利用点击化学制备有机硅材料及应用

夏勇; 姚洪涛; 缪智辉; 王芳; 祁争健; 孙宇

doi:10.7536/PC141111

化学进展 ›› 2015, Vol. 27 ›› Issue (5) :532-538 DOI: 10.7536/PC141111

综述与评价

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利用点击化学制备有机硅材料及应用

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Preparation and Application of Silicone Materials Based on Click Chemistry

Xia Yong¹, Yao Hongtao¹, Miao Zhihui¹, Wang Fang¹, Qi Zhengjian*¹, Sun Yu*²

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摘要

有机硅材料因其特殊结构和性能已成为材料科学研究领域的热点之一,点击化学以其反应条件温和、高效、易于进行且无副产物和高产率等优点受到化学家的广泛关注.本文综述了近年来点击化学在有机硅材料合成中的研究成果,重点介绍了利用点击化学对有机硅化合物的功能化,有机硅两亲性聚合物及有机硅弹性体的合成及在生物医学和光电材料等方面的应用,并对点击化学在新型材料领域中的应用及其发展方向进行了展望.

Abstract

Silicone materials have been investigated widely in broad fields for their versatile and excellent structure and performance. With highly selective and simple orthogonal reactions that do not yield side products and give heteroatom-linked molecular systems with high efficiency under a variety of mild conditions, click chemistry is of great interest in novel material research. The current review is made of the recent research progress in preparation and modification of silicone materials by means of click chemistry, and especially, it introduces the synthesis of polysiloxane based amphiphilic polymer and elastomer and functionalization of polysiloxane. In addition, the applications of these silicone materials in fields of biomedical materials and photoelectric materials are summarized. Finally, we present the trend and future prospects of novel silicone materials based on click chemistry.

Contents
1 Introduction
2 Synthesis of silicone materials by click chemistry
2.1 Functional polysiloxane
2.2 Polysiloxane-based elastomer
2.3 Organosilicon surfactant
2.4 Photoelectric materials
2.5 Other applications
3 Conclusion

Graphical abstract

关键词

有机硅材料 / 点击化学 / 两亲性聚合物 / 弹性体 / 光电材料

Key words

silicone materials / click chemistry / amphiphilic polymers / elastomer / photoelectric materials

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夏勇, 姚洪涛, 缪智辉, 王芳, 祁争健, 孙宇. 利用点击化学制备有机硅材料及应用[J]. 化学进展, 2015, 27(5): 532-538 DOI:10.7536/PC141111

Xia Yong, Yao Hongtao, Miao Zhihui, Wang Fang, Qi Zhengjian, Sun Yu. Preparation and Application of Silicone Materials Based on Click Chemistry[J]. Progress in Chemistry, 2015, 27(5): 532-538 DOI:10.7536/PC141111

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