硅纳米晶的制备及其在太阳电池中的应用研究

刘超; 谭瑞琴; 曾俞衡; 王维燕; 黄金华; 宋伟杰

doi:10.7536/PC150162

化学进展 ›› 2015, Vol. 27 ›› Issue (9) :1302-1312 DOI: 10.7536/PC150162

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硅纳米晶的制备及其在太阳电池中的应用研究

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Preparation of Silicon Nanocrystals and Their Applications in Solar Cells

Liu Chao¹, Tan Ruiqin^1*, Zeng Yuheng², Wang Weiyan², Huang Jinhua², Song Weijie²

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摘要

硅纳米晶由于量子限域效应的作用而产生了多种不同于体硅材料的新特性,如荧光效应显著、光学带隙可调等,因而在微电子、光伏、生物医学等领域受到极大的重视。本文介绍了分立的硅纳米晶颗粒和硅纳米晶薄膜的制备方法,并对比了不同方法制备硅纳米晶体的优缺点。着重介绍了硅纳米晶体在太阳电池中应用的几种方式,包括利用纯硅纳米晶薄膜制备太阳电池、硅纳米晶体与有机薄膜基质结合形成复合结构太阳电池、含有硅纳米晶颗粒的硅墨水在太阳电池中的应用等。

Abstract

Because of the quantum confinement effect, silicon nanocrystals exhibit some new features different from bulk silicon, such as enhanced photoluminescence and adjustable optical band gap, etc. Silicon nanocrystals have attracted much attention in the fields of microelectronics, photovoltaic, biomedicine and so on. In this paper, the different preparation methods of freestanding silicon nanocrystals and silicon nanocrystals embedded in thin films are reviewed, the advantages and disadvantages of different preparation methods are analyzed. Furthermore, the applications of silicon nanocrystals are focused on photovoltaic, including solar cells made up of pure silicon-nanocrystal films, organic solar cells combined with silicon nanocrystals, and silicon nanocrystals ink for solar cells.

Contents
1 Introduction
2 Synthesis of Si nanocrystals
2.1 Synthesis of freestanding Si nanocrystals
2.2 Synthesis of Si nanocrystals embedded in films
3 Applications of Si nanocrystals in solar cells
3.1 Si nanocrystal films as the emitter or optical absorb layer in solar cells
3.2 Organic solar cells combined with silicon nanocrystals
3.3 Silicon nanocrystals ink for solar cells
4 Conclusion

关键词

硅纳米晶 / 硅量子点 / 制备 / 太阳电池

Key words

silicon nanocrystals / silicon quantum dot / preparation / solar cells

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刘超, 谭瑞琴, 曾俞衡, 王维燕, 黄金华, 宋伟杰. 硅纳米晶的制备及其在太阳电池中的应用研究[J]. 化学进展, 2015, 27(9): 1302-1312 DOI:10.7536/PC150162

Liu Chao, Tan Ruiqin, Zeng Yuheng, Wang Weiyan, Huang Jinhua, Song Weijie. Preparation of Silicon Nanocrystals and Their Applications in Solar Cells[J]. Progress in Chemistry, 2015, 27(9): 1302-1312 DOI:10.7536/PC150162

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Received	Published	Revised
2015-01-01	2015-09-15	2015-05-01
Online Date
2015-06-24

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