水热炭的制备、性质及应用

吴艳姣; 李伟; 吴琼; 刘守新

doi:10.7536/PC150745

化学进展 ›› 2016, Vol. 28 ›› Issue (1) :121-130 DOI: 10.7536/PC150745

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水热炭的制备、性质及应用

吴艳姣, 李伟, 吴琼, 刘守新*

作者信息 +

Preparation, Properties and Applications of Hydrochar

Wu Yanjiao, Li Wei, Wu Qiong, Liu Shouxin*

Author information +

文章历史 +

摘要

水热炭是一种以生物质或其组分为原料,以水为溶剂和反应介质,在150~375 ℃和自生压力下,经水热反应得到的以碳为主体,含氧官能团丰富,热值(HHV)高的黑色固体产物。水热炭的性质主要受原料种类、反应温度和时间的影响。水热炭在吸附、多孔炭制备、催化剂载体和清洁能源等领域展现出了良好的应用前景。本文综述了水热炭的制备、性质和形成机理,并对水热炭的应用进行了总结,对水热炭未来的发展方向进行了展望。

Abstract

Hydrochar is a black carbonaceous solid which is derived from biomass via hydrothermal carbonization condition: using water as solvent and reaction medium, at the temperature of 150~375 ℃ and autogenously pressure. Rich oxygen-containing functional groups, together with high heat value (HHV) are the distinguished properties of hydrochar. Their properties are influenced by raw materials type, hydrothermal carbonization temperature and time. It has revealed a promising perspective in absorbent, preparation of porous carbon, catalyst carrier and clean energy. In this study, the production, properties and formation mechanism of hydrochar are summarized. Meanwhile, the applications of hydrochar are reviewed and the future development is prospected.

Contents
1 Introduction
2 Production of hydrochar
2.1 Influence of feedstock
2.2 Influence of hydrothermal temperature
3 Properties of hydrochar
3.1 Surface chemical properties
3.2 High heat value
3.3 Microcrystalline structure
3.4 Morphological characterization
4 Formation mechanism of hydrochar
5 Applications of hydrochar
5.1 Adsorption of heavy metal ion
5.2 Preparation of porous carbon
5.3 Solid acid catalyst
5.4 Clean energy
6 Conclusion

关键词

水热炭 / 制备 / 表面化学性质 / 机理 / 应用

Key words

hydrochar / preparation / surface chemical properties / mechanism / applications

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吴艳姣, 李伟, 吴琼, 刘守新. 水热炭的制备、性质及应用[J]. 化学进展, 2016, 28(1): 121-130 DOI:10.7536/PC150745

Wu Yanjiao, Li Wei, Wu Qiong, Liu Shouxin. Preparation, Properties and Applications of Hydrochar[J]. Progress in Chemistry, 2016, 28(1): 121-130 DOI:10.7536/PC150745

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原文顺序 | 出版日期 | 本文引用

[1] Mumme J, Eckervogt L, Pielert J, Diakité M, Rupp F, Kern J. Bioresour. Technol., 2011, 102: 9255.
[2] Hoekman S K, Broch A, Robbins C, Zielinska B, Felix L. Biomass Conversion and Biorefinery, 2013, 3: 113.
[3] Wu C H, Chang C Y, Lin J P, Hwang J Y. Fuel, 1997, 76: 1151.
[4] Bini R, Ceppatelli M, Citroni M, Schettino V. Chem. Phys., 2012, 398: 262.
[5] Benavente V, Calabuig E, Fullana A. J. Anal. Appl. Pyrolysis, 2015, 113: 89.
[6] Yan W, Hastings J T, Acharjee T C, Coronella C J, Vásquez V R. Energy Fuels, 2010, 24: 4738.
[7] Kambo H S, Dutta A. Energ. Convers. Manage., 2015, 105: 746.
[8] Pala M, Kantarli I C, Buyukisik H B, Yanik J. Bioresour. Technol., 2014, 161: 255.
[9] Liu Z, Balasubramanian R. Appl.Energ., 2014, 114: 857.
[10] Lynam J G, Coronella C J, Yan W, Reza M T, Vasquez V R. Bioresour. Technol., 2011, 102: 6192.
[11] Lynam J G, Reza M T, Vasquez V R, Coronella C J. Fuel, 2012, 99: 271.
[12] Novianti S, Biddinika M K, Prawisudha P, Yoshikawa K. Procedia Environ. Sci., 2014, 20: 46.
[13] Sevilla M, Fuertes A B. Energ. Environ. Sci., 2011, 4(5): 1765.
[14] Steinbeiss S, Gleixner G, Antonietti M. Soil Biol. Biochem., 2009, 41(6): 1301.
[15] Li Y, Liu X. Mater. Chem. Phys., 2014, 148(1): 380.
[16] Basso D, Weiss-Hortala E, Patuzzi F, Castello D, Baratieri M, Fiori L. Bioresour. Technol., 2015, 182: 217.
[17] Libra J A, Ro K S, Kammann C, Funke A, Berge N D, Neubauer Y. Biofuels, 2011, 2(1): 71.
[18] Kurse A, Dahmen N. J. Supercrit. Fluid., 2015, 96: 36.
[19] Zhang L, Xu C C, Champagne P. Energy Convers. Manage., 2010, 51(5): 969.
[20] He M, Hu Z, Xiao B, Li J, Guo X, Luo S, Yang F, Feng Y, Yang G J, Liu S M. Int. J. Hydrogen Energy, 2009, 34(1): 195.
[21] Buah W K, Cunliffe A M, Williams P T. Process Saf. Environ. Prot., 2007, 85(5): 450.
[22] Ryu C, Sharifi V N, Swithenbank J. Int. J. Energ. Res., 2007, 31(2): 177.
[23] Berge N D, Ro K S, Mao J, Flora J R, Chappell M A, Bae S. Environ. Sci. Technol., 2011, 45(13): 5696.
[24] Phan A N, Ryu C, Sharifi V N, Swithenbank J. J. Anal. Appl. Pyrolysis, 2008, 81(1): 65.
[25] Xiao G, Jin B S, Zhong Z P, Chi Y, Ni M J, Cen K F, Xiao R, Huang Y J, Huang H. J. Environ. Sci., 2007, 19(11): 1398.
[26] Bosmans A, Helsen L. Third International Symposium on Energy from Biomass and Waste. Environmental Sanitary Engineering Centre, Venice, Italy, 2010. 227.
[27] Sevilla M, Maciá-Agulló J A, Fuertes A B. Biomass Bioenergy, 2011, 35(7): 3152.
[28] Bach Q V, Tran K Q, Skreiberg Q, Khalil R A, Phan A N. Fuel, 2014, 137: 375.
[29] Kang W, Li H, Yan Y, Xiao P, Zhu L, Tang K. J. Phys. Chem.C, 2011, 115(14): 6250.
[30] Lu X, Jordan B, Berge N D. Waste Manage., 2012, 32(7): 1353.
[31] Wörmeyer K, Ingram T, Saake B, Brunner G, Smirnova I. Bioresour. Technol., 2011, 102(5): 4157.
[32] Akaln M K, Tekin K, Karagöz S. Bioresour. Technol., 2012, 110: 682.
[33] Jamari S S, Howse J R. Biomass Bioenergy, 2012, 47: 82.
[34] Biller P, Friedman C, Ross A B. Bioresour. Technol., 2013, 136(3):188.
[35] Takata E, Tsutsumi K, Tsutsumi Y, Tabata K. Bioresour. Technol., 2013, 143(6):53.
[36] Tekin K, Karagöz S, Bekta? S. Renew. Sust. Energ. Rev., 2014, 40: 673.
[37] Liu C, Sun R. Cereal Straw As A Resource for Sustainable Biomaterials Biofuels.1st ed. 2010.131.
[38] Hodgson E M, Nowakowski D J, Shield I, Riche A, Bridgwater A V, Clifton-Brown J C. Bioresour. Technol., 2011, 102(3): 3411.
[39] Sevilla M, Gu W, Falco C, Titirici M M, Fuertes A B, Yushin G. J. Power Sources, 2014, 267: 26.
[40] Zhang J, Lin Q, Zhao X. Journal of Integrative Agriculture, 2014, 13(3): 471.
[41] Kang S, Li X, Fan J, Jie C. Bioresour. Technol., 2012, 110: 715.
[42] Poerschmann J, Weiner B, Baskyr I. Chemosphere, 2013, 92(11): 1472.
[43] Hwang I H, Aoyama H, Matsuto T, Nakagishi T, Matsuo T. Waste Manage., 2012, 32(3): 410.
[44] Liu Z, Quek A, Hoekman S K, Balasubramanian R. Fuel, 2013, 103: 943.
[45] Kang S M, Xiang L, Juan F, Jie C. Ind. Eng. Chem. Res., 2012, 51: 9023.
[46] Parshetti G K, Hoekman S K, Balasubramanian R. Bioresour. Technol., 2013, 135: 683.
[47] Reza M T, Borrego A G, Wirth B. Int. J. Coal Geol., 2014, 134: 74.
[48] Gao Y, Wang X, Wang J, Li X, Cheng J, Yang H. Energy, 2013, 58(9): 376.
[49] Reza M T, Rottler E, Herklotz L, Wirth B. Bioresour. Technol., 2015: 336.
[50] Wild T, Bergins C, Strauβ K. Chem. Ing. Tech., 2004, 76:1715.
[51] Funke A, Ziegler F. Biofuels, Bioprod. Bioref., 2010, 4(2): 160.
[52] Khan A A, De Jong W, Jansens P J, Spliethoff H. Fuel Process. Technol., 2009, 90(1): 21.
[53] Álvarez-Murillo A, Román S, Ledesma B, Sabio E. J. Anal. Appl. Pyrol., 2015, 113: 307.
[54] Kambo H S, Dutta A. Appl.Energ., 2014, 135: 182.
[55] Hoekman S K, Broch A, Robbins C. Energy Fuels, 2011, 25(4): 1802.
[56] Sevilla M, Fuertes A B. Carbon, 2009, 47(9): 2281.
[57] Liu Y, Fang Y, Lu X. Chem. Eng. J., 2013, 229:105.
[58] Hu J, Shen D, Wu S, Zhang H, Xiao R. J. Anal. Appl. Pyrolysis, 2014, 106: 118.
[59] Lu L, Kong C, Sahajwalla V, Harris D. Fuel, 2002, 81(9): 1215.
[60] Yin Y, Zhang J, Sheng C, Korean J. Chem. Eng., 2009, 26(3):895.
[61] Maeda R N, Serpa V I, Rocha V A L, Mesquita R A A, Anna L M M S, Castro A M D. Process Biochem., 2011, 46(5): 1196.
[62] Falco C, Marco-Lozar J P, Salinas-Torres D, Morallón E, Cazorla-Amorós D, Titirici M M. Carbon, 2013, 62: 346.
[63] Roman S, Nabais J M V, Ledesma B, González J F, Laginhas C, Titirici M M. Microporous Mesoporous Mat., 2013, 165: 127.
[64] Amonette J E, Joseph S. Biochar Environ. Manage.: Sci. Technol., 2009, 33.
[65] Fuertes A B, Arbestain M C, Sevilla M, Fiol S, Smernik R J, Aitkenhead W P. Soil Res., 2010, 48(7): 618.
[66] van Zandvoort I, Wang Y, Rasrendra C B, Van Eck E R, Bruijnincx P C, Heeres H J. ChemSusChem, 2013, 6(9): 1745.
[67] Baccile N, Laurent G, Babonneau F, Fayon F, Titirici M M, Antonietti M. J. Phys. Chem.C, 2009, 113(22): 9644.
[68] van Putten R J, van der Waal J C, de Jong E, Rasrendra C B, Heeres H J, de Vrise J G. Chem. Rev., 2013, 113(3): 1499.
[69] Lange J P, van der Heide E, van Buijtenen J, Price R. ChemSusChem, 2012, 5(1): 150.
[70] Faravelli T, Frassoldati A, Migliavacca G, Ranzi E. Biomass Bioenergy, 2010, 34(3): 290.
[71] Britt P F, Iii A C, Thomas K B, Lee S K. J. Anal. Appl. Pyrolysis, 1995, 33: 1.
[72] Hu J, Shen D, Xiao R, Wu S, Zhang H. Energy Fuels, 2012, 27(1): 285.
[73] Yong T L K, Matsumura Y. Ind. Eng. Chem. Res., 2013, 52(16): 5626.
[74] Falco C, Baccile N, Titirici M M. Green Chem., 2011, 13(11): 3273.
[75] Sevilla M, Titirici M. Boletín del Grupo Español del Carbón, 2012, 25: 7.
[76] Pyrzyńska K, Bystrzejewski M. Colloids and Surface A:Physicochemical and Engineering Aspects, 2010, 362: 102.
[77] Bhatnagar A, Hogland W, Marques M, Sillanpää M. Chem. Eng. J., 2013, 219: 499.
[78] Wu Q, Li W, Liu S. Mater. Res. Bull., 2014, 60: 516.
[79] Demir-Cakan R, Baccile N, Antonietti M, Titirici M M. Chem. Mater., 2009, 21(3): 484.
[80] Zhang Z, Cao X, Liang P, Liu Y H. J. Radioanal. Nucl. Chem., 2013, 295(2): 1201.
[81] Hao W, Björkman E, Lilliestrle M, Hedin N. Appl.Energ., 2013, 112: 526.
[82] Pari G, Darmawan S, Prihandoko B. Procedia Environ. Sci., 2014, 20: 342.
[83] Jain A, Balasubramanian R, Srinivasan M P. Micropor. Mesopor. Mat., 2015, 203: 178.
[84] Zhu X, Liu Y, Qian F, Chao Z, Zhang S, Chen J. Bioresour. Technol., 2014, 154: 209.
[85] Qi X, Li L, Wang Y, Liu N, Smith R L. Chem. Eng. J., 2014, 256: 407.
[86] Palomar J, Lemus J, Gilarranz M A, Rodriguez J J. Carbon, 2009, 47(7): 1846.
[87] Lemus J, Palomar J, Heras F, Gilarranz M A, Rodriguez J J. Sep. Purif. Methods, 2012, 97: 11.
[88] Martín-Jimeno F J, Suárez-García F, Paredes J I,Martínez-Alonso A, Tascón J. Carbon, 2015, 81: 137.
[89] Zheng M, Zhang H, Xiao Y, Dong H, Liu Y, Xu R. Mater. Lett., 2013, 109: 279.
[90] Wu X, Zhou J, Xing W, Wang G, Cui H, Zhuo S. J. Mater. Chem., 2012, 22(43): 23186.
[91] Li Y, Li X M. RSC Advances, 2013, 3(7): 2398.
[92] Gao F, Shao G, Qu J, Lv S, Li Y, Wu M. Electrochim. Acta, 2015, 155: 201.
[93] Kalpana D, Omkumar K S, Kumar S S, Renganathan N G. Electrochim. Acta, 2006, 52(3): 1309.
[94] Zhang C, Wang H, Liu F, Wang L, He H. Cellulose, 2013, 20(1): 127.
[95] van de Vyver S, Thomas J, Geboers J, Keyzer S, Smet M, Dehaen W. Energ. Environ. Sci., 2011, 4(9): 3601.
[96] Calucci L, Rasse D P, Forte C. Energy Fuels, 2012, 27(1): 303.
[97] Qi X, Lian Y, Yan L, Smith R L. Catal. Commun., 2014, 57: 50.
[98] Shuai L, Pan X. Energ. Environ. Sci., 2012, 5(5): 6889.
[99] Yan L, Liu N, Wang Y, Machida H, Qi X. Bioresour. Technol., 2014, 173: 462.
[100] Reza M T, Uddin M H, Lynam J G, Coronella C J. Biomass Bioenergy, 2014, 63: 229.
[101] Yu G, Yano S, Inoue H, Inoue S, Endo T, Sawayama S. Appl. Biochem. Biotechnol., 2010, 160(2): 539.
[102] Tremel A, Stemann J, Herrmann M, Erlach B, Spliethoff H. Fuel, 2012, 102: 396.
[103] Schimmelpfennig S, Müller C,Grünhage L, Koch C, Kammann C. Agric. Ecosyst. Environ., 2014, 191: 39.
[104] Busch D, Stark A, Kammann C I, Glaser B. Ecotox. Environ. Safe., 2013, 97(5): 59.
[105] Fang J, Gao B, Chen J, Zimmerman A R. Chem. Eng. J.,2015, 267: 253.

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Received	Published	Revised
2015-07-01	2016-01-15	2015-09-01
Online Date
2015-12-21

摘要

Abstract

关键词

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