锂离子电池铌基氧化物负极材料

doi:10.7536/PC140932

化学进展 ›› 2015, Vol. 27 ›› Issue (2/3) :297-309 DOI: 10.7536/PC140932

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锂离子电池铌基氧化物负极材料

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Nb-Based Oxides as Anode Materials for Lithium Ion Batteries

Lou Shuaifeng¹, Cheng Xinqun¹, Ma Yulin¹, Du Chunyu¹, Gao Yunzhi¹, Yin Geping*^1,2

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摘要

锂离子电池负极材料钛酸锂由于其高功率和优异的循环性能得到了广泛的研究,但是较低的比容量(175 mAh/g)限制了其应用前景。与钛酸锂相比,铌基氧化物具有相似的嵌脱锂电位和更高的比容量,也展现出良好的倍率性能和循环性能,有望成为新型功率型负极材料。本文综述了多种铌基复合金属氧化物(Nb₂O₅,TiNb₂O₇,LiNb₃O₈等)的晶体结构、电化学性能和嵌脱锂机理,讨论了材料的组成、形貌和制备工艺等对其嵌脱锂性能的影响,并概述其作用机制。此外,本文还归纳总结了铌基材料嵌脱锂行为的共性,并比较了它们与钛酸锂的异同,对其作为高功率锂离子电池负极材料的研究趋势和发展前景进行了展望。

Abstract

Li₄Ti₅O₁₂ as anode materials for lithium ion batteries has been widely studied because of its excellent rate performance and cycle performance, but the low specific capacity (175 mAh/g) limits its application in the future. Compared with Li₄Ti₅O₁₂, niobium based oxides have similar lithium ion insertion/extraction potential and higher specific capacity. In addition,they also have good rate performance and promising to be new anode materials with high power performance, that have got increasing researchers' attention in recent years. In this paper,the crystal structure, electrochemical performance and lithium ion insertion/extraction mechanism of various niobium based oxides materials (Nb₂O₅, TiNb₂O₇, LiNb₃O₈, etc.) are reviewed. The effects on lithium ion transfer and storage performance originate from component, particle morphology and preparation technology are discussed. Meanwhile, the influencing mechanism is also summarized. In addition, the generality in electrochemical lithium insertion and extraction behavior of niobium based oxides materials, the differences and similarities compared with Li₄Ti₅O₁₂ are summarized the tendency and prospect of them as anode materials for high power lithium ion batteries in the end are also discussed.

Contents
1 Introduction
2 Research status of Nb-based oxides anode materials for lithium ion battery
2.1 Niobium oxides
2.2 Titanium niobium oxides
2.3 Lithium niobium oxides
2.4 Potassium niobium oxides
2.5 Vanadium niobium oxides
2.6 Other niobium based oxides
3 Understand of intercalation and deintercalation of lithium ion for niobium based oxide
4 Summary

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关键词

锂离子电池 / 负极材料 / 铌基氧化物 / 嵌脱锂机理 / 电化学性能

Key words

lithium ion batteries / anode materials / Nb-based materials / mechanism of lithium insertion and extraction / electrochemical performance

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娄帅锋, 程新群, 马玉林, 杜春雨, 高云智, 尹鸽平. 锂离子电池铌基氧化物负极材料[J]. 化学进展, 2015, 27(2/3): 297-309 DOI:10.7536/PC140932

Nb-Based Oxides as Anode Materials for Lithium Ion Batteries[J]. Progress in Chemistry, 2015, 27(2/3): 297-309 DOI:10.7536/PC140932

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