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硼吸附材料及其性能
Materials for Boron Adsorption
硼酸作为一种重要的化学品,广泛应用于工业生产及高尖端技术领域。由于在其生产和应用过程中产生大量含硼废水,从水溶液中回收或脱除硼对资源的重复利用、降低环境污染等都有重要意义。吸附法提硼具有深度脱硼、杂质去除彻底、吸附剂可循环利用和工艺简单等优势,是一种高效脱硼方法,其核心问题在于设计与制备硼吸附容量大、机械强度高且易再生的吸附材料。本文综述了近年来国内外硼吸附材料的类型及其吸附性能,按照吸附功能团的结构将硼吸附材料进行划分,着重介绍了目前应用最广的葡甲胺类吸附剂和最具发展前景的含双酚羟基功能团的吸附剂的研究与应用情况,同时介绍了新型有机-无机杂化硼吸附材料,并指出了今后硼吸附材料的发展趋势,为盐湖卤水提硼、淡化海水脱硼和废水除硼等应用开发中硼吸附材料的选择提供重要参考。
Boric acid, as an important boron compound, has been widely used in industrial production and cutting-edge technology. Massive wastewater containing boron were discharged during the industrial process. Adsorption technique is an efficient method for removal or recovery of boron from aqueous solutions as it has advantages of high boron recovery, renewable adsorbents and easy operation. The key to the adsorption process is the the selection of adsorbents with high adsorption capacity, acceptable mechanical strength and regeneration capability. In this review, we mainly review different kinds of boron-selective adsorbents reported in recent years and their adsorption performances. Boron adsorbents are catalogued by their functional groups. Among the reported adsorbents, the most widely used N-methyl-D-glucamine (NMDG) functionalized adsorbents are extensively demonstrated, and the adsorbents with structure of diols binding phenolic moiety are discussed. Moreover, other organic-inorganic hybrid adsorbents are introduced. This review may be helpful to the design of novel high-performance adsorbents for boron recovery or removal from aqueous solutions such as from salt lake brine and desalinize seawater.
Contents
1 Introduction
2 NMDG functionalized adsorbents
2.1 NMDG functionalized organic resins
2.2 NMDG functionalized organic-inorganic hybrid materials
3 Other active diols functionalized adsorbents
3.1 Polymeric adsorbents
3.2 Phenolic adsorbents
4 Inorganic adsorbents
4.1 Magnesium hydroxide
4.2 Hydroxide of aluminum, iron, calcium
5 Natural adsorbents
6 Conclusion and outlook
boron
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