单原子催化——概念、方法与应用

靳永勇; 郝盼盼; 任军; 李忠

doi:10.7536/PC150640

化学进展 ›› 2015, Vol. 27 ›› Issue (12) :1689-1704 DOI: 10.7536/PC150640

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单原子催化——概念、方法与应用

靳永勇, 郝盼盼, 任军*, 李忠

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Single Atom Catalysis:Concept, Method and Application

Jin Yongyong, Hao Panpan, Ren Jun*, Li Zhong

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摘要

单原子催化体系的成功构建将催化领域研究深入到更小的尺度范围,不仅可以从原子层次认识复杂的多相催化反应,而且由于其优越的催化性能在工业催化中具有巨大的应用潜能。本文基于近年来国内外研究者在单原子催化领域的研究工作,总结归纳了单原子催化剂的性能特征,介绍了单原子催化剂的制备手段、表征技术、理论研究及其在CO氧化、选择性加氢和光电催化等反应中的应用研究进展,分析了单原子催化剂特殊的电子结构对催化性能和反应机理的影响及其作用机制,指出了单原子催化体系在研究领域取得的突破与不足,对于深刻认识单原子催化的概念与原理、完善实验与理论研究方法、拓展应用范围和尽早实现工业应用提出了建议与展望。

Abstract

With the fabrication of single atom catalysts (SACs) as a new concept, researches on catalysts have deep into smaller scale, which can make it available to dissect complex heterogeneous catalysis on atomic lever, simultaneously provide vast opportunities for applications in industrial catalysis because of their predominant performances. Based on the previous achievements, the main components of this research are as follows: the performance characteristics of SACs are summarized, the preparation, characterizations and theoretical approaches about SACs are introduced, the research developments of applications in CO oxidization, selective hydrogenation and photoelectrocatalysis reaction, etc. are illustrated, the influences of the exceptive electronic structure of SACs on catalytic performance and reaction mechanism are analyzed, the breakthroughs and the shortages of SACs system are pointed out. All these discussions contribute to the profound understanding on principles of SACs, improvement of both theoretical and experimental researches, and furthermore put forward suggestions and prospective for expanding its application range and achieving industrial applications.

Contents
1 Introduction
2 Fabrication and properties of SACs
2.1 Selection of substrates
2.2 Preparation methods
2.3 Catalytic characteristics
3 Structural characterization of SACs
3.1 Characterization methods
3.2 Structual characterization
4 Theoretical methods
4.1 Configuration prediction
4.2 Exploration of reaction mechanism
5 Application of SACs
5.1 Oxidation reaction
5.2 Hydrogenation reaction
5.3 Photoelectrocatalysis reaction
5.4 Other reactions
6 Conclusion

关键词

单原子催化 / 中心原子 / 电子结构 / 不饱和配位 / 强相互作用

Key words

single-atom catalysis / central atoms / electron structure / unsaturated coordination / strong interaction

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靳永勇, 郝盼盼, 任军, 李忠. 单原子催化——概念、方法与应用[J]. 化学进展, 2015, 27(12): 1689-1704 DOI:10.7536/PC150640

Jin Yongyong, Hao Panpan, Ren Jun, Li Zhong. Single Atom Catalysis:Concept, Method and Application[J]. Progress in Chemistry, 2015, 27(12): 1689-1704 DOI:10.7536/PC150640

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Received	Published	Revised
2015-06-01	2015-12-15	2015-08-01
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2015-09-17

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