基于芘的离子荧光化学传感器

钟克利; 郭宝峰; 周雪; 蔡克迪; 汤立军; 金龙一

doi:10.7536/PC150138

化学进展 ›› 2015, Vol. 27 ›› Issue (9) :1230-1239 DOI: 10.7536/PC150138

综述与评论

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基于芘的离子荧光化学传感器

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作者信息 +

Ionics Fluorescent Chemsensor Based on Pyrene

Zhong Keli¹, Guo Baofeng¹, Zhou Xue¹, Cai Kedi¹, Tang Lijun^1*, Jin Longyi^2*

Author information +

文章历史 +

摘要

芘是一种简单的芳香化合物,在溶液中可形成动态的和静态的激基缔合物,在长波长处出现荧光发射峰。利用单体和激基缔合物荧光波长的不同,芘常被用作荧光团来合成各种荧光化学传感器。本文对基于芘的荧光化学传感器的研究进展进行综述,主要包括其在单一阳离子、双阳离子和阴离子识别检测中的分子设计、作用机理和应用,并对该类荧光化学传感器的发展前景进行了展望。

Abstract

Pyrene is a simple aromatic molecule, and it can easily form dynamic and static excimer in solution, which shows long wavelength fluorescence emission. Owing to the different fluorescence emission wavelengths of pyrene monomer and excimer, pyrene is often used as fluorophore for the synthesis of various fluorescent sensors. The progress of pyrene-based fluorescent chemosensors, including the molecular design, mechanism and their application to single-cation, dication as well as anion recognition are summarized. The developing prospect of this type of fluorescent chemosensor is envisaged in this review.

Contents
1 Introduction
2 Fluorescence sensors for single-cation
2.1 Fluorescent sensors for Hg²⁺ 2.2 Fluorescent sensors for Cu²⁺ 2.3 Fluorescent sensors for Zn²⁺ 2.4 Fluorescent sensors for Ag⁺ 2.5 Fluorescent sensors for other single-cation 3 Fluorescence sensors for dication
3.1 Fluorescent sensors for Hg²⁺,Cu²⁺ 3.2 Fluorescent sensors for Hg²⁺,Pb²⁺ 3.3 Fluorescent sensors for other dication
4 Fluorescent sensors for anion
5 Conclusion

Graphical abstract

关键词

芘 / 荧光传感器 / 阳离子 / 阴离子

Key words

pyrene / fluorescent sensors / cation / anion

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钟克利, 郭宝峰, 周雪, 蔡克迪, 汤立军, 金龙一. 基于芘的离子荧光化学传感器[J]. 化学进展, 2015, 27(9): 1230-1239 DOI:10.7536/PC150138

Zhong Keli, Guo Baofeng, Zhou Xue, Cai Kedi, Tang Lijun, Jin Longyi. Ionics Fluorescent Chemsensor Based on Pyrene[J]. Progress in Chemistry, 2015, 27(9): 1230-1239 DOI:10.7536/PC150138

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