TinO2n-1系列氧化物的特性、制备方法及应用

应杭君; 田华军; 孟阵; 韩伟强

doi:10.7536/PC141023

化学进展 ›› 2015, Vol. 27 ›› Issue (4) :361-372 DOI: 10.7536/PC141023

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Ti_nO_2n-1系列氧化物的特性、制备方法及应用

应杭君, 田华军, 孟阵, 韩伟强*

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Ti_nO_2n-1 Series Compounds——Properties, Preparation Methods and Applications

Ying Hangjun, Tian Huajun, Meng Zhen, Han Weiqiang*

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摘要

Ti_nO_2n-1是钛的一系列亚化学计量氧化物,具有导电性好、可见光响应能力强、电化学性能优异、环保无毒等诸多优良特性。其中,Ti₄O₇单晶的电导率达1500 S ·cm^-1,和石墨相当。Ti_nO_2n-1的相结构、电磁学以及电化学方面的研究已有很多进展。目前,科研人员已开发出了一系列制备Ti_nO_2n-1的方法,最主要的方法是高温还原TiO₂及其前驱体,已成功制备出纳米球、纳米管及纳米线等不同形貌的材料。由于其特性优良,Ti_nO_2n-1在惰性电极、催化剂载体、锂电池、热电及光电材料、光催化降解等方面的应用引起了研究人员的关注,并得到一些商业化应用,例如Ti₄O₇已开发为商业电极等,具有广阔的应用前景。本文对Ti_nO_2n-1的结构及物化特性进行了总结,并概括归纳了该系列亚氧化物的制备方法,最后介绍了Ti_nO_2n-1目前的应用情况并对今后的发展作出展望,以期为Ti_nO_2n-1系列化合物的研究发展提供相关的参考和依据。

Abstract

Ti_nO_2n-1 is a series of substoichiometric oxides of titanium with many excellent properties such as high electronic conductivity, strong visible light absorption, outstanding electrochemistry stability and environmental compatibility. Ti₄O₇ exhibits a single crystal conductivity of 1500 S ·cm^-1, comparable to that of graphite. These materials have been studied for many years and their properties of structure, magnetics and electrics have been widely investigated. A lot of preparation methods have been developed for the purpose of property research and application development. The most commonly used preparation method is reduction of TiO₂ or its precursor at a high temperature, and some interesting morphologies have been obtained, like nanosphere, nanorod and nanowire. In recent years, their wonderful properties arouse peoples interest for their applications in noble electrodes, catalyst carriers, lithium batteries, thermoelectric and photoelectric materials, photocatalysis materials and so on. For example, Ti₄O₇ has been commoditized and utilized in many fields. However, a lot of work is remained to do for the full use of these titanic oxides, such as exploration of new feature and strategies to improve the specific surface area of these materials.According to the work of the predecessors, this paper introduces the structure features, physicochemical properties of Ti_nO_2n-1, and makes a summary of some typical preparation methods and applications, with the purpose of providing some reference for the research and development of Ti_nO_2n-1 series compounds.

Contents
1 Introduction
2 Structural properties of Ti_nO_2n-1
3 Physicochemical properties of Ti_nO_2n-1
4 Preparation methods of Ti_nO_2n-1
4.1 High temperature sintering
4.2 Laser ablation
4.3 Sol-gel sintering
5 Application of Ti_nO_2n-1
5.1 Application of Ti_nO_2n-1 in noble electrodes
5.2 Application of Ti_nO_2n-1 in fuel cells
5.3 Application of Ti_nO_2n-1 in batteries
5.4 Application of Ti_nO_2n-1 in thermoelectric and photoelectric materials
5.5 Application of Ti_nO_2n-1 in photocatalytic degradation
[JP] 6 Conclusion and outlook

Graphical abstract

关键词

Ti_nO_2n-1 / Magnéli / 性质 / 制备方法 / 应用

Key words

Ti_nO_2n-1 / Magnéli / property / preparation method / application

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应杭君, 田华军, 孟阵, 韩伟强. Ti_nO_2n-1系列氧化物的特性、制备方法及应用[J]. 化学进展, 2015, 27(4): 361-372 DOI:10.7536/PC141023

Ying Hangjun, Tian Huajun, Meng Zhen, Han Weiqiang. Ti_nO_2n-1 Series Compounds——Properties, Preparation Methods and Applications[J]. Progress in Chemistry, 2015, 27(4): 361-372 DOI:10.7536/PC141023

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