基于外壁作用的瓜环基超分子配位聚合物

祝黔江; 薛赛凤; 陶朱

doi:10.7536/PC141036

化学进展 ›› 2015, Vol. 27 ›› Issue (6) :625-632 DOI: 10.7536/PC141036

超分子化学专辑

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基于外壁作用的瓜环基超分子配位聚合物

祝黔江, 薛赛凤, 陶朱*

作者信息 +

Supramolecular Coordination Polymers Based on the Outer-Surface Interaction of Cucurbit [n] urils

Zhu Qianjiang, Xue Saifeng, Tao Zhu*

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文章历史 +

摘要

利用瓜环外壁的结构导向作用设计并构筑瓜环-金属离子超分子配位聚合物可能成为瓜环配位化学研究的一个新方向。根据瓜环外壁作用类型,研究内容包括:1) 瓜环外壁取代烷基推电子效应对瓜环基超分子配位聚合物形成的促进作用;2) 瓜环外壁与化合物芳环的相互作用对瓜环基超分子配位聚合物形成的促进作用;3) 瓜环外壁与无机阴离子的相互作用对瓜环基超分子配位聚合物形成的促进作用;4) 瓜环外壁取代羟基的配位作用对瓜环基超分子配位聚合物形成的促进作用。这些瓜环基超分子配位聚合物可能具有吸附捕集、分离提纯和分析等功能性质。

Abstract

A series of supramolecular polymers based on direct coordination of metal ions to the cucurbit[n] urils with the aid of the outer-surface interactions of cucurbit[n] urils could become a new branch in Q s-based coordination chemistry. According to the characteristics of the outer-surface interactions of cucurbit[n] urils, they can be catalogued in: 1) electrodonating effect of the alkyl-substituted groups on the outer-surface of cucurbit[n] urils; 2) interactions between methine or methylene moieties on the outer-surface of cucurbit[n] urils and aromatic moiety of organic structure directing agents; 3) interactions between methine or methylene moieties on the outer-surface of cucurbit[n] urils as well as ion-dipole interactions between positive portal carbonyl carbon of cucurbit[n] urils and chloride anion from polychlorometallate anions; 4) coordination interaction between hydroxyl groups on the outer-surface of cucurbit[n] urils with metal ions. Based on the characteristics of the supramolecular coordination polymers, they have potential applications in the fields, such as absorption, analysis, separation, isolation, and so on.

Contents
1 Introduction
2 Typical outer-surface interactions of cucurbit[n]urils resulting in the formation of Q[n]s-based coordination polymers
2.1 Electrodonating effect of the alkyl-substituted groups on the outer-surface of cucurbit[n]urils
2.2 π…π stacking between portal carbonyl groups of cucurbit[n]uril as well as C—H…π interaction between methine or methylene moieties on the outer-surface of cucurbit[n]urils and aromatic moiety of organic structure directing agents
2.3 Unusual hydrogen bonding between methine or methylene moieties on the outer-surface of cucurbit[n]urils as well as ion-dipole interactions between positive portal carbonyl carbon of cucurbit[n]urils and chloride anion from polychlorometallate anions
2.4 Coordination interaction between hydroxyl groups on the outer-surface of cucurbit[n]urils with metal ions
3 Potential applications of the supramolecular coordination polymers
4 Conclusion and outlook

Graphical abstract

关键词

瓜环外壁作用 / 结构导向 / 金属-瓜环配位 / 配位聚合物 / 功能性质

Key words

outer-surface interaction of cucurbit[n] urils / structure directing strategies / coordination of cucurbit uril with metal ions / coordination polymers / functional properties

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祝黔江, 薛赛凤, 陶朱. 基于外壁作用的瓜环基超分子配位聚合物[J]. 化学进展, 2015, 27(6): 625-632 DOI:10.7536/PC141036

Zhu Qianjiang, Xue Saifeng, Tao Zhu. Supramolecular Coordination Polymers Based on the Outer-Surface Interaction of Cucurbit [n] urils[J]. Progress in Chemistry, 2015, 27(6): 625-632 DOI:10.7536/PC141036

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原文顺序 | 出版日期 | 本文引用

[1] Wang F, Han C Y, He C L, Zhou Q Z, Zhang J Q, Wang C, Li N, Huang F H. J. Am. Chem. Soc., 2008, 130: 11254.
[2] Zhang Z B, Luo Y, Chen J Z, Dong S Y, Yu Y H, Ma Z, Huang F H. Angew. Chem. Int. Ed., 2011, 50: 1397.
[3] Dong S Y, Luo Y, Yan X Z, Zheng B, Ding X, Yu Y H, Ma Z, Zhao Q L, Huang F H. Angew. Chem. Int. Ed., 2011, 50: 1905.
[4] Yan X Z, Xu D H, Chi X D, Chen J Z, Dong S Y, Ding X, Yu Y H, Huang F H. Adv. Mater., 2012, 24, 362.
[5] Kuehl C J, Kryschenko Y K, Radhakrishnan U, Seidel S R, Huang S D, Stang P J. Proc.Natl.Acad.Sci.U.S.A., 2002, 99: 4932.
[6] Kim H J, Kim T, Lee L. Acc. Chem. Res., 2011, 44: 72.
[7] Sanchez C, Arribart H, Guille M M G. Nature Mat., 2005, 4: 277.
[8] Orme C A, Noy A, Wierzbicki A, McBride M T, Grantham M, Teng H H, Dove P M, DeYoreo J J. Nature, 2001, 411: 775.
[9] Dong S Y, Zheng B, Xu D H, Yan X Z, Zhang M M, Huang F H. Adv. Mater., 2012, 24, 3191.
[10] Zhang M M, Xu D H, Yan X Z, Chen J Z, Dong S Y, Zheng B, Huang F H. Angew. Chem. Int. Ed., 2012, 51: 7011.
[11] Ji X F, Yao Y, Li J Y, Yan X Z, Huang F H. J. Am. Chem. Soc., 2013, 135: 74.
[12] Freeman W A, Mock W L, Shih N Y. J. Am. Chem. Soc., 1981, 103: 7367.
[13] Day A I, Arnold A P. WO 0068232 2000, 8.
[14] Kim J, Jung I S, Kim S Y, Lee E, Kang J K, Sakamoto S, Yamaguchi K, Kim K. J. Am. Chem. Soc., 2000, 122: 540.
[15] Day A I, Blanch R J, Arnold A P, Lorenzo S, Lewis G R, Dance I A. Angew. Chem. Int. Ed., 2002, 41: 275.
[16] Cheng X J, Liang L L, Chen K, Ji N N, Xiao X, Zhang J X, Zhang Y Q, Xue S F, Zhu Q J, Ni X L, Tao Z. Angew. Chem. Int. Ed., 2013, 52: 7252.
[17] Ni X L, Xiao X, Cong H, Zhu Q J, Xue S F, Tao Z. Acc. Chem. Res., 2014, 47: 1386.
[18] Kim K. Chem. Soc. Rev., 2002, 31: 96.
[19] Lagona J, Mukhopadhyay P, Chakrabarti S, Isaacs L. Angew. Chem. Int. Ed., 2005, 44: 4844.
[20] Masson E, Ling X X, Joseph R, Kyeremeh-Mensah L, Lu X Y. RSC Adv., 2012, 2: 1213.
[21] Sokolov M N, Dybtsev D N, Fedin V P. Russ. Chem. Bull. Int. Ed., 2003, 52: 1041.
[22] Gerasko A, Sokolov M N, Fedin V P. Pure Appl. Chem., 2004, 76: 1633.
[23] Fedin V P. Russ. J. Coord. Chem., 2004, 30: 151.
[24] Ni X L, Xiao X, Cong H, Liang L L, Chen K, Cheng X J, Ji N N, Zhu Q J, Xue S F, Tao Z. Chem. Soc. Rev., 2013, 42: 9480.
[25] Zhang F, Yajima T, Li Y Z, Xu G Z, Chen H L, Liu Q T, Yamauchi O. Angew. Chem. Int. Ed., 2005, 44: 3402.
[26] Fang X K, Kogerler P, Isaacs L, Uchida S, Mizuno N. J. Am. Chem. Soc., 2009, 131: 432.
[27] Hoffmann F, Cornelius M, Morell J, Froba M. Angew. Chem. Int. Ed., 2006, 45: 3216.
[28] Lu Y. Angew. Chem. Int. Ed., 2006, 45: 7664.
[29] Ni X L, Lin J X, Zheng Y Y, Wu W S, Zhang Y Q, Xue S F, Zhu Q J, Tao Z, Day A I. Cryst. Growth Des., 2008, 8: 3446.
[30] Li Z F, Wu F, Zhou F G, Ni X L, Feng X, Xiao X, Zhang Y Q, Xue S F, Zhu Q J, Lindoy L F, Clegg J K, Tao Z, Wei G. Cryst. Growth Des., 2010, 10: 5113.
[31] Li Z F, Liang L L, Wu F, Zhou F G, Ni X L, Feng X, Xiao X, Zhang Y Q, Xue S F, Zhu Q J, Clegg J K, Tao Z, Lindoy L F, Wei G. CrystEngComm, 2013, 15: 1994.
[32] Feng X, Du H, Chen K, Xiao X, Luo S X, Xue S F, Zhang Y Q, Zhu Q J, Tao Z, Zhang X Y, Gang W. Cryst. Growth Des., 2010, 10: 2901.
[33] Feng X, Chen K, Zhang Y Q, Xue S F, Zhu Q J, Tao Z, Day A I. CrystEngComm, 2011, 13: 5049.
[34] Chen K, Liang L L, Liu H J, Zhang Y Q, Xue S F, Tao Z, Xiao X, Zhu Q J, Lindoy L F, Wei G. CrystEngComm, 2012, 14: 7994.
[35] Chen K, Hu Y F, Xiao X, Xue S F, Tao Z, Zhang Y Q, Zhu Q J, Liu J X. RSC Adv., 2012, 2: 3217.
[36] Liang L L, Ni X L, Zhao Y, Chen K, Xiao X, Zhang Y Q, Redshaw C, Zhu Q J, Xue S F, Tao Z. Inorg. Chem., 2013, 52: 1909.
[37] Liang L L, Zhao Y, Chen K, Xiao X, Clegg J K, Zhang Y Q, Tao Z, Xue S F, Zhu Q J, Wei G. Polymers, 2013, 5: 418.
[38] Liang L L, Zhao Y, Zhang Y Q, Tao Z, Xue S F, Zhu Q J, Liu J X. CrystEngComm, 2013, 15: 3943.
[39] Zhao Y, Liang L L, Chen K, Zhang T, Xiao X, Zhang Y Q, Tao Z, Xue S F, Zhu Q J. CrystEngComm, 2013, 15: 7987.
[40] Xiao X, Tao Z, Xue S F, Zhang Y Q, Zhu Q J, Liu J X, Wei G. CrystEngComm, 2011, 13: 3794.
[41] Jon S Y, Selvapalam N, Oh D H, Kang J K, Kim S Y, Jeon Y J, Lee J W, Kim K. J. Am. Chem. Soc., 2003, 125: 10186.
[42] Zhao Y, Liang L L, Chen K, Ji N N, Cheng X J, Xiao X, Zhang Y Q, Xue S F, Zhu Q J, Dong N, Tao Z. Dalton Trans., 2014, 43: 929.