石墨烯基水凝胶的研究进展

刘静静; 楚晖娟; 魏宏亮; 祝红征; 朱靖; 何娟

doi:10.7536/PC150512

化学进展 ›› 2015, Vol. 27 ›› Issue (11) :1591-1603 DOI: 10.7536/PC150512

综述与评论

扫码查看或转发全文

石墨烯基水凝胶的研究进展

刘静静, 楚晖娟, 魏宏亮*, 祝红征, 朱靖, 何娟

作者信息 +

Progress in Graphene-Based Hydrogels

Liu Jingjing, Chu Huijuan, Wei Hongliang*, Zhu Hongzheng, Zhu Jing, He Juan

Author information +

文章历史 +

摘要

石墨烯具有独特的导电、导热和力学性能,既能够自组装为电化学性能优良的石墨烯水凝胶,又可以与小分子和聚合物进行复合制备多功能性复合水凝胶,大幅度地拓展了传统水凝胶的应用范围。本文主要分为四部分来综述近些年来石墨烯基水凝胶的研究进展。第一部分简要介绍了石墨烯的研究背景和石墨烯基水凝胶的研究意义。第二部分主要根据石墨烯基水凝胶的组成将其分为石墨烯水凝胶、石墨烯/小分子和石墨烯/聚合物复合水凝胶三类,分别介绍了它们的制备方法、形成机理和凝胶性能。其中,对石墨烯/小分子复合水凝胶的介绍以石墨烯基超分子水凝胶为主,而对石墨烯/聚合物复合水凝胶的介绍以智能型水凝胶为主。第三部分主要介绍了石墨烯基水凝胶在超级电容器、水处理、控释药物、微流体开关、催化剂载体等方面的应用和发展。最后,对该领域所面临的挑战进行了总结和展望。

Abstract

The unique properties of graphene, such as high electrical conductivity, high thermal conductivity and excellent mechanical properties, have made graphene not only a gelator to self-assemble into the graphene hydrogel with extraordinary electromechanical performance, but also a filler to blend with small molecules and macromolecules for the preparation of multifunctional graphene-based hybrid hydrogels, which fully exploits the practical applications of traditional hydrogels. Herein, recent progress in graphene-based hybrid hydrogels has been reviewed and the whole article can be divided into four sections. In the first section, a brief introduction on the development of graphene as well as the significance of the fabrication of graphene-based hydrogels is devoted. In the second section, the graphene-based hybrid hydrogels are roughly divided into three categories: graphene hydrogel, graphene/small molecules and graphene/macromolecules hybrid hydrogels according to their composition. The preparation methods of various hydrogels, as well as the mechanisms of their gelation process and the hydrogels' performance, are also presented. With the presentation of graphene/small molecules hybrid hydrogels, emphasis is given to the development of graphene-based supramolecular hydrogels, while with the presentation of graphene/macromolecules hybrid hydrogels, graphene-based intelligent hydrogels contributed a much higher proportion. In the third section, the applications of graphene-based hybrid hydrogels in supercapacitor, water purification, controlled release drug, microfluidic switch, catalyst support, etc., are introduced respectively. Finally, challenges in the development of graphene-based hydrogels are summarized briefly and future prospect is given as well.

Contents
1 Introduction
2 Categories of graphene-based hydrogels
2.1 Graphene hydrogels
2.2 Graphene/small molecules hybrid hydrogels
2.3 Graphene/macromolecules hybrid hydrogels
3 Applications of graphene-based hydrogels
3.1 Supercapacitor
3.2 Water purification
3.3 Drug-controlled release
3.4 Microfluidic switch
3.5 Catalyst support
3.6 Others
4 Conclusion

Graphical abstract

关键词

石墨烯 / 复合水凝胶 / 凝胶化 / 自组装 / 药物控释

Key words

graphene / hybrid hydrogels / gelation / self-assembly / drug-controlled release

引用本文

引用格式 ▾

刘静静, 楚晖娟, 魏宏亮, 祝红征, 朱靖, 何娟. 石墨烯基水凝胶的研究进展[J]. 化学进展, 2015, 27(11): 1591-1603 DOI:10.7536/PC150512

Liu Jingjing, Chu Huijuan, Wei Hongliang, Zhu Hongzheng, Zhu Jing, He Juan. Progress in Graphene-Based Hydrogels[J]. Progress in Chemistry, 2015, 27(11): 1591-1603 DOI:10.7536/PC150512

登录浏览全文

4963

注册一个新账户忘记密码

参考文献

原文顺序 | 出版日期 | 本文引用

[1] Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A. Science, 2004, 306:666.
[2] Sutter P W, Flege J I, Sutter E A. Nat. Mater., 2008, 7:406.
[3] Berger C, Song Z, Li X, Wu X, Brown N, Naud C, Mayou D, Li T, Hass J, Marchenkov A N, Conrad E H, First P N, de Heer W A. Science, 2006, 312:1191.
[4] Kim K S, Zhao Y, Jang H, Lee S Y, Kim J M, Kim K S, Ahn J-H, Kim P, Choi J-Y, Hong B H. Nature, 2009, 457:706.
[5] Eizenberg M, Blakely J M. Surf. Sci., 1979, 82:228.
[6] Rangappa D, Sone K, Wang M, Gautam U K, Golberg D, Itoh H, Ichihara M, Honma I. Chem. Eur. J., 2010, 16:6488.
[7] Park S, Ruoff R S. Nat. Nanotechnol., 2009, 4:217.
[8] Dreyer D R, Park S, Bielawski C W, Ruoff R S. Chem. Soc. Rev., 2010, 39:228.
[9] Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958, 80:1339.
[10] Si Y, Samulski E T. Nano Lett., 2008, 8:1679.
[11] Tung V C, Allen M J, Yang Y, Kaner R B. Nat. Nanotechnol., 2009, 4:25.
[12] Shen B, Lu D, Zhai W, Zheng W. J. Mater. Chem. C, 2013, 1:50.
[13] McAllister M J, Li J L, Adamson D H, Schniepp H C, Abdala A A, Liu J, Herrera-Alonso M, Milius D L, Car R, Prud'homme R K, Aksay I A. Chem. Mater., 2007, 19:4396.
[14] Zhang H B, Wang J W, Yan Q, Zheng W G, Chen C, Yu Z Z. J. Mater. Chem., 2011, 21:5392.
[15] Peak C W, Wilker J J, Schmidt G. Colloid and Polymer Science, 2013, 291:2031.
[16] Li C, Shi G. Adv. Mater., 2014, 26:3992.
[17] Nardecchia S, Carriazo D, Ferrer M L, Gutierrez M C, del Monte F. Chem. Soc. Rev., 2013, 42:794.
[18] Xu Y, Sheng K, Li C, Shi G. ACS Nano, 2010, 4:4324.
[19] Zhang L, Shi G. J. Phys. Chem. C, 2011, 115:17206.
[20] Sui Z, Zhang X, Lei Y, Luo Y. Carbon, 2011, 49:4314.
[21] Zhang X, Sui Z, Xu B, Yue S, Luo Y, Zhan W, Liu B. J. Mater. Chem., 2011, 21:6494.
[22] Sheng K X, Xu Y X, Li C, Shi G Q. New Carbon Mater., 2011, 26:9.
[23] Zhang L, Chen G, Hedhili M N, Zhang H, Wang P. Nanoscale, 2012, 4:7038.
[24] Bi H, Yin K, Xie X, Zhou Y, Wan N, Xu F, Banhart F, Sun L, Ruoff R S. Adv. Mater., 2012, 24:5124.
[25] Li H, Zhang B, Lu C. Mater. Lett., 2014, 129:24.
[26] Compton O C, An Z, Putz K W, Hong B J, Hauser B G, Brinson L C, Nguyen S T. Carbon, 2012, 50:3399.
[27] Rybtchinski B. ACS Nano, 2011, 5:6791.
[28] Adhikari B, Biswas A, Banerjee A. Langmuir, 2012, 28:1460.
[29] Delbecq F, Endo H, Kono F, Kikuchi A, Kawai T. Polymer, 2013, 54:1064.
[30] Ogoshi T, Ichihara Y, Yamagishi T A, Nakamoto Y. Chem. Commun., 2010, 46:6087.
[31] Adhikari B, Biswas A, Banerjee A. ACS Appl. Mater. Interfaces, 2012, 4:5472.
[32] Cheng Q Y, Zhou D, Gao Y, Chen Q, Zhang Z, Han B H. Langmuir, 2012, 28:3005.
[33] Ai W, Du Z-Z, Liu J-Q, Zhao F, Yi M D, Xie L H, Shi N E, Ma Y W, Qian Y, Fan Q-L, Yu T, Huang W. RSC Adv., 2012, 2:12204.
[34] Qiu L, Yang X, Gou X, Yang W, Ma Z F, Wallace G G, Li D. Chem. Eur. J., 2010, 16:10653.
[35] Zhang C, Ren L, Wang X, Liu T. J. Phys. Chem. C, 2010, 114:11435.
[36] Cong H P, Ren X C, Wang P, Yu S-H. ACS Nano, 2012, 6:2693.
[37] Szejtli J. Chem. Rev., 1998, 98:1743.
[38] Zu S Z, Han B H. J. Phys. Chem. C, 2009, 113:13651.
[39] Liu J, Chen G, Jiang M. Macromolecules, 2011, 44:7682.
[40] Luan V H, Tien H N, Hoa L T, Hien N T M, Oh E S, Chung J, Kim E J, Choi W M, Kong B S, Hur S H. J. Mater. Chem. A, 2013, 1:208.
[41] van Hoang L, Chung J S, Kim E J, Hur S H. Chem. Eng. J., 2014, 246:64.
[42] Hu H, Zhao Z, Wan W, Gogotsi Y, Qiu J. Adv. Mater., 2013, 25:2219.
[43] Garcia A, Marquez M, Cai T, Rosario R, Hu Z, Gust D, Hayes M, Vail S A, Park C D. Langmuir, 2007, 23:224.
[44] Osada Y, Gong J P. Prog. Polym. Sci., 1993, 18:187.
[45] Liu F, Urban M W. Prog. Polym. Sci., 2010, 35:3.
[46] Alzari V, Nuvoli D, Sanna R, Peponi L, Piccinini M, Bon S B, Marceddu S, Valentini L, Kenny J M, Mariani A. Colloid Polym. Sci., 2013, 291:2681.
[47] Liang J, Huang Y, Zhang L, Wang Y, Ma Y, Guo T, Chen Y. Adv. Funct. Mater., 2009, 19:2297.
[48] Kim J E, Lee H S. Polymer, 2014, 55:287.
[49] Sridhar V, Oh I K. J. Colloid Interf. Sci., 2010, 348:384.
[50] Zhang L, Wang Z, Xu C, Li Y, Gao J, Wang W, Liu Y. J. Mater. Chem., 2011, 21:10399.
[51] Bai H, Li C, Wang X, Shi G. Chem. Commun., 2010, 46:2376.
[52] Lu N, Liu J, Li J, Zhang Z, Weng Y, Yuan B, Yang K, Ma Y. J. Mater. Chem. B, 2014, 2:3791.
[53] Zhu C H, Lu Y, Peng J, Chen J F, Yu S H. Adv. Funct. Mater., 2012, 22:4017.
[54] Huang S, Shen J, Li N, Ye M. J. Appl. Polym. Sci., 2015, doi:10.1002/app.41530.
[55] Wu Y, Cai M, Pei X, Liang Y, Zhou F. Macromol. Rapid Commun., 2013, 34:1785.
[56] Zhang E, Wang T, Lian C, Sun W, Liu X, Tong Z. Carbon, 2013, 62:117.
[57] Hou C, Zhang Q, Zhu M, Li Y, Wang H. Carbon, 2011, 49:47.
[58] Hou C, Zhang Q, Li Y, Wang H. Carbon, 2012, 50:1959.
[59] Ma X, Li Y, Wang W, Ji Q, Xia Y. Eur. Polym. J., 2013, 49:389.
[60] Jang J H, Kim J K, Huh D S. Macromol. Res., 2014, 22:1132.
[61] Lee S, Lee H, Sim J H, Sohn D. Macromol. Res., 2014, 22:165.
[62] Faghihi S, Karimi A, Jamadi M, Imani R, Salarian R. Mater. Sci. Eng. C, 2014, 38:299.
[63] Huang Y, Zeng M, Ren J, Wang J, Fan L, Xu Q. Colloids Surf. A, 2012, 401:97.
[64] Shen J, Yan B, Li T, Long Y, Li N, Ye M. Compos. Part A-Appl. S., 2012, 43:1476.
[65] Liu J, Cui L, Kong N, Barrow C J, Yang W. Eur. Polym. J., 2014, 50:9.
[66] Shen J, Yan B, Li T, Long Y, Li N, Ye M. Soft Matter, 2012, 8:1831.
[67] Liu R, Liang S, Tang X-Z, Yan D, Li X, Yu Z Z. J. Mater. Chem., 2012, 22:14160.
[68] Shi Y, Ma C, Peng L, Yu G. Adv. Funct. Mater., 2015, 25:1219.
[69] Sun S, Wu P. J. Mater. Chem., 2011, 21:4095.
[70] Li Z, Shen J, Ma H, Lu X, Shi M, Li N, Ye M. Mater. Sci. Eng. C, 2013, 33:1951.
[71] Cong H P, Wang P, Yu S H. Chem. Mater., 2013, 25:3357.
[72] Lei W, Si W, Xu Y, Gu Z, Hao Q. Microchim. Acta, 2014, 181:707.
[73] Yuan M, Liu A, Zhao M, Dong W, Zhao T, Wang J, Tang W. Sens. Actuators, B, 2014, 190:707.
[74] Chen S, Bao P, Huang X, Sun B, Wang G. Nano Res., 2014, 7:85.
[75] Zhang L L, Zhao X S. Chem. Soc. Rev., 2009, 38:2520.
[76] Li N, Tang S, Dai Y, Meng X. J. Mater. Sci., 2014, 49:2802.
[77] Stoller M D, Park S, Zhu Y, An J, Ruoff R S. Nano Lett., 2008, 8:3498.
[78] Wang Y, Shi Z Q, Huang Y, Ma Y F, Wang C Y, Chen M M, Chen Y S. J. Phys. Chem. C, 2009, 113:13103.
[79] Quan H, Shao Y, Hou C, Zhang Q, Wang H, Li Y. Mater. Sci. Eng. B, 2013, 178:769.
[80] Chang Y, Han G, Yuan J, Fu D, Liu F, Li S. J. Power Sources, 2013, 238:492.
[81] Xu Y, Huang X, Lin Z, Zhong X, Huang Y, Duan X. Nano Res., 2013, 6:65.
[82] Zhang F, Xiao F, Dong Z H, Shi W. Electrochim. Acta, 2013, 114:125.
[83] She X, Sun P, Yu X, Zhang Q, Wu Y, Li L, Huang Y, Shang S, Jiang S. J. Inorg. Oraganomet. P., 2014, 24:884.
[84] Wang H, Xu Z, Yi H, Wei H, Guo Z, Wang X. Nano Energy, 2014, 7:86.
[85] Chen P, Yang J J, Li S S, Wang Z, Xiao T Y, Qian Y H, Yu S H. Nano Energy, 2013, 2:249.
[86] Zhao Y, Liu J, Hu Y, Cheng H, Hu C, Jiang C, Jiang L, Cao A, Qu L. Adv. Mater., 2013, 25:591.
[87] Xu J, Wang L, Zhu Y. Langmuir, 2012, 28:8418.
[88] Hou C, Zhang Q, Li Y, Wang H. J. Hazard. Mater., 2012, 205:229.
[89] Cong H P, Qiu J H, Yu S H. Small, 2015, 11:1165.
[90] Sun H, Xu Z, Gao C. Adv. Mater., 2013, 25:2554.
[91] Tiwari J N, Mahesh K, Le N H, Kemp K C, Timilsina R, Tiwari R N, Kim K S. Carbon, 2013, 56:173.
[92] Xu Y, Wu Q, Sun Y, Bai H, Shi G. ACS Nano, 2010, 4:7358.
[93] Wang X, Liu Z, Ye X, Hu K, Zhong H, Yu J, Jin M, Guo Z. Appl. Surf. Sci., 2014, 308:82.
[94] Gao H, Sun Y, Zhou J, Xu R, Duan H. ACS Appl. Mater. Interfaces, 2013, 5:425.
[95] Chen Y, Chen L, Bai H, Li L. J. Mater. Chem. A, 2013, 1:1992.
[96] Liu Z, Robinson J T, Sun X, Dai H. J. Am. Chem. Soc., 2008, 130:10876.
[97] Wang J, Liu C, Shuai Y, Cui X, Nie L. Colloids Surf. B, 2014, 113:223.
[98] Ehrbar M, Schoenmakers R, Christen E H, Fussenegger M, Weber W. Nat. Mater., 2008, 7:800.
[99] Koutsopoulos S, Zhang S. J. Controlled Release, 2012, 160:451.
[100] Wu J, Chen A, Qin M, Huang R, Zhang G, Xue B, Wei J, Li Y, Cao Y, Wang W. Nanoscale, 2015, 7:1655.
[101] Zhang E, Wang T, Hong W, Sun W, Liu X, Tong Z. J. Mater. Chem. A, 2014, 2:15633.
[102] Moon Y E, Jung G, Yun J, Kim H I. Mater. Sci. Eng. B, 2013, 178:1097.