催化甘油脱水氧化连串反应制丙烯酸

花东龙; 庄晓煜; 童东绅; 俞卫华; 周春晖

doi:10.7536/PC150604

化学进展 ›› 2016, Vol. 28 ›› Issue (2/3) :375-390 DOI: 10.7536/PC150604

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催化甘油脱水氧化连串反应制丙烯酸

^1,2*

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Catalytic Oxidehydration of Glycerol to Acrylic Acid

Hua Donglong¹, Zhuang Xiaoyu¹, Tong Dongshen¹, Yu Weihua¹, Zhou Chunhui^1,2*

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摘要

本文综述了近年来单反应器中甘油脱水氧化连串反应制备丙烯酸的研究进展。文中简介了甘油来源及丙烯酸的需求背景;概括了当前对单反应器中的催化体系、反应温度、接触时间、氧气分压及甘油浓度等的研究状况;重点讨论了单、双床层气固相体系中复合氧化物型催化剂和分子筛负载型催化剂的催化性能及其影响因素,涉及的催化剂有V-P、Fe-P、W-V、Mo-V、CsPW-Nb、VMo-SiC等复合氧化物和V₂O₅/BEA、V₂O₅/MFI分子筛负载型催化剂等;总结了当前研究对气固相催化反应机理和可能发生的副反应的认识;评述了催化剂的失活现象与再生问题;此外,还讨论了液固相体系中Cu/SiO₂-MnO₂ 和POM/Al₂O₃催化剂的催化特点及反应机理。最后分析了单反应器中甘油脱水氧化连续反应制丙烯酸反应过程尚存的难题,从反应体系的选取、催化剂性能的改进以及催化剂积炭消除等方面展望了可能的解决途径和方向。

Abstract

This article deals with the recent research and development on catalytic oxidehydration of glycerol into acrylic acid in a single reactor. The biorenewable glycerol as a platform chemical for the production of acrylic acid is introduced. The reaction parameters such as temperature, contact time, partial pressure of oxygen and glycerol concentration in the gas-solid systems and the liquid-solid systems are examined. The catalytic performances of oxide composites and molecular sieve-supported catalysts in a single-bed system and a double-bed gas-solid system are discussed. The catalysts include V-P, Fe-P, W-V, Mo-V, CsPW-Nb, VMo-SiC oxide composites, V₂O₅/BEA and V₂O₅/MFI. The postulated reaction mechanisms and probable side reactions in the gas-solid system are presented, followed by the discussion on the issues of catalyst deactivation and regeneration. Then the catalytic characteristics of Cu/SiO₂-MnO₂ and POM/Al₂O₃ catalysts and the reaction mechanism in the liquid-solid system are remarked. The problems and the prospects in the selection of catalytic system, the improvement of catalysts and the elimination of coking of catalysts are commented.

Contents
1 Introduction
2 Gas-solid catalytic reactions
2.1 Gas-solid catalytic reactions in a single-bed reactor
2.2 Gas-solid catalytic reactions in a double-bed reactor
2.3 Mechanism of gas-solid catalytic reactions
2.4 Deactivation and regeneration of catalysts
3 Liquid-solid catalytic reactions
3.1 Reaction conditions of liquid-solid catalytic reactions
3.2 Catalysts of liquid-solid catalytic reactions
3.3 Mechanism of liquid-solid catalytic reactions
4 Conclusion

Graphical abstract

关键词

甘油 / 催化剂 / 脱水反应 / 氧化反应 / 丙烯酸 / 反应机理

Key words

glycerol / catalysts / dehydration / oxidation / acrylic acid / reaction mechanism

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花东龙, 庄晓煜, 童东绅, 俞卫华, 周春晖. 催化甘油脱水氧化连串反应制丙烯酸[J]. 化学进展, 2016, 28(2/3): 375-390 DOI:10.7536/PC150604

Hua Donglong, Zhuang Xiaoyu, Tong Dongshen, Yu Weihua, Zhou Chunhui. Catalytic Oxidehydration of Glycerol to Acrylic Acid[J]. Progress in Chemistry, 2016, 28(2/3): 375-390 DOI:10.7536/PC150604

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