二氧化钛在钙钛矿太阳电池中的应用

阙亚萍; 翁坚; 胡林华; 戴松元

doi:10.7536/PC150740

化学进展 ›› 2016, Vol. 28 ›› Issue (1) :40-50 DOI: 10.7536/PC150740

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二氧化钛在钙钛矿太阳电池中的应用

^1*

^1,2*

作者信息 +

Applications of Titanium Dioxide in Perovskite Solar Cells

Que Yaping¹, Weng Jian¹, Hu Linhua^1*, Dai Songyuan^1,2*

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摘要

纳米TiO₂由于具有合适的禁带宽度、良好的光电化学稳定性、制作工艺简单等特点,目前广泛应用于染料敏化、量子点和钙钛矿等太阳电池中。作为电池的重要组成部分之一,纳米TiO₂晶体尺寸、颗粒大小和制备方法等明显影响电池的光伏性能,相关研究工作一直是染料敏化、量子点和钙钛矿等太阳电池方面的重点。本文综述了纳米TiO₂作为致密层和骨架层在钙钛矿太阳电池中的应用研究进展,主要讨论了纳米TiO₂的不同形貌、制备方法以及结构等对电池光电性能的影响,并针对纳米TiO₂在后续对电池性能提升方面进行了展望。

Abstract

TiO₂ is widely used in photovoltaic field like dye-sensitized solar cells, quantum dot-sensitized solar cells and so on because of its proper forbidden band width, good optical and chemical stability, nontoxicity, corrosion resistance and simple manufacturing process etc. Recently, inorganic-organic hybrid perovskite solar cell has attracted great attention as a new class of photovoltaic devices and its rapid development has led the power conversion efficiency up to 20%. TiO₂ nanomaterial appears to be a good candidate to be applied in it, which is usually used as compact layer or skeleton layer in perovskite solar cells. As an important part, its crystalline phase, particle size, morphology, preparation methods, film thickness and coverage have great influence on the performance of solar cells. This paper summarizes recent progress of titanium dioxide in the application of perovskite solar cells. We introduce the role TiO₂ play in constructing perovskite solar cells and discuss different preparation methods (high/low temperature) and various optimization methods (modulation of structure, size, shape and interface interaction) of TiO₂. What's more, we analyze the influence of these differences on the performance of perovskite solar cells. In the end, further optimization of TiO₂ materials in the applications of perovskite solar cells is also prospected.

Contents
1 Introduction
2 Recent progress of TiO₂ compact layer
2.1 Preparation methods of TiO₂ compact layer
2.2 Interface optimization of TiO₂ compact layer
2.3 The film thickness of TiO₂ compact layer
3 Recent progress of TiO₂ scaffold layer
3.1 Particle size, pore size and film thickness of TiO₂ scaffold layer
3.2 Crystal phase and morphology of TiO₂
3.3 Surface treatment of TiO₂ scaffold layer
3.4 The influence of TiO₂ on J-V hysteresis
4 Conclusion and prospects

关键词

二氧化钛 / 致密层 / 骨架层 / 钙钛矿太阳电池

Key words

titanium dioxide / compact layer / scaffold layer / perovskite solar cell

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阙亚萍, 翁坚, 胡林华, 戴松元. 二氧化钛在钙钛矿太阳电池中的应用[J]. 化学进展, 2016, 28(1): 40-50 DOI:10.7536/PC150740

Que Yaping, Weng Jian, Hu Linhua, Dai Songyuan. Applications of Titanium Dioxide in Perovskite Solar Cells[J]. Progress in Chemistry, 2016, 28(1): 40-50 DOI:10.7536/PC150740

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Received	Published	Revised
2015-07-01	2016-01-15	2015-09-01
Online Date
2015-12-21

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