碳材料修饰铋系光催化剂及其应用

张霞; 樊静

doi:10.7536/PC150940

化学进展 ›› 2016, Vol. 28 ›› Issue (4) :438-449 DOI: 10.7536/PC150940

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碳材料修饰铋系光催化剂及其应用

张霞, 樊静*

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Carbon Materials Modified Bismuth Based Photocatalysts and Their Applications

Zhang Xia, Fan Jing*

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摘要

可见光半导体光催化剂具有高效利用太阳能从而解决能源及环境问题的优势,引起光催化及其他领域人们的关注.铋系光催化剂多属于窄带隙半导体材料,能够吸收太阳光谱中的大量可见光.此外,铋系光催化剂独特的层状晶体结构及较深的价带位置决定了其具有较高的催化活性,成为近年来半导体光催化领域研究的热点.碳基质材料由于具有比表面积大、热和化学稳定性高以及导电能力强等物理化学性质而被人们广泛研究.将碳材料与铋系半导体进行复合,两者之间的协同效应能够增强对反应物的吸附量,拓宽对太阳光的吸收范围,加速电子/空穴对的分离,从而提高催化活性.此外,碳材料修饰的铋光催化剂更易被分离及回收利用,可有效降低应用成本,具有潜在的应用前景.本文对近年来利用碳基质材料修饰铋系光催化剂的类型、制备方法、结构与性能、作用机理及其应用研究进行了综述,提出了目前利用碳材料修饰铋系光催化剂在材料设计、机理研究及应用等方面存在的主要问题,并对其未来发展方向进行了展望.

Abstract

Visible light responsive semiconductor photocatalysts have attracted considerable attention due to their capacity of efficient use of sunlight to solve energy and environmental problems. Most of bismuth based photocatalysts have narrow bandgap and can absorb abundant visible light in natural solar spectrum. Moreover,the unique layered structure and deeper valance band of the bismuth based photocatalysts make them to have excellent photocatalytic activity and become the focus of research in photocatalysis field. Carbonaceous materials have been widely studied because of their unique physicochemical properties such as large surface area, high thermal and chemical stability and outstanding electron conductivity. Combining bismuth-based photocatalysts with carbonaceous materials, the synergistic effects between them endow the composites with increased surface adsorption capacity, extended light absorption thresholds, and enhanced separation of photogenerated electron/hole pairs. All of these are beneficial to the improvement of photocatalytic activities. In addition, it is easier to separate and recover the composite photocatalysts for recycling utilization, thereby reducing the cost in practical application. Therefore, bismuth based photocatalysts modified with diverse carbonaceous materials are expected to have promising application in future. In this article, the researches on the type, preparation methods, structure, performance, mechanism of action, and application of these carbonaceous materials modified bismuth photocatalysts have been reviewed in detail. The main problems in design, mechanism research and application are presented, and the future development directions have been suggested.

Contents
1 Introduction
1.1 Bismuth based photocatalysts
1.2 Construction of bismuth based composite photocatalysts
2 Carbon loading bismuth based photocatalysts
2.1 Activated carbon supporter
2.2 Graphene supporter
2.3 Carbon nanotubes supporter
2.4 Fullerence and other nanocarbon supporter
3 Carbon coating bismuth-based photocatalysts
4 Carbon doping bismuth-based photocatalysts
5 Conclusion and outlook

Graphical abstract

关键词

铋系光催化剂 / 碳修饰 / 复合材料 / 污染物 / 降解

Key words

bismuthbased photocatalysts / carbon modification / composite materials / pollutants / degradation

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张霞, 樊静. 碳材料修饰铋系光催化剂及其应用[J]. 化学进展, 2016, 28(4): 438-449 DOI:10.7536/PC150940

Zhang Xia, Fan Jing. Carbon Materials Modified Bismuth Based Photocatalysts and Their Applications[J]. Progress in Chemistry, 2016, 28(4): 438-449 DOI:10.7536/PC150940

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