端羟基聚丁二烯液体橡胶的合成、化学改性及应用

郑娜; 介素云; 李伯耿

doi:10.7536/PC151023

化学进展 ›› 2016, Vol. 28 ›› Issue (5) :665-672 DOI: 10.7536/PC151023

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端羟基聚丁二烯液体橡胶的合成、化学改性及应用

郑娜, 介素云*, 李伯耿

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Synthesis, Chemical Modifications and Applications of Hydroxyl-Terminated Polybutadiene

Zheng Na, Jie Suyun*, Li Bogeng

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摘要

端羟基聚丁二烯(HTPB)是一种低分子量的遥爪液体橡胶,因具有玻璃化温度低、透明度好、黏度低、不易挥发、耐油耐老化、低温和加工性能好等优点,在军事和民用领域均具有广泛的应用。HTPB的性能主要受其主链微观结构的影响,不同的制备方法得到不同链结构的HTPB,其性能也有较大的差别。另外,通过对HTPB主链中的双键或末端羟基进行化学修饰可将其转变为不同分子结构或不同官能团的遥爪聚合物,赋予改性后的HTPB不同性能,并拓宽其应用领域。本文主要概述端羟基聚丁二烯的合成方法、化学改性和应用。

Abstract

Hydroxyl-terminated polybutadiene (HTPB) is a low molecular-weight telechelic liquid rubber. Because of its various advantages, such as low glass transition temperature, good transparency, low viscosity, hard volatilization, oil resistance, good processability, HTPB has a wide range of applications in military and civilian fields. The properties of HTPB are mainly influenced by its chain microstructure. The different synthetic methods produce HTPB with different microstructure, which will result in the large difference in the properties. In addition, the chemical modifications of C＝C double bonds in the main chain and hydroxyl groups in the chain ends lead to the formation of telechelic polymers with different molecular structure and various functional groups. After modifications, the different properties are endowed to HTPB and the application fields are also expanded. In this review, the research progress about the synthesis, chemical modifications and applications of HTPB is discussed in detail.

Contents
1 Introduction
2 Synthesis of HTPB
2.1 Free radical polymerization
2.2 Anionic polymerization
2.3 Ring-opening metathesis polymerization
2.4 Oxidolysis of polybutadiene
3 Chemical modifications of HTPB
3.1 Reactions with double bonds in the main chain
3.2 Reactions with hydroxyl groups in the chain ends
3.3 Reactions with carbon atoms at the terminal
4 Applications
4.1 Solid propellants
4.2 HTPB-based polyurethane
4.3 Block copolymers
5 Conclusion

Graphical abstract

关键词

端羟基聚丁二烯 / 液体橡胶 / 化学改性 / 应用

Key words

hydroxyl-terminated polybutadiene(HTPB) / liquid rubber / chemical modifications / applications

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郑娜, 介素云, 李伯耿. 端羟基聚丁二烯液体橡胶的合成、化学改性及应用[J]. 化学进展, 2016, 28(5): 665-672 DOI:10.7536/PC151023

Zheng Na, Jie Suyun, Li Bogeng. Synthesis, Chemical Modifications and Applications of Hydroxyl-Terminated Polybutadiene[J]. Progress in Chemistry, 2016, 28(5): 665-672 DOI:10.7536/PC151023

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