中文   |   English   |   Email Alert

车用质子交换膜燃料电池材料部件

王诚*1, 王树博1, 张剑波2, 李建秋2, 欧阳明高2, 王建龙1

化学进展 ›› 2015, Vol. 27 ›› Issue (2/3) :310-320

PDF (3335KB)
化学进展 ›› 2015, Vol. 27 ›› Issue (2/3) :310-320 DOI: 10.7536/PC140827
综述与评论
扫码查看或转发全文

车用质子交换膜燃料电池材料部件

    王诚*1, 王树博1, 张剑波2, 李建秋2, 欧阳明高2, 王建龙1
作者信息 +

The Key Materials and Components for Proton Exchange Membrane Fuel Cell

  • Wang Cheng*1, Wang Shubo1, Zhang Jianbo2, Li Jianqiu2, Yang Minggao2, Wang Jianlong1
Author information +
文章历史 +

摘要

车用燃料电池主要包括质子交换膜燃料电池、金属-空气燃料电池等,其中质子交换膜燃料电池是目前车用燃料电池的主要开发对象(以下简称车用燃料电池)。经过全球范围内近十年的持续研发,车用燃料电池在能量效率、功率密度与比功率、低温启动等功能特性方面已经取得了突破性进展,新一轮的燃料电池汽车产业化浪潮正在迫近。然而,车用燃料电池的耐久性和成本还没达到预期商业化目标,是其产业化的最后障碍。探索和研发燃料电池用新型关键材料部件是解决这两大问题、推进其商业化进程的关键所在,也是车用燃料电池长期的研究重点和热点。本文系统地梳理了近几年来车用燃料电池质子交换膜、催化层、气体扩散层、双板板关键材料部件的研究进展和成果,并分类进行了简要评述,分析了其性能与商业化目标的差距。最后展望了车用燃料电池关键材料部件今后的发展方向。

Abstract

Vehicle fuel cells include proton exchange membrane fuel cell (PEMFC), metal/air fuel cell, etc. The PEMFC is the most promising candidate for automobile application. Through over a decade continuous research and development all over the world, the performances of PEMFC, such as energy efficiency, volume and mass power density, low temperature start ability, have attained breakthrough progress. A new round of fuel cell automobile industrialization has been being approached. However, the properties of durability and cost of the PEMFC system have not met the target of industrialization, and the state of art of durability and cost become the obstacles of PEMFC automobiles industrialization. The novel key materials and components used in the PEMFC should be focused on in the future study, and must be further researched and developed for the two obstacles resolution and the PEMFC industrialization promotion. In this paper, based on a large number of current research articles, the progress and achievement of key materials and components for PEMFC, include proton exchange membrane, catalyst layer, gas diffusion layer, bipolar plate, have been detailed analyzed and classified reviewed. The gap between their state of art and the target of industrialization is analyzed and the emphasis development direction in the future is summarized based on the key materials and components.

Contents
1 Introduction
2 Proton exchange membrane
3 Catalyst layer
3.1 Catalysts
3.2 Support materials for catalysts
3.3 Fabrication technology of catalyst layer
4 Gas diffusion layer
5 Bipolar plate
6 Summary and outlook

Graphical abstract

关键词

氢能 / 燃料电池汽车 / 催化剂 / 质子交换膜 / 扩散层 / 双极板

Key words

hydrogen energy / fuel cell automobile / catalyst / proton exchange membrane / gas diffusion layer / bipolar plate

引用本文

引用格式 ▾
王诚, 王树博, 张剑波, 李建秋, 欧阳明高, 王建龙. 车用质子交换膜燃料电池材料部件[J]. 化学进展, 2015, 27(2/3): 310-320 DOI:10.7536/PC140827
Wang Cheng, Wang Shubo, Zhang Jianbo, Li Jianqiu, Yang Minggao, Wang Jianlong. The Key Materials and Components for Proton Exchange Membrane Fuel Cell[J]. Progress in Chemistry, 2015, 27(2/3): 310-320 DOI:10.7536/PC140827

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 欧阳明高(Ouyang M G). 内燃机学报( Transactions of CSICE), 2008, 26: 107.
[2] Sung W, Song Y, Yu K, Lim T. SAE Int. J. Engines, 2010, 3(1): 768.
[3] Yokoyama T. California Air Resources Board ZEV Symposium, Sacramento CA, Sep., 2009. 21.
[4] 李建秋(Li J Q), 方川(Fang C), 徐梁飞(Xu L F). 汽车安全与节能学报(Journal of Automotive Safety and Energy), 2014, 5(1): 17.
[5] Jones D J. Global Change, Energy Issues and Regulation Policies. Netherlands: Springer, 2013: 161.
[6] The Fuel Cell Technical Team. Fuel Cell Technical Team Roadmap, Washington: DOE, June 2013.
[7] Matthew M. Polymer Electrolyte Fuel Cell Degradation. Dutch: Elsevier, 2011. 112.
[8] Holmström N, Wiezell K, Lindbergh G. J. Electro. Soc., 2012, 159 (8): F369.
[9] Chen Y, Guo R L, Lee C H, Lee M, James E. McGrath. International Journal of Hydrogen Energy, 2012, 37: 6132.
[10] Wang Z B, Tang H L, Li J R, Jin A P, Wang Z, Zhang H L, Pan M. International Journal of Hydrogen Energy, 2013, 38: 4725.
[11] Jung M S, Kim T H, Yoon Y J, Kang C G, Yu D M, Lee J Y, Kim H J, Hong Y T. Journal of Membrane Science, 2014, 459:72.
[12] Chen S W, Chen K C, Zhang X, Hara R, Endo N, Higa M, Okamoto K, Wang L J. Polymer, 2013, 54: 236.
[13] Feng S G, Shang Y M, Wang Y W, Liu G S, Xie X F, Dong W Q, Xu J M, Mathurb V K. Journal of Membrane Science, 2010, 352: 14.
[14] Feng S G, Shang Y M, Liu G S, Dong W Q, Xie X F, Xu J M, Mathurb V K. Journal of Power Sources, 2010, 195: 6450.
[15] Feng S G, Shang Y M, WangY Z, Xie X F, Mathurb V K, Xu J M. Journal of Power Sources, 2010, 195: 2541.
[16] Feng S G, Shang Y M, Wang S B, Xie X F, WangY Z, Wang Y W, Xu J M. Journal of Membrane Science, 2010, 346: 105.
[17] Mader J A, Benicewicz B C. Fuel Cells, 2011, 11(2): 222.
[18] Qian W, Shang Y M, Fang M, Wang S B, Xie X F, Wang J H, Wang W X, Du J Y, Wang Y W, Mao Z Q. International Journal of Hydrogen Energy, 2012, 37: 12919.
[19] Qian W, Shang Y M, Wang S B, Xie X F, Mao Z Q. International Journal of Hydrogen Energy, 2013, 38: 11053.
[20] Makharia R, Kocha S S, Yu P T, Sweikart M A, Gu W, Wagner F T, Gasteiger H A. ECS Transactions, 2006, 1 (8): 3.
[21] Lee K, Zhang J, Wang H, Wilkinson D P. J. Appl. Electrochem., 2006, 36(5): 507.
[22] Antolini E, Gonzalez E R. Solid State Ionics, 2009, 180(9/10): 746.
[23] Zhang P, Huang S Y, Popov B N. J. Electrochem. Soc., 2010, 157(8): B1163.
[24] Seger B, Kongkanand A, Vinodgopal K, Kamat P V. J. Electroanal. Chem., 2008, 621: 198.
[25] Antolini E, Gonzalez E R. Appl. Catal. B: Environ, 2010, 96: 245.
[26] Debe M K. ECS Trans., 2012, 45 (2): 47.
[27] Antolini E, Perez J. J. Mater. Sci., 2011, 46: 4435.
[28] Ehteshami S M M, Chan S H. Electrochimica Acta, 2013, 93: 334.
[29] Zhou X W, Gan Y L, Du J J, Tian D N, Zhang R H, Yang C Y, Dai Z X. Journal of Power Sources, 2013, 232: 310.
[30] Galeano C, Baldizzone C, Bongard H, Spliethoff B, Weidenthaler C, Meier J C, Mayrhofer K J J, Schüth F. Adv. Funct. Mater., 2014, 24: 220.
[31] Zhang G, Shao Z G, Lu W T, Xie F, Xiao H, Qin X P, Yi B L. Applied Catalysis B: Environmental, 2013, 132/133: 183.
[32] Choi R, Choi S, Choi C H, Nam K M, Woo S I, Park J T, Han S W. Chem. Eur. J., 2013, 19: 8190.
[33] Wang S Y, Jiang S P, Xin W G, Guo J. Electrochimica Acta, 2011, 56: 1563.
[34] Kim J M, Joh H I, Jo S M, Ahn D J, Ha H Y, Hong S A, Kim S K. Electrochimica Acta, 2010, 55: 4827.
[35] Guo S J, Zhang S, Sun X L, Sun S H. J. Am. Chem. Soc., 2011, 133: 15354.
[36] Bi Y P, Lu G X. Electrochemistry Communications, 2009, 11: 45.
[37] Sun S H, Jaouen F, Dodelet J P. Adv. Mater., 2008, 20: 3900.
[38] Shimizu W, Okada K, Fujita Y, Zhao S S, Murakami Y. Journal of Power Sources, 2012, 205: 24.
[39] Zhou X J, Qiao J L, Yang L, Zhang J J. Adv. Energy Mater., 2014, 4(8): 1301523.
[40] He W, Jiang H J, Zhou Y, Yang S D, Xue X Z, Zou Z Q, Zhang X G, Akins D L, Yang H. Carbon, 2012, 50(1): 265.
[41] Liao C S, Liao C T, Tso C Y, Shy H J. Mater. Chem. Phys., 2011, 130(1/2): 270.
[42] Kundu P, Nethravathi C, Deshpande P A, Rajamathi M, Madras G, Ravishankar N. Chem. Mater., 2011, 23(11): 2772.
[43] Paul R R K, Mulchandani A. J. Power Sources, 2013, 223: 23.
[44] Qiu J D, Wang G C, Liang R P, Xia X H, Yu H W. J. Phys.Chem. C, 2011, 115(31): 15639.
[45] Maiyalagan T, Dong X, Chen P, Wang X. J. Mater. Chem., 2012, 22: 5286.
[46] Hu Y, Zhang H, Wu P, Zhang H, Zhou B, Cai C. Phys. Chem.Chem. Phys., 2011, 13: 4083.
[47] Choi S M, Seo M H, Kim H J, Kim W B. Synth. Met., 2011, 161: 2405.
[48] Hung T F, Wang B, Tsai C W, Tu M H, Wang G X, Liu R S, Tsai D P, Lo M Y, Shy D S, Xing X K. Int. J. Hydrogen Energy, 2012, 37(19): 14205.
[49] Li Y J, Li Y J, Zhu E, McLouth T, Chiu C Y, Huang X Q, Huang Y. J. Am. Chem. Soc., 2012, 134(30): 12326.
[50] Guo S J, Sun S H. J. Am. Chem. Soc., 2012, 134(5): 2492.
[51] Rajalakshmi N, Lakshmi N, Dhathathreyan K S. International Journal of Hydrogen Energy, 2008, 33: 7521.
[52] Ioroi T, Akita T, Asahi M, Yamazaki S I, Siroma Z, Fujiwara N, Yasuda K. Journal of Power Sources, 2013, 223: 183.
[53] Kakinuma K, Chino Y J, Senoo Y C, Uchida M, Kamino T, Uchida H, Deki S, Watanabe M. Electrochimica Acta, 2013, 110: 316.
[54] Du C Y, Chen M, Cao X Y, Yin G P, Shi P F. Electrochemistry Communications, 2009, 11: 496.
[55] Suzuki S, Onodera T, Kawaji J, Mizukami T, Morishima M, Yamaga K. Journal of Power Sources, 2013, 223: 79.
[56] Yin S B, Mu S C, Lv H F, Cheng N C, Pan M, Fu Z Y. Applied Catalysis B: Environmental, 2010, 93: 233.
[57] Kimmel Y, Yang L R, Kelly T G, Rykov S A, Chen J G. Journal of Catalysis, 2014, 312: 216.
[58] Ou Y W, Cui X L, Zhang X Y, Jiang Z Y. Journal of Power Sources, 2010, 195: 1365.
[59] Middelman E. Fuel Cells Bulletin, 2002, 2002(11): 9.
[60] Tian Z Q, Lim S H, Poh C K, Tang Z, Xia Z T, Luo Z Q, Shen P K, Chua D, Feng Y P, Shen Z X, Lin J Y. Advanced Energy Materials, 2011, 1(6): 1205.
[61] Debe M K, Hendricks S M, Vernstrom G D, Meyers M, Brostrom M, Stephens M, Chan Q, Willey J, Hamden M, Mittelsteadt C K, Capuano C B, Ayers K E, Anderson E B. Journal of the Electrochemical Society, 2012, 159(6): K165.
[62] Bonnefont A, Ruvinskiy P, Rouhet M, Orfanidi A, Neophytides S, Savinova E. WIREs Energy Environ, 2014, 3: 505.
[63] Pan C F, Wu H, Wang C, Wang B, Zhang L, Cheng Z D, Hu P, Pan W, Zhou Z Y, Yang X, Zhu J. Advanced Martials, 2008, 20(9): 1644.
[64] Dong B, Gwee L, Salas-de la Cruz D, Winey K I, Elabd Y A. Nano Letters, 2010. 10(9): 3785.
[65] Cindrella L, Kannan A M, Lin J F, Saminathan K, Ho Y, Lin C W, Wertz J. J. Power Sources, 2009, 194: 146.
[66] Arvay A, Yli-Rantala E, Liu C H, Peng X H, Koski P, Cindrella L, Kauranen P, Wilde P M, Kannan A M. J. Power Sources, 2012, 213: 317.
[67] Park H. Energy Conversion and Management, 2014, 81: 220.
[68] Cho J, Oh H, Park J, Min K, Lee E, Jyoung J. International Journal of Hydrogen Energy, 2014, 39: 495.
[69] Burheim O S, Su H, Pasupathi S, Pharoah J G, Pollet B G. International Journal of Hydrogen Energy, 2013, 38: 8437.
[70] Seo J H, Baik K D, Kim D K, Kim S, Choi J W, Kim M, Song H H, Kim M S. International Journal of Hydrogen Energy, 2013, 38: 16245.
[71] Middleman E, Kout W, Vogelaar B, Lenssen J, de Waal E. J. Power Sources, 2003, 118: 44.
[72] Cho E A, Jeon U S, Ha H Y, Hong S A, Oh I H. J. Power Sources, 2004, 125: 178.
[73] Kuan H C, Ma C C M, Chen K H, Chen S M. J. Power Sources, 2004, 134: 7.
[74] Heinzel A, Mahlendorf F, Neimzig O, Kreuz C. J. Power Sources, 2004, 131: 35.
[75] Wang H, Turner J A. Fuel Cells, 2010, 10(4): 510.
[76] Hermann A, Chaudhuri T, Spagnol P. Int. J. Hydrogen Energy, 2005, 30: 1297.
[77] Mehta V, Cooper J S. J. Power Sources, 2003, 114: 32.
[78] Brett D J L, Brandon N P. J. Fuel Cell Sci. Technol., 2007, 4: 29.
[79] Pozio A, Silva R F, De Francesco M, Giorgi L. Electrochim. Acta, 2003, 48: 1543.
[80] Wang H, Sweikart M A, Turner J A. J. Power Sources, 2003, 115: 243.
[81] Wang H, Turner J A. J. Power Sources, 2004, 128: 193.
[82] Wang H, Teeter G, Turner J A. J. Electrochem. Soc., 2005, 152: B99.
[83] Wang H, Turner J A. ECS Transactions, 2006, 1: 263.
[84] Brady M P, Weisbrod K, Zawodzinski C, Paulauskas I, Buchanan R A, Walker L R. Electrochem. Solid State Lett., 2002, 5: A24.
[85] Brady M P, Weisbrod K, Paulauskas I, Buchanan R A, More L, Wang H, Wilson M, Garzon F, Alker L R. Scripta Mater., 2004, 50: 1017.
[86] Yang M J, Zhang D M. Energy, 2014, 64: 242.
[87] 刘峰(Liu F), 王诚(Wang C), 张剑波(Zhang J B), 兰爱东(Lan A D), 李建秋(Li J Q), 欧阳明高(Ouyang M G). 化学进展(Progress in Chemistry), 2014, 26(11): 1763.

PDF (3335KB)

5687

访问

0

被引

详细

导航
相关文章

/

〈 〉