钛的阳极氧化过程与TiO2纳米管的形成机理

王晶; 范昊雯; 张贺; 陈群; 刘仪; 马卫华

doi:10.7536/PC150813

化学进展 ›› 2016, Vol. 28 ›› Issue (2/3) :284-295 DOI: 10.7536/PC150813

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钛的阳极氧化过程与TiO₂纳米管的形成机理

王晶, 范昊雯, 张贺, 陈群, 刘仪, 马卫华*

作者信息 +

Anodizing Process of Titanium and Formation Mechanism of Anodic TiO₂ Nanotubes

Wang Jing, Fan Haowen, Zhang He, Chen Qun, Liu Yi, Ma Weihua*

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摘要

阳极氧化法制备的TiO₂纳米管因其独特的结构和优异的性能在多个领域获得广泛应用。阳极氧化TiO₂的生长机理也成为本领域的研究热点,最近几年有关生长机理的文章屡见报端。本文从两种阳极氧化钛膜对比的角度,综述了阳极氧化钛纳米管生长机理的最新研究进展和研究意义。首先介绍了Ti的阳极氧化过程,综述了两种阳极氧化钛膜(致密膜和多孔膜)的区别和联系。随后阐述了TiO₂纳米管的形成过程,重点综述了TiO₂纳米管的几种生长机理。分析表明,传统的"场致溶解"理论在解释纳米管结构和形成过程时存在很多局限性,而黏性流动模型和两电流模型相结合能较全面地解释TiO₂纳米管的形成过程,但电子电流的产生机制和纳米孔道中的氧气气泡还有待进一步的实验验证。

Abstract

Anodic TiO₂nanotubes fabricated by anodization have a wide range of applications in a variety of fields because of their unique structure and excellent performance. Also, the formation mechanisms of anodic TiO₂ nanotubes have gradually become a hotspot of research in the field of the porous anodic oxides. A series of papers about formation mechanisms of anodic TiO₂ nanotubes have been published in many famous journals in recent years. The present article has reviewed the latest progress and significance of the research on formation mechanisms of anodic TiO₂ nanotubes in the contrast of two kinds of anodic oxide films. Here, we firstly introduce the anodizing process of Ti, and then analyze the difference and connections of two kinds of anodic oxide films,that are compact anodic oxide film and porous anodic oxide film. Then we introduce the growth process of TiO₂ nanotubes, focusing on different kinds of formation mechanisms of TiO₂ nanotubes. The results show that there are a lot of limitations for the traditional field-assisted dissolution theory in explaining the growth process and the porous structure of TiO₂ nanotubes, but the combination of viscous flow model and growth model of two currents can give a comprehensive explanation to the growth process of TiO₂ nanotubes. However, the validity of oxygen evolution resulting from electronic current has yet to be further investigation.

Contents
1 Introduction
2 Electrochemical anodization of Ti
2.1 Compact anodic titanium oxide films
2.2 Porous anodic titanium oxide films or TiO₂ nanotubes
3 Formation mechanism and growth process of TiO₂ nanotubes
3.1 Field-assisted dissolution theory and growth process of TiO₂ nanotubes
3.2 Viscous flow model
3.3 Growth model of two currents and growth process of TiO₂ nanotubes
4 Conclusion

Graphical abstract

关键词

阳极氧化 / TiO₂纳米管 / 形成机理 / 黏性流动 / 电子电流

Key words

anodization / TiO₂ nanotubes / formation mechanism / viscous flow / electronic current

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王晶, 范昊雯, 张贺, 陈群, 刘仪, 马卫华. 钛的阳极氧化过程与TiO₂纳米管的形成机理[J]. 化学进展, 2016, 28(2/3): 284-295 DOI:10.7536/PC150813

Wang Jing, Fan Haowen, Zhang He, Chen Qun, Liu Yi, Ma Weihua. Anodizing Process of Titanium and Formation Mechanism of Anodic TiO₂ Nanotubes[J]. Progress in Chemistry, 2016, 28(2/3): 284-295 DOI:10.7536/PC150813

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