主链或侧链含二茂铁的聚合物的合成和应用

金亨到; 王立; 俞豪杰; 童荣柏; 周卫东

doi:10.7536/PC150620

化学进展 ›› 2016, Vol. 28 ›› Issue (1) :51-57 DOI: 10.7536/PC150620

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主链或侧链含二茂铁的聚合物的合成和应用

金亨到, 王立*, 俞豪杰, 童荣柏, 周卫东*

作者信息 +

Synthesis and Application of Main-or Side-Chain Ferrocene-Based Polymers

Kim Hyongdo, Wang Li*, Yu Haojie, Tong Rongbai, Zhou Weidong*

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摘要

由于二茂铁基聚合物独特的结构和性能,其在电化学、生物医学及光学等领域具有广阔应用前景。开发新型二茂铁基聚合物并探索其应用已经成为科研工作者的研究热点。本文主要综述主链或侧链含二茂铁的聚合物的合成及应用。其中合成主链含二茂铁的聚合物的方法主要有缩聚法和开环聚合法等。合成侧链含二茂铁的聚合物的方法主要有自由基聚合法、原子转移自由基聚合法和可逆加成断裂链转移聚合法等。最后,对二茂铁基聚合物的应用前景进行了展望。

Abstract

Ferrocene-based polymers have wide application prospect in various fields such as electrochemistry, biomedicine, optics and so on, because of their unique structures and properties. The synthesis and exploration of the application of the ferrocene-based polymers have become a hot topic. In this review, we mainly focus on the synthesis and applications of the main-chain ferrocene-based polymers or side-chain ferrocene-based polymers. For synthesis of main-chain ferrocene-based polymers, polycondensation reaction, ring-opening polymerization and other synthetic methods have been summarized. For synthesis of side-chain ferrocene-based polymers, free radical polymerization, atom transfer radical polymerization (ATRP) method, reversible addition-fragmentation chain transfer (RAFT) polymerization have been applied. Finally, the future applications of ferrocene-based materials are prospected.

Contents
1 Introduction
2 Synthesis of main-chain ferrocene-based polymers
2.1 Polycondensation reaction
2.2 Ring-opening polymerization
3 Synthesis of side-chain ferrocene-based polymers
3.1 Free-radical polymerization
3.2 RAFT polymerization 3.3 ATRP method
3.4 Other synthetic method
4 Application of ferrocene-based polymers
4.1 Application in electrochemistry
4.2 Application in biology and medicine
4.3 Application in liquid crystal
4.4 Other applications
5 Conclusion

关键词

二茂铁基聚合物 / 合成 / 应用 / 功能材料

Key words

ferrocene-based polymer / synthesis / application / functional material

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金亨到, 王立, 俞豪杰, 童荣柏, 周卫东. 主链或侧链含二茂铁的聚合物的合成和应用[J]. 化学进展, 2016, 28(1): 51-57 DOI:10.7536/PC150620

Kim Hyongdo, Wang Li, Yu Haojie, Tong Rongbai, Zhou. Synthesis and Application of Main-or Side-Chain Ferrocene-Based Polymers[J]. Progress in Chemistry, 2016, 28(1): 51-57 DOI:10.7536/PC150620

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Received	Published	Revised
2015-06-01	2016-01-15	2015-09-01
Online Date
2015-12-21

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