全共轭嵌段共聚物的合成组装与应用

熊丽娜; 张雪勤; 孙莹; 杨洪

doi:10.7536/PC150515

化学进展 ›› 2015, Vol. 27 ›› Issue (12) :1774-1783 DOI: 10.7536/PC150515

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全共轭嵌段共聚物的合成组装与应用

熊丽娜, 张雪勤*, 孙莹, 杨洪

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Synthesis, Self-Assembly and Application of All-Conjugated Block Copolymers

Xiong Lina, Zhang Xueqin*, Sun Ying, Yang Hong

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摘要

全共轭嵌段共聚物体系将共轭聚合物的光电特性和嵌段聚合物的自组装优势相结合,是近几年发展起来的一类新型自组装光电功能材料,对其自组装机理、自组装结构与光电性能之间关系的研究,有利于共轭聚合物微观纳米结构的构筑以及未来光电器件的开发。本文主要介绍全共轭嵌段共聚物包括共轭聚电解质在内的合成发展过程,综述其在溶液中和薄膜状态下独特的自组装行为,介绍共轭聚合物在光电器件中的应用,并对其今后的研究方向做出展望。

Abstract

Combining the optoelectronic characteristics of the conjugated polymers and the self-assembling behavior of the block polymers, all-conjugated block copolymers have been developed as a new class of optoelectronic functional materials with unique self-assembling behavior in recent years. Researching on the relationship among its assembling structure, the mechanism of self-assembly and the photophysical properties has significant impacts on the manipulating nanoscale morphology patterns of conjugated polymers and the development of organic photovoltaic devices. This paper reviews the development of the synthesis process of all-conjugated block copolymers including conjugated polyelectrolytes. Their unique behavior of self-assembly in solution and thin-film state is discussed. Finally, the application of conjugated polymers in optoelectronic devices is introduced, and its future research and development are prospected.

Contents
1 Introduction
2 Synthesis
2.1 Reaction between macromolecular precursors
2.2 Grignard metathesis
2.3 Synthesis of CPEs
3 Self-assembly
3.1 Self-assembly in solution
3.2 Self-assembly in thin film
4 Application
4.1 Application in PSC
4.2 Application in OFET
4.3 Application in PLED
5 Conclusion and outlook

Graphical abstract

关键词

全共轭嵌段共聚物 / 共轭聚电解质 / 自组装 / 光电器件应用

Key words

all-conjugated block copolymers / conjugated polyelectrolytes / self-assembly / application in optoelectronic devices

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熊丽娜, 张雪勤, 孙莹, 杨洪. 全共轭嵌段共聚物的合成组装与应用[J]. 化学进展, 2015, 27(12): 1774-1783 DOI:10.7536/PC150515

Xiong Lina, Zhang Xueqin, Sun Ying, Yang Hong. Synthesis, Self-Assembly and Application of All-Conjugated Block Copolymers[J]. Progress in Chemistry, 2015, 27(12): 1774-1783 DOI:10.7536/PC150515

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