种子生长法制备Au@Ag核壳纳米粒子

张东杰, 张丛筠, 卢亚, 郝耀武, 刘亚青

doi:10.7536/PC150140

化学进展 ›› 2015, Vol. 27 ›› Issue (8) :1057-1064 DOI: 10.7536/PC150140

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种子生长法制备Au@Ag核壳纳米粒子

张东杰, 张丛筠, 卢亚, 郝耀武, 刘亚青

作者信息 +

Preparation of Au@Ag Core-Shell Nanoparticles through Seed-Mediated Growth Method

Zhang Dongjie, Zhang Congyun, Lu Ya, Hao Yaowu, Liu Yaqing

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摘要

Au@Ag核壳纳米粒子由于具有优异的局部等离子共振性质 (LSPR),近年来引起人们极大的关注,目前,在成像、催化、信息存储、生化传感等领域已经得到了广泛的应用。在制备Au@Ag核壳纳米粒子的方法中,种子生长法的应用最为广泛,因为它可以实现对Ag壳尺寸及形貌的有效控制。本文综述了影响Au@Ag核壳纳米粒子核壳结构尺寸、形貌、Ag壳厚度以及覆盖均匀程度的一些主要因素,包括Au种子的形貌和浓度、AgNO₃浓度、封端剂、还原剂以及其他一些影响因素。研究发现,Au@Ag核壳纳米粒子在表面增强拉曼光谱 (SERS) 方面具有广泛的应用前景。

Abstract

Au@Ag core-shell nanoparticles have received considerable attention for recent years because of the localized surface plasmon resonance (LSPR). At present, Au@Ag core-shell nanoparticles have been widely used in applications related to photonics, catalysis, information storage, chemical/biological sensing. Due to the well controlled size and morphology of Ag shell, seed-mediated growth method has become the most practical approach to synthesize Au@Ag core-shell nanoparticles. This review provides a short summary of some main factors, such as the morphology and concentration of Au seeds, concentration of AgNO₃, capping agents, reductants and some other factors, which affect the size, morphology, the thickness and uniform coating of Ag shell during the seed-mediated growth of Au@Ag core-shell nanoparticles. Recent studies have shown that Au@Ag core-shell nanoparticles would benefit the further development of the surface-enhanced Raman scattering (SERS).

Contents
1 Introduction
2 Classification of Au@Ag core-shell nanoparticles
3 Preparation of Au@Ag core-shell nanoparticles by seed-mediated growth method
3.1 Precursors
3.2 Capping agents
3.3 Reductants
3.4 Some other factors
4 Conclusion

Graphical abstract

关键词

核壳结构 / 种子生长法 / 纳米粒子

Key words

core-shell structure / seed-mediated growth method / nanoparticle

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张东杰, 张丛筠, 卢亚, 郝耀武, 刘亚青. 种子生长法制备Au@Ag核壳纳米粒子[J]. 化学进展, 2015, 27(8): 1057-1064 DOI:10.7536/PC150140

Zhang Dongjie, Zhang Congyun, Lu Ya, Hao Yaowu, Liu Yaqing. Preparation of Au@Ag Core-Shell Nanoparticles through Seed-Mediated Growth Method[J]. Progress in Chemistry, 2015, 27(8): 1057-1064 DOI:10.7536/PC150140

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