘向(Liu X), 张伟(Zhang W), 张新荣(Zhang X R), 孙毅(Sun Y), 蒋永伟(Jiang Y W), 朱荣杰(Zhu R J). 第30届全国化学与物理电源学术年会论文集(Proceeding of 30^th Annual Meeting on Power Sources). 上海(Shanghai), 2013. 467.
[18] Chen J, Siegel J B, Matsuura T, Stefanopoulou A G. J. Electrochem. Soc., 2011,158 (9): B1164.
[19] Reiser C A, Bregoli L, Patterson T W, Yi J S, Yang J D, Perry M L, Jarvi T D. Electrochem. Solid-State Lett., 2005, 8 (6): A273.
[20] Dross R, Maynard B. ECS Trans., 2007, 11 (1): 1059.
[21] Tang H, Qi Z, Ramani M, Elter J F. J. Power Sources, 2006, 158: 1306.
[22] Carter R N, Brady B K, Subramanian K, Tighe T, Gasteiger H A. ECS Trans., 2007, 11 (1): 423.
[23] Young A P, Stumper J, Gyenge E. J. Electrochem. Soc., 2009, 156 (8): B913.
[24] Borup R, Meyers J, Pivovar B, Kim Y S, Mukundan R, Garland N, Myers D, Wilson M, Garzon F, Wood D, Zelenay P, More K, Stroh K, Zawodzinski T, Boncella J, McGrath J E, Inaba M, Miyatake K, Hori M, Ota K, Ogumi Z, Miyata S, Nishikata A, Siroma Z, Uchimoto Y, Yasuda K, Kimijima K, Iwashita N. Chem. Rev., 2007, 107: 3904.
[25] Jo Y Y, Cho E, Kim J H, Lim T H, Oh I H, Kim S K, Kim H J, Jang J H. J. Power Sources, 2011, 196: 9906.
[26] Fairweather J D, Spernjak D, Weber A Z, Harvey D, Wessel S, Hussey D S, Jacobson D L, Artyushkova K, Mukundan R, Borup R L. J. Electrochem. Soc., 2013, 160(9): F980.
[27] De Bruijn F A, Dam V A T, Janssen G J M. Fuel Cells, 2008, 8(2): 3.
[28] Huang C, Tan K S, Lin J, Tan K L. Chem. Phys. Lett., 2003, 371: 80.
[29] Healy J, Hayden C, Xie T, Olson K, Waldo R, Brundage R, Gasteiger H. J. Abbott. Fuel Cells, 2005, 5: 302.
[30] Collier A, Wang H, Yuan X Z, Zhang J, Wilkinson D P. Int. J. Hydrogen Energy, 2006, 31: 1838.
[31] Inaba M, Kinumoto T, Kiriake M, Umebayashi R, Tasaka A, Ogumi Z. Electrochim. Acta, 2006, 51: 5746.
[32] Curtin D E, Lousenberg R D, Henry T J, Tangeman P C, Tisack M E. J. Power Sources, 2004, 131: 41.
[33] 王芳(Wang F). 武汉理工大学硕士论文(Master Dissertation of Wuhan University of Technology), 2008.
[34] Escobedo G, Raiford K, Nagarajan G S, Schwiebert K E. ECS Trans., 2006, 1: 303.
[35] Tang H, Peikang S, Jiang S P, Wang F, Pan M. J. Power Sources, 2007, 170: 85.
[36] Kreitmeier S, Schuler G A, Wokaun A, Büchi F N. J. Power Sources, 2012, 212: 139.
[37] Endoh E, Terazono S, Widjaja H, Takimoto Y. Electrochem. Solid-State Lett., 2004, 7(7): A209.
[38] Le Canut J, Abouatallah R M, Harrington D A. J. Electrochem. Soc., 2006, 153(5): A857.
[39] Kadyk T, Hanke-Rauschenbach R, Sundmacher K. Int. J. Hydrogen Energy, 2012, 37(9): 7689.
[40] Laconti A B, Hamdan M, McDonald R C. Handbook of Fuel Cells: Fundamentals, Technology, and Applications. NY: Wiley, 2003. 647.
[41] Ralph T R, Hogarth M P. Platinum Metals Rev., 2002, 46: 117.
[42] Xie J, Wood D L, Wayne D M, Zawodzinski T A, Atanassov P, Borup R L. J. Electrochem. Soc., 2005, 152 (1): A104.
[43] Zhang F Y, Advani S G, Prasad A K, Boggs M E, Sullivan S P, Beebe T P. Electrochim. Acta, 2009, 54: 4025.
[44] Wood D L, Chlistunoff J, Majewski J, Borup R L. J. Am. Chem. Soc., 2009, 131: 18096.
[45] St-Pierre J, Jia N. J. New Mater. Electrochem. Syst., 2002, 5: 263.
[46] Oszcipok M, Riemann D, Kronenwett U, Kreideweis M, Zedda M. J. Power Sources, 2005, 145: 407.
[47] Cindrella L, Kannan A M, Lin J F, Saminathan K, Ho Y, Lin C W, Wertz J. J. Power Sources, 2009, 194: 146.
[48] Seidenberge K, Wilhelm F, Schmitt T, Lehnert W, Scholta J. J. Power Sources, 2011, 196: 5317.
[49] Schulze M, Wagner N, Kaz T, Friedrich K A. Electrochim. Acta, 2007, 52: 2328.
[50] Frisk J W, Hicks M T, Atanasoski R T, Boand W M, Schmoeckel A K, Kurkowski M J. Fuel Cell Seminar. San Antonio: Elsevier, 2004. 10.
[51] Owejan J E, Yu P T, Makharia R. ECS Trans., 2007, 11 (1): 1049.
[52] Frisk J, Boand W, Hicks M, Kurkowski M, Atanasoski R, Schmoeckel A. Fuel Cell Seminar. San Antonio: Elsevier, 2004. 1.
[53] Aoki T, Matsunaga A, Ogami Y, Maekawa A, Mitsushima S, Ota K, Nishikawa H. J. Power Sources, 2010, 195: 2182.
[54] Mehta V, Cooper J S. J. Power Sources, 2003, 114: 32.
[55] De Bruijn F. Green Chem., 2005, 7: 132.
[56] Brett D J L, Brandon N P. J. Fuel Cell Sci. Technol., 2007, 4: 29.
[57] Wind J, Späh R, Kaiser W, Böhm G. J. Power Sources, 2002, 105: 256.
[58] Pozio A, Silva R F, de Francesco M, Giorgi L. Electrochim. Acta, 2003, 48: 154.
[59] Makkus R C, Janssen A H H, de Bruijn F A, Mallant R K A M. J. Power Sources, 2000, 86: 274.
[60] Eom K, Cho E, Nam S W, Lim T H, Jang J H, Kim H J, Hong B K, Yang Y C. Electrochim. Acta, 2012, 78: 324.
[61] Wu J, Yuan X Z, Martin J J, Wang H, Zhang J, Shen J, Wu S, Merida W. J. Power Sources, 2008, 184: 104.
[62] Stassi A, Gatto I, Monforte G, Baglio V, Passalacqua E, Antonucci V, Aricò A S. J. Power Sources, 2012, 208: 35.
[63] Travitsky N, Ripenbein T, Golodnitsky D, Rosenberg Y, Burshtein L, Peled E. J. Power Sources, 2006, 161(2): 782.
[64] Colón-Mercado H R, Popov B N. J. Power Sources, 2006, 155: 253.
[65] Wan L J, Moriyama T, Ito M, Uchida H, Watanabe M. Chem. Commun., 2002, 1: 58.
[66] Gasteiger H A, Kocha S S, Sompalli B, Wagner F T. Appl. Catal. B, 2005, 56: 9.
[67] Yu P, Pemberton M, Plasse P. J. Power Sources, 2005, 144: 11.
[68] Zhang J, Sasaki K, Sutter E, Adzic R R. Science, 2007, 315: 200.
[69] Antolini E, Salgado J R C, Gonzalez E R. J. Power Sources, 2006, 160: 957.
[70] Debe M K, Schmoeckel A K, Vernstrom G D, Atanasoski R. J. Power Sources, 2006, 161: 1002.
[71] Roy S C, Harding A W, Russell A E, Thomas K M. J. Electrochem. Soc., 1997, 144: 2323.
[72] Shao Y Y, Yin G P, Gao Y Z, Shi P F. J. Electrochem. Soc., 2006, 153: A1093.
[73] Pollet B G, Staffell I, Shang J L. Electrochim. Acta, 2012, 84: 235.
[74] Mathias M F, Makharia R, Gasteiger H A, Conley J J, Fuller T J, Gittleman G J, Kocha S S, Miller D P, Mittelsteadt C K, Xie T, Yan S G, Yu P T. Electrochem. Soc. Inter., 2005, 14: 24.
[75] Borup R L, Davey J R, Garzon F H, Wood D L, Inbody M A. J. Power Sources, 2006, 163: 76.
[76] Wheat W S, Meltser M A, Masten D A. US 8288049-B2, 2004.
[77] Makino S. Japanese Patent 2004111243, 2004.
[78] Knights S D, Colbow K M, St-Pierre J, Wilkinson D P. J. Power Sources, 2004, 127: 127.
[79] Cho E A, Ko J J, Ha H Y, Hong S A, Lee K Y, Lim T W, Oh I H. J. Electrochem. Soc., 2004, 151: A661.
[80] Sun X, Saha M S. London: Springer, 2008. 655.
[81] Sharma S, Pollet B G. J. Power Sources, 2012, 208: 96.
[82] Shrestha S, Liu Y, Mustain W E. Catal. Rev., 2011, 53(3): 256.
[83] Rajalakshmi N, Lakshmi N, Dhathathreyan K S. International Journal of Hydrogen energy, 2008, 33: 7521.
[84] Kakinuma K, Chino Y, Senoo Y, Uchida M, Kamino T, Uchida H, Deki S, Watanabe M. Electrochimica Acta, 2013, 110: 316.
[85] Yin S B, Mu S C, Lv H F, Cheng N C, Pan M, Fu Z Y. Applied Catalysis B: Environmental, 2010, 93: 233.
[86] Kimmel Y, Yang L, Kelly T G, Rykov S A, Chen J G. Journal of Catalysis, 2014, 312: 216.
[87] Ou Y W, Cui X L, Zhang X Y, Jiang Z Y. J. Power Sources, 2010, 195: 1365.
[88] Atanasoski R T, Atanasoska L L, Cullen D A, Haugen G M, More K L, Vernstrom G D. Electrocatal., 2012, 284.
[89] Genorio B, Strmcnik D, Subbaraman R, Tripkovic D, Karapetrov G, Stamenkovic V R, Pejovnik S, Markovic N M. Nat. Mater., 2010, 9.
[90] Kim J H, Cho E A, Jang J H, Kim H J, Lim T H, Oh I H, Ko J J, Oh S C. J. Electrochem. Soc., 2010, 157: B104.
[91] Ofstad A B, Davey J R, Sunde S, Borup R L. ECS Trans., 2008, 16 (2): 1301.
[92] Reiser C A, Yang D, Sawyer R D. US 2005147855-A1, 2005.
[93] Yu P T, Wagner F T. US 2006046106-A1, 2006.
[94] Kim J H, Cho E A, Jang J H, Kim H J, Lim T H, Oh I H, Ko J J, Oh S C. J. Electrochem. Soc., 2010, 157 (1): B118.
[95] Perry M L, Patterson T W, Reiser C. ECS Trans., 2006, 3 (1): 783.
[96] Yu Y, Wanga G, Tu Z, Zhan Z, Pan M. Electrochim. Acta, 2012, 71: 181.
[97] Taniguchi A, Akita T, Yasuda K, Miyazaki Y. Int. J. Hydrogen Energy, 2008, 33: 2323.
[98] Gerard M, Poirot-Crouvezier J P, Hissel D, Pera M C. Int. J. Hydrogen Energy, 2010, 35: 12295.
[99] Gubler L, Kuhn H, Schmidt T J, Scherer G G, Brack H P, Simbeck K. Fuel Cells, 2004, 4: 196.
[100] Gubler L, Gürsel S A, Scherer G G. Fuel Cells, 2005, 5: 317.
[101] Yu J R, Yi B L, Xing D M, Liu F Q, Shao Z G, Fu Y Z, Zhang H M. Phys. Chem. Chem. Phys, 2003, 5: 611.
[102] Trogadas P, Parrondo J, Ramani V. Electrochemical and Solid State Letters, 2008, 11: B113.
[103] Ramani V, Kunz H R, Fenton J M. J. Power Sources, 2005, 152: 182.
[104] Haugen G M, Meng F, Aieta N, Horan J L, Kuo M C, Frey M H, Hamrock S J, Herring A M. ECS Trans., 2006, 3: 551.
[105] Liu Y H, Yi B L, Shao Z G. Electrochemical and Solid State Letters, 2006, (9): A356.
[106] Pan M, Yang X S, Shen C H. Composite Materials, 2003, (iii): 385.
[107] Hommura S, Kawahara K, Shimohira T. Journal of the Electrochemical Society, 2008, 155: A29.
[108] Liu W, Ruth K, Rusch G. J. New Mater. Electrochem. Syst., 2001, 4: 227.
[109] Xu H, Wu M, Liu Y, Mittal V, Vieth R, Kunz H R, Bonville L J, Fenton J M. ECS Trans., 2006, 3: 561.
[110] Jung G, Chuang K, Jao T, Yeh C, Lin C. Appl Energy, 2012, 100: 81.
[111] Bose A, Babburi P, Kumar R, Myers D, Mawdsley J, Milhuff J. J. Power Sources, 2013, 243: 964.
[112] Liu D, Case S. J. Power Sources, 2006, 162(1): 521.
[113] Borup R L. Fuel Cell Durability Conference, Washington DC: Elsevier, 2005. 8.
[114] Tawfik H, Hung Y, Mahajan D. J. Power Sources, 2007, 163: 755.
[115] Lee S J, Huang C H, Lai J J, Chen Y P. J. Power Sources, 2004, 131: 162.