石墨烯基气凝胶催化还原特性及其应用

陈晓燕, 孙怡然, 于飞, 陈君红, 马杰

doi:10.7536/PC150430

化学进展 ›› 2015, Vol. 27 ›› Issue (11) :1542-1554 DOI: 10.7536/PC150430

综述与评论

扫码查看或转发全文

石墨烯基气凝胶催化还原特性及其应用

陈晓燕, 孙怡然, 于飞, 陈君红, 马杰

作者信息 +

The Catalytic Properties for Reduction of Graphene-Based Aerogels and Their Applications

Chen Xiaoyan, Sun Yiran, Yu Fei, Chen Junhong, Ma Jie

Author information +

文章历史 +

摘要

石墨烯基气凝胶(GA)是一种内部连通的三维石墨烯宏观体,其在继承了石墨烯良好的化学稳定性和优良催化性能的同时拥有更高的比表面积和导电性。GA由于其优越的性能和独特的结构在催化、能量存储、吸附等领域得到广泛的应用。本文主要从GA催化还原特性展开,综述了具有不同催化性能的石墨烯基气凝胶的制备方法,将其总结归纳分为GA、掺杂型GA、复合型GA以及掺杂复合型GA四种类型,并详细介绍了制备方法对石墨烯基气凝胶催化性能的影响。石墨烯基气凝胶因具有优良的电化学活性和催化特性,在燃料电池、染料敏化太阳能电池、微生物电解池和电化学传感器等领域具有广泛的应用前景。最后对石墨烯基气凝胶在催化领域的应用前景进行分析和展望。

Abstract

Graphene-based aerogels(GA) are three-dimensional macrostructures of graphene with interconnected networks. While inheriting the excellent chemical stability and catalytic performance of graphene, GA exhibits higher specific surface area and excellent conductivity comparing to two-dimensional structure. Because of the superior properties and unique structure, GA are widely applied in catalysis, energy storage and adsorption. This review is expanded around the catalytic reduction performance of GA. Firstly, the preparation methods of GA with different catalytic properties are reviewed, which are classified into four types as graphene aerogels, doped GA, GA composite and doped GA composite. Then the influence on catalytic performance of GA prepared with different methods is introduced in detail. The admirable electrochemical and catalytic performance of GA indicates wide application prospects in fuel cells, dye-sensitized solar cells, microbial electrolysis cells and electrochemical sensors. Finally, the catalysis applications of GA are analysed and outlooked.

Contents
1 Introduction
2 GA and its catalytic properties
3 Synthesis and modification of catalytical active GA
3.1 Preparation of pure GA
3.2 Preparation of doped GA
3.3 Preparation of GA composite
3.4 Preparation of doped GA composite
4 Applications of GA in reduction catalyst
4.1 Applications in positive electrode of fuel cells
4.2 Applications in counter electrode of dye-sensitized solar cells
4.3 Applications in cathode of microbial electrolysis cells
4.4 Applications in hydrogen peroxide electro-chemical sensors
5 Conclusion and outlook

Graphical abstract

关键词

石墨烯气凝胶 / 催化还原 / 制备方法 / 掺杂 / 复合

Key words

graphene aerogels / catalytic reduction / preparation method / doping / composite

引用本文

引用格式 ▾

陈晓燕, 孙怡然, 于飞, 陈君红, 马杰. 石墨烯基气凝胶催化还原特性及其应用[J]. 化学进展, 2015, 27(11): 1542-1554 DOI:10.7536/PC150430

Chen Xiaoyan, Sun Yiran, Yu Fei, Chen Junhong, Ma Jie. The Catalytic Properties for Reduction of Graphene-Based Aerogels and Their Applications[J]. Progress in Chemistry, 2015, 27(11): 1542-1554 DOI:10.7536/PC150430

登录浏览全文

4963

注册一个新账户忘记密码

参考文献

原文顺序 | 出版日期 | 本文引用

[1] Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A. Science, 2004, 306:666.
[2] Geim A K, Novoselov K S. Nature Materials, 2007, 6:183.
[3] Huang X, Zeng Z, Fan Z, Liu J, Zhang H. Advanced Materials, 2012, 24:5979.
[4] Chao D, Zhu C, Xia X, Liu J, Zhang X, Wang J, Liang P, Lin J, Zhang H, Shen Z X. Nano Letters, 2014, 15:565.
[5] Wang X, Shi G. Energy & Environmental Science, 2015, 8:790.
[6] Wu Z S, Sun Y, Tan Y Z, Yang S, Feng X, Müllen K. Journal of the American Chemical Society, 2012, 134:19532.
[7] Kistler S. Journal of Physical Chemistry, 1932, 36:52.
[8] Ebelmen J. Annale de Chimie et de Physique, 1846, 16:129.
[9] Geffcken W. Kolloid-Zeitschrift, 1939, 86:55.
[10] Dislich H. Angewandte Chemie International Edition in English, 1971, 10:363.
[11] Yoldas B E. Journal of Materials Science, 1975, 10:1856.
[12] Ramsey D E, Davis R F. American Ceramic Society Bulletin, 1975, 54:312.
[13] Tewari P H, Hunt A J, Lofftus K D. Materials Letters, 1985, 3:363.
[14] Jones S M, Sakamoto J. Applications of Aerogels in Apace Exploration, in Aerogels Handbook. Springer, 2011. 721.
[15] Li C, Shi G. Advanced Materials, 2014, 26:3992.
[16] Li C, Shi G. Nanoscale, 2012, 4:5549.
[17] Biener J, Stadermann M, Suss M, Worsley M A, Biener M M, Rose K A, Baumann T F. Energy & Environmental Science, 2011, 4:656.
[18] Kavan L, Yum J H, Grätzel M. ACS Nano, 2010, 5:165.
[19] Schniepp H C, Li J L, McAllister M J, Sai H, Herrera-Alonso M, Adamson D H, Prud'homme R K, Car R, Saville D A, Aksay I A. Journal of Physical Chemistry B, 2006, 110:8535.
[20] Fan X, Zheng W T, Kuo J L. ACS Applied Materials & Interfaces, 2012, 4:2432.
[21] Zhao Y, Kim Y H, Dillon A C, Heben M J, Zhang S B. Physical Review Letters, 2005, 94:155504.
[22] Yoon M, Yang S, Wang E, Zhang Z. Nano Letters, 2007, 7:2578.
[23] Hu X, Wu Y, Li H, Zhang Z. Journal of Physical Chemistry C, 2010, 114:9603.
[24] Novoselov K S, Geim A K, Morozov S, Jiang D, Zhang Y, Dubonos S, Grigorieva I, Firsov A. Science, 2004, 306:666.
[25] Sun H, Xu Z, Gao C. Advanced Materials, 2013, 25:2554.
[26] Kepic D, Markovic Z, Nikolic M, Dramicanin M, Cincovic M M, Markovic B T, Holclajtnerantunovic I. Journal of Optoelectronics & Advanced Materials, 2012, 14:95.
[27] Zhang X, Sui Z, Xu B, Yue S, Luo Y, Zhan W, Liu B. J.Mater.Chem., 2011, 18:6494.
[28] Berger C, Song Z, Li T, Li X, Ogbazghi A Y, Feng R, Dai Z, Marchenkov A N, Conrad E H, First P N. Journal of Physical Chemistry B, 2004, 108:19912.
[29] Srivastava S K, Vankar V D, Kumar V. Nanoscale Research Letters, 2008, 3:25.
[30] Stankovich S, Dikin D A, Piner R D, Kohlhaas K A, Kleinhammes A, Jia Y, Wu Y, Nguyen S T, Ruoff R S. Carbon, 2007, 45:1558.
[31] Xia X, Chao D, Zhang Y, Shen Z, Fan H. Nano Today, 2014, 9:785.
[32] Li Y, Chen J, Huang L, Li C, Hong J D, Shi G. Advanced Materials, 2014, 26:4789
[33] Chen Z, Ren W, Gao L, Liu B, Pei S, Cheng H M. Nature Materials, 2011, 10:424.
[34] Min B H, Kim D W, Kim K H, Choi H O, Jang S W, Jung H T, Min B H, Kim D W, Kim K H, Choi H O. Carbon, 2014:446.
[35] Yong Y C, Dong X C, Chan-Park M B, Song H, Chen P. ACS Nano, 2012, 6:2394.
[36] Batzill M. Surface Science Reports, 2012, 67:83.
[37] Pettes M T, Ji H, Ruoff R S, Li S. Nano Letters, 2012, 12:2959.
[38] Choi B G, Yang M H, Hong W H, Choi J W, Yun S H. ACS Nano, 2012, 6:4020.
[39] Vickery J L, Patil A J, Mann S. Advanced Materials, 2009, 21:2180.
[40] Estevez L, Kelarakis A, Gong Q, Da'As E H, Giannelis E P. Journal of the American Chemical Society, 2011, 133:6122.
[41] Bai H, Li C, Wang X, Shi G. Chemical Communications, 2010, 14:2376.
[42] Tang Z, Shen S, Zhuang J, Wang X. Angewandte Chemie International Edition, 2010, 49:4707.
[43] Zu S Z and Han B H. Journal of Physical Chemistry C, 2009, 113:13651.
[44] Yin S, Goldovsky Y, Herzberg M, Liu L, Sun H, Zhang Y, Meng F, Cao X, Sun D D, Chen H. Advanced Functional Materials, 2013, 23:2972.
[45] Yang X, Zhu J, Qiu L, Li D. Advanced Materials, 2011, 23:2833.
[46] Zhang L L, Zhao X, Stoller M D, Zhu Y, Ji H, Murali S, Wu Y, Perales S, Clevenger B, Ruoff R S. Nano Letters, 2012, 12:1806.
[47] Zhu Y, Murali S, Stoller M D, Ganesh K J, Cai W, Ferreira P J, Pirkle A, Wallace R M, Cychosz K A, Thommes M. Science, 2011, 332:1537.
[48] Hummers Jr W S, Offeman R E. Journal of the American Chemical Society, 1958, 80:1339.
[49] Xu Y, Lu Z, Hua B, Hong W, Li C, Shi G. Journal of the American Chemical Society, 2009, 131:13490.
[50] Xu Y, Sheng K, Li C, Shi G. ACS Nano, 2010, 4:4324.
[51] Xu Y, Bai H, Lu G, Li C, Shi G. Journal of the American Chemical Society, 2008, 130:5856.
[52] Hong W, Xu Y, Li C, Lu G, Shi G. Electrochemistry Communications, 2008, 10:1555.
[53] Wu X, Zhou J, Xing W, Wang G, Cui H, Zhuo S, Xue Q, Yan Z, Qiao S Z. Journal of Materials Chemistry, 2012, 22:23186.
[54] Cheng W Y, Wang C C, Lu S Y. Carbon, 2013, 54:291.
[55] Chen W, Yan L. Nanoscale, 2011, 3:3132.
[56] Jeon K J, Lee Z, Pollak E, Moreschini L, Bostwick A, Park C M, Mendelsberg R, Radmilovic V, Kostecki R, Richardson T J. ACS Nano, 2011, 5:1042.
[57] ZHU Z F, CHENG S, DONG X N. Journal of Functional Materials, 2013, 21:002.
[58] Kong X K, Chen Q W, Lun Z Y. Journal of Materials Chemistry A, 2014, 2:610.
[59] Zhang C, Mahmood N, Yin H, Liu F, Hou Y. Advanced Materials, 2013, 25:4932.
[60] Choi C H, Chung M W, Kwon H C, Park S H, Woo S I. Journal of Materials Chemistry A, 2013, 1:3694.
[61] Liu H, Liu Y, Zhu D. Journal of Materials Chemistry, 2011, 21:3335.
[62] Choi C H, Chung M W, Kwon H C, Park S H, Woo S I. Journal of Materials Chemistry A, 2013, 1:3694.
[63] Zhou X, Bai Z, Wu M, Qiao J, Chen Z. Journal of Materials Chemistry A, 2015, 3:3343.
[64] Wang M, Wang J, Hou Y, Shi D, Wexler D, Poynton S D, Slade R C T, Zhang W, Liu H, Chen J. ACS Applied Materials & Interfaces, 2015, 7:7066.
[65] Yang S, Zhi L, Tang K, Feng X, Maier J, Müllen K. Advanced Functional Materials, 2012, 22:3634.
[66] Ahn H J, Kim I H, Yoon J C, Kim S I, Jang J H. Chemical Communications, 2014, 50:2412.
[67] Su Y, Zhang Y, Zhuang X, Li S, Wu D, Zhang F, Feng X. Carbon, 2013, 62:296.
[68] Wu Z S, Winter A, Chen L, Sun Y, Turchanin A, Feng X, Müllen K. Advanced Materials, 2012, 24:5130.
[69] Jeong H M, Lee J W, Shin W H, Choi Y J, Shin H J, Kang J K, Choi J W. Nano Letters, 2011, 11:2472.
[70] Wu Z S, Ren W, Xu L, Li F, Cheng H M. ACS Nano, 2011, 5:5463.
[71] Wang S, Iyyamperumal E, Roy A, Xue Y, Yu D, Dai L. Angewandte Chemie International Edition, 2011, 50:11960.
[72] Qiu Y. Physical Chemistry Chemical Physics, 2011, 13:12554.
[73] Tang G, Jiang Z G, Li X, Zhang H B, Dasari A, Yu Z Z. Carbon, 2014, 77:592.
[74] Zhang J, Cao Y, Feng J, Wu P. Journal of Physical Chemistry C, 2012, 116:8063.
[75] Jiang X, Yang X, Zhu Y, Shen J, Fan K, Li C. Journal of Power Sources, 2013, 237:178.
[76] Tang H, Sui Y, Zhu X, Bao Z. Nanoscale Research Letters, 2015, 10:260.
[77] Chen L, Wang X, Zhang X, Zhang H. Journal of Materials Chemistry, 2012, 22:22090.
[78] Fan Z, Yan J, Zhi L, Zhang Q, Wei T, Feng J, Zhang M, Qian W, Wei F. Advanced Materials, 2010, 22:3723.
[79] Ma Y, Sun L, Huang W, Zhang L, Zhao J, Fan Q, Huang W. Journal of Physical Chemistry C, 2011, 115:24592.
[80] Zhang D, Wen X, Shi L, Yan T, Zhang J. Nanoscale, 2012, 4:5440.
[81] Fan W, Miao Y E, Huang Y, Tjiu W W, Liu T. RSC Advances, 2015, 5:9228.
[82] Ma J, Li C, Yu F, Chen J. ChemSusChem, 2014, 7:3304.
[83] Tan C, Cao J, Khattak A M, Cai F, Jiang B, Yang G, Hu S. Journal of Power Sources, 2014, 270:28.
[84] Yin H, Zhang C, Liu F, Hou Y. Advanced Functional Materials, 2014, 24:2930.
[85] Hou Y, Zhang B, Wen Z, Cui S, Guo X, He Z, Chen J. Journal of Materials Chemistry A, 2014, 2:13795.
[86] Wei H, Xu M W, Bao S J, Yang F, Chai H. RSC Advances, 2014, 4:16979.
[87] Cao Z, Zou Y, Xiang C, Sun L X, Xu F. Analytical Letters, 2007, 40:2116.
[88] Ohnuki H, Saiki T, Kusakari A, Endo H, Ichihara M, Izumi M. Langmuir, 2007, 23:4675.