超级电容器用石墨烯/金属氧化物复合材料

李丹; 刘玉荣; 林保平; 孙莹; 杨洪; 张雪勤

doi:10.7536/PC141024

化学进展 ›› 2015, Vol. 27 ›› Issue (4) :404-415 DOI: 10.7536/PC141024

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超级电容器用石墨烯/金属氧化物复合材料

^1,2

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Graphene/Metal Oxide Composites as Electrode Material for Supercapacitors

Li Dan¹, Liu Yurong^1,2, Lin Baoping*¹, Sun Ying¹, Yang Hong¹, Zhang Xueqin¹

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文章历史 +

摘要

超级电容器是一种具有高功率密度和长循环寿命的新型储能装置,碳材料、金属氧化物和导电聚合物是常见的三种超级电容器电极材料。在石墨烯/金属氧化物复合材料中,石墨烯和金属氧化物可以发挥各自的优点,结合石墨烯优异的循环稳定性能和金属氧化物的高容量特性,纳米复合材料的综合性能可以得到很大地提升。因此,石墨烯/金属氧化物复合物的研究是超级电容器领域的热点研究方向之一。本文以金属氧化物的种类、石墨烯的结构和复合物的制备方法为线索,综述了国内外应用于超级电容器方面的石墨烯/金属氧化物复合材料的研究进展,归纳总结出与石墨烯复合最优的金属氧化物类型和制备方法,并进一步对该类复合材料的发展趋势进行了展望。

Abstract

Supercapacitor has been recognized as a very promising new energy storage device due to its high power density and long cycle life. Carbon materials, metal oxides and conductive polymers are three more commonly utilized electrode materials for supercapacitors. The combination of the cycling stability of graphene and high capacity of metal oxide provides the graphene/metal oxide composite superiors performance. Consequently, significant research interest has been directed into the research of the graphene/metal oxide composite. In this paper, we present a review on the research progress of the graphene/metal oxide composite for supercapacitor application in term of the types of metal oxides, grapheme structure and preparation methods. Furthermore, the optimum synthesizing conditions and an outlook of the developing trend for the graphene/metal oxide composite are summarized.

Contents
1 Introduction
2 MnO₂/graphene composites
2.1 Solvothermal (hydrothermal) method
2.2 Electrochemical deposition
2.3 Chemical reaction
2.4 Self-assembly method
3 RuO₂/graphene composites
3.1 Sol-gel method
3.2 Solvothermal (hydrothermal) method
4 NiO/graphene composites
4.1 Chemical precipitation
4.2 Solvothermal (hydrothermal) method
4.3 Other methods
5 Co₃O₄/graphene composites
5.1 Chemical precipitation
5.2 Solvothermal (hydrothermal) method
5.3 Other methods
6 ZnO/graphene composites
7 Other metal oxides
8 Binary metal oxides
9 Conclusion

Graphical abstract

关键词

超级电容器 / 石墨烯 / 金属氧化物 / 复合材料 / 制备方法 / 电化学性能

Key words

supercapacitor / graphene / metal oxide / composites / preparation methods / electrochemical performance

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李丹, 刘玉荣, 林保平, 孙莹, 杨洪, 张雪勤. 超级电容器用石墨烯/金属氧化物复合材料[J]. 化学进展, 2015, 27(4): 404-415 DOI:10.7536/PC141024

Li Dan, Liu Yurong, Lin Baoping, Sun Ying, Yang Hong, Zhang Xueqin. Graphene/Metal Oxide Composites as Electrode Material for Supercapacitors[J]. Progress in Chemistry, 2015, 27(4): 404-415 DOI:10.7536/PC141024

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