有序介孔硅材料主-客体组装及应用研究

张晓东; 董寒; 王吟; 崔立峰

doi:10.7536/PC150351

化学进展 ›› 2015, Vol. 27 ›› Issue (10) :1374-1383 DOI: 10.7536/PC150351

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有序介孔硅材料主-客体组装及应用研究

张晓东*, 董寒, 王吟*, 崔立峰*

作者信息 +

Host-Guest Assembly and Application of Ordered Mesoporous Silica Materials

Zhang Xiaodong*, Dong Han, Wang Yin*, Cui Lifeng*

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摘要

介孔分子筛材料具有高的比表面积和孔体积、发达的孔结构、可控的形貌、表面基团可功能化、耐热、无毒无害等特点,以其为研究核心,在学术界和工业界均具有广泛的应用前景。通过模板法合成孔径在纳米范围的有序介孔硅材料,其具有从一维到三维高度规整的孔道结构,在吸附、分离、催化、生物医药工程等领域展现出巨大的应用潜能。利用具有几何和电子束缚特性的有序规整孔道作为微反应器来进行纳米结构主-客体组装,势必会显著增强其应用价值。本文以有序介孔硅材料规整孔道为基础和出发点,结合本课题组多年的研究结果,系统概述了近几年客体在有序介孔硅材料孔道内组装的进展,探讨了主-客体组装过程中的影响因素和合成机理。最后,着重对主-客体组装材料在环境净化和生物医药工程领域的应用进行概述。

Abstract

Mesoporous molecular sieve materials have been widely studied in academic and industry due to their remarkable physicochemical properties, including the high specific surface area and pore volume, extensively pore structure, controllable morphology, surface functionalization, good thermal stability, non-toxic and harmless. Ordered mesoporous silica materials, prepared by template method, possess well-ordered periodicity and one dimension to three dimensional interconnected pore structures that are of interest for numerous applications, such as adsorption, separation, catalysis and biomedicine engineering. In order to utilize the geometric and electronic bound properties of ordered-mesochannels as micro reactor, it is necessary to develop host-guest assembly from fundamental and application point of view. In this review, combining with the latest work in our group, ordered mesochannels of mesoporous silica materials are used as a base and starting point. The research progress of host-guest assembly in recent years are introduced systematically. Influence factors, including the choice of templates, organic groups and guest, preparation methods and other necessary modifications, and synthetic mechanism in the process of host-guest assembly are also discussed. Finally, host-guest assembly of ordered mesoporous silica materials in environmental purification and biomedical engineering application are summarized.

Contents
1 Introduction
2 The assembly of ordered mesoporous silica materials
2.1 Classification and characteristics of ordered mesoporous silica materials
2.2 Host- the assembly of metal ions
2.3 Guest-the assembly of metal particles
2.4 Guest-the assembly of MOFs
2.5 Guest-the assembly of enzymes and drug molecules
3 Applications
3.1 Environmental purification
3.2 Biology field
4 Conclusion and outlook

Graphical abstract

关键词

有序介孔硅材料 / 限域 / 纳米粒子 / 环境净化 / 催化 / 主-客体

Key words

ordered mesoporous silica material / confined / nanoparticles / environmental purification / catalysis / host-guest

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张晓东, 董寒, 王吟, 崔立峰. 有序介孔硅材料主-客体组装及应用研究[J]. 化学进展, 2015, 27(10): 1374-1383 DOI:10.7536/PC150351

Zhang Xiaodong, Dong Han, Wang Yin, Cui Lifeng. Host-Guest Assembly and Application of Ordered Mesoporous Silica Materials[J]. Progress in Chemistry, 2015, 27(10): 1374-1383 DOI:10.7536/PC150351

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