催化剂的孔道限域效应

薛丽君; 张迪; 魏杰; 刘欣梅

doi:10.7536/PC151026

化学进展 ›› 2016, Vol. 28 ›› Issue (4) :450-458 DOI: 10.7536/PC151026

综述与评论

扫码查看或转发全文

催化剂的孔道限域效应

薛丽君, 张迪, 魏杰, 刘欣梅*

作者信息 +

Pore Confinement Effects of Catalysts

Xue Lijun, Zhang Di, Wei Jie, Liu Xinmei*

Author information +

文章历史 +

摘要

限域孔道可以调控催化剂的表面电子分布和几何结构,进而影响催化剂的活性、选择性和稳定性.本文结合理论计算和实验方法,从热力学、动力学、几何效应以及电子转移等角度出发,阐明了不同限域体系中催化剂活性组分和反应分子特性的差异,揭示了限域孔道对反应物种扩散、吸附和反应等过程的影响规律,以期为催化剂的微观结构设计和反应性能调控提供借鉴.

Abstract

The surface electronic distribution and geometric construction of catalysts can be regulated by confined pore canals, which will affect the activity, selectivity and stability of catalysts. Combined with theoretical calculations and experimental methods, from the perspectives of thermodynamics, kinetics, geometric effect and electron transfer, this review illustrates the differences of the active components of catalysts and the characteristics of reaction molecules in different confined systems, and reveals the influence of confined pore canals on the diffusion, adsorption and reaction of reaction species. It aims to provide a reference for the microstructure design and performance control of catalysts.

Contents
1 Introduction
2 Pore confinement effects on diffusion
3 Pore confinement effects on adsorption
4 Pore confinement effects on catalytic reaction
5 Conclusion

Graphical abstract

关键词

催化剂 / 孔道限域效应 / 扩散 / 吸附 / 催化反应

Key words

catalysts / pore confinement effects / diffusion / adsorption / catalytic reaction

引用本文

引用格式 ▾

薛丽君, 张迪, 魏杰, 刘欣梅. 催化剂的孔道限域效应[J]. 化学进展, 2016, 28(4): 450-458 DOI:10.7536/PC151026

Xue Lijun, Zhang Di, Wei Jie, Liu Xinmei. Pore Confinement Effects of Catalysts[J]. Progress in Chemistry, 2016, 28(4): 450-458 DOI:10.7536/PC151026

登录浏览全文

4963

注册一个新账户忘记密码

参考文献

原文顺序 | 出版日期 | 本文引用

[1] Derouane E G, André J M, Lucas A A. Chem. Phys. Lett., 1987, 137 (4): 336.
[2] Derouane E G, Andre J M, Lucas A A. J. Catal., 1988, 110 (1): 58.
[3] Abouelnasr M K, Smit B. Phys. Chem. Chem. Phys., 2012, 14 (33): 11600.
[4] Boekfa B, Pantu P, Probst M, Limtrakul J. J. Phys. Chem. C, 2010, 114 (35): 15061.
[5] Hua B Y, Wang J, Wang K, Li X, Zhu X J, Xia X H. Chem. Commun., 2012, 48 (17): 2316.
[6] Liu X, Wang A, Wang X, Mou C Y, Zhang T. Chem. Commun., 2008, 27: 3187.
[7] Bhide S Y, Ghosh D, Yashonath S, Ananthakrishna G. Curr. Sci. India, 2004, 87 (7): 971.
[8] Yashonath S, Ghorai P K. J. Phys. Chem. B, 2008, 112 (3): 665.
[9] June R L, Bell A T, Theodorou D N. J. Phys. Chem., 1992, 96 (3): 1051.
[10] Barrer R M. Chem-Ing-Tech, 1980, 52 (4): 366.
[11] Yashonath S, Santikary P. J. Phys. Chem., 1994, 98 (25): 6368.
[12] Yashonath S. Faraday Discuss., 1997, 106: 105.
[13] Rajappa C, Yashonath S. J. Phys. Chem. B, 1997, 101 (40): 8035.
[14] Rajappa C, Yashonath S. J. Chem. Phys., 1999, 110 (12): 5960.
[15] 陈爱城 (Chen A C), 陈胜利 (Chen S L), 娄亚峰 (Lou Y F), 陈静 (Chen J). 石油学报 (石油加工)(Acta Petrolei Sinica (Petroleum Processing Section)), 2014, 2: 266.
[16] Montanari T, Finocchio E, Busca G. J. Phys. Chem. C, 2010, 115 (4): 937.
[17] Chiang H, Bhan A. J. Catal., 2010, 271 (2): 251.
[18] Bevilacqua M, Alejandre A G, Resini C, Casagrande M, Ramirez J. Phys. Chem. Chem. Phys., 2002, 4 (18): 4575.
[19] Trombetta M, Busca G. J. Catal., 1999, 187 (2): 521.
[20] Montanari T, Bevilacqua M, Busca G. Appl. Catal. A, 2006, 307 (1): 21.
[21] Radovic L R, Rodriguez-Reinoso F. Chem. Phys. Carbon, 1997, 243.
[22] Liang C, Li Z, Dai S. Angew. Chem. Int. Ed., 2008, 47 (20): 3696.
[23] Pan X, Bao X. Acc. Chem. Res., 2011, 44 (8): 553.
[24] Chen H, Sholl D S. J. Am. Chem. Soc., 2004, 126 (25): 7778.
[25] Peer M, Qajar A, Rajagopalan R, Foley H C. Carbon, 2014, 66: 459.
[26] Santiso E E, Kostov M K, George A M, Nardelli M B, Gubbins K E. Appl. Surf. Sci., 2007, 253 (13): 5570.
[27] Holbrook B P M, Rajagopalan R, Dronvajjala K, Choudhary YK, Foley H C. J. Mol. Catal. A: Chem., 2013, 367: 61.
[28] Guil J M, Guil-López R, Perdigón-Melón J A, Corma A. Micropor. Mesopor. Mater., 1998, 22 (1): 269.
[29] Zheng A, Zhang H, Lu X, Liu S B, Deng F. J. Phys. Chem. B, 2008, 112 (15): 4496.
[30] Huang S J, Zhao Q, Chen W H, Han X, Bao X, Lo P S, Lee H K, Liu S B. Catal. Today, 2004, 97 (1): 25.
[31] Zhao Q, Chen W H, Huang S J, Liu S B. Stud. Surf. Sci. Catal., 2003, 145: 205.
[32] Zheng A, Han B, Li B, Liu S B, Deng F. Chem. Commun., 2012, 48 (55): 6936.
[33] Kondratyuk P, Yates J T. Acc. Chem. Res., 2007, 40 (10): 995.
[34] Guan J, Pan X, Liu X, Bao X. J. Phys. Chem. C, 2009, 113 (52): 21687.
[35] Zhu Y, Li L, Zhang C, Casillas G, Sun Z, Yan Z, Ruan G, Peng Z, Raji A R O, Kittrell C, Hauge R H, Tour J M. Nat. Commun., 2012, 3: 1225.
[36] Dimitrakakis G K, Tylianakis E, Froudakis G E. Nano Lett., 2008, 8 (10): 3166.
[37] Martinez De La Hoz J M, Balbuena P B. ACS Catal., 2015, 5 (1): 215.
[38] Gomez D A, Combariza A F, Sastre G. Phys. Chem. Chem. Phys., 2012, 14 (7): 2508.
[39] Bae Y S, Hauser B G, Colón Y J, Hupp J T, Farha O K, Snurr R Q. Micropor. Mesopor. Mater., 2013, 169: 176.
[40] Jen H W. Catal. Today, 1998, 42 (1): 37.
[41] Shimura K, Miyazawa T, Hanaoka T, Hirata S. J. Mol. Catal. A: Chem., 2014, 394: 22.
[42] Xiong H, Zhang Y, Wang S, Li J. Catal. Commun., 2005, 6 (8): 512.
[43] Borg Ø, Eri S, Blekkan E A, Storsæter S, Wigum H, Rytter E, Holmen A. J. Catal., 2007, 248 (1): 89.
[44] Khodakov A Y, Bechara R, Griboval-Constant A. Appl. Catal. A, 2003, 254 (2): 273.
[45] Song D, Li J. J. Mol. Catal. A: Chem., 2006, 247 (1): 206.
[46] Santiso E E, George A M, Turner C H, Kostov M K, Gubbins K E, Buongiorno-Nardelli M, Sliwinska-Bartkowiak M. Appl. Surf. Sci., 2005, 252 (3): 766.
[47] Toulhoat H, Lontsi Fomena M, de Bruin T. J. Am. Chem. Soc., 2011, 133 (8): 2481.
[48] Gounder R, Iglesia E. Acc. Chem. Res., 2011, 45 (2): 229.
[49] Gounder R, Iglesia E. J. Am. Chem. Soc., 2009, 131 (5): 1958.
[50] Gounder R, Iglesia E. Angew. Chem. Int. Ed., 2010, 49 (4): 808.
[51] Turner C H, Johnson J K, Gubbins K E. J. Chem. Phys., 2001, 114 (4): 1851.
[52] Byl O, Kondratyuk P, Yates J. J. Phys. Chem. B, 2003, 107 (18): 4277.
[53] Johnson J K, Panagiotopoulos A Z, Gubbins K E. Mol. Phys., 1994, 81 (3): 717.
[54] Turner C H, Brennan J K, Pikunic J, Gubbins K E. Appl. Surf. Sci., 2002, 196 (1): 366.
[55] Turner C H, Brennan J K, Johnson J K, Gubbins K E. J. Chem. Phys., 2002, 116 (5): 2138.
[56] Sokolov S, Kondratenko E V, Pohl M M, Barkschat A, Rodemerck U. Appl. Catal. B, 2012, 113: 19.
[57] Xu L, Song H, Chou L. Appl. Catal. B, 2011, 108: 177.
[58] Chen Z, Guan Z, Li M, Yang Q, Li C. Angew. Chem. Int. Ed., 2011, 50 (21): 4913.
[59] Yang H, Zhang L, Zhong L, Yang Q, Li C. Angew. Chem. Int. Ed., 2007, 46 (36): 6861.
[60] Yang H, Li J, Yang J, Liu Z, Yang Q, Li C. Chem. Commun., 2007, 10: 1086.
[61] Yang H, Zhang L, Su W, Yang Q, Li C. J. Catal., 2007, 248 (2): 204.
[62] Bai S, Li B, Peng J, Zhang X, Yang Q, Li C. Chem. Sci., 2012, 3 (9): 2864.
[63] Liu X, Wang P, Zhang L, Yang J, Li C, Yang Q. Chem. Eur. J., 2010, 16 (42): 12727.
[64] Liu X, Li X, Yan Z. Appl. Catal. B: Environ., 2012, 121: 50.
[65] Weingarten R, Tompsett G A, Conner W C, Huber G W. J. Catal., 2011, 279 (1): 174.
[66] Trens P, Tanchoux N, Papineschi P M, Maldonado D, di Renzo F, Fajula F. Micropor. Mesopor. Mater., 2005, 86 (1): 354.
[67] Kresge C, Leonowicz M, Roth W, Vartuli J, Beck J. Nature, 1992, 359 (6397): 710.
[68] Tanchoux N, Pariente S, Trens P, Fajula F. J. Mol. Catal. A: Chem., 2009, 305 (1): 8.
[69] Rao Y, Kang J, Antonelli D. J. Am. Chem. Soc., 2008, 130 (2): 394.
[70] Phung T K, Hernández L P, Lagazzo A, Busca G. Appl. Catal. A: Gen., 2015, 493: 77.
[71] Botas J, Serrano D, García A, de Vicente J, Ramos R. Catal. Today, 2012, 195 (1): 59.
[72] Botas J, Serrano D, García A, Ramos R. Appl. Catal. B: Environ., 2014, 145: 205.
[73] Makarfi Y I, Yakimova M S, Lermontov A S, Erofeev V I, Koval L M, Tretiyakov V F. Chem. Eng. J., 2009, 154 (1): 396.
[74] Li J, Wei Y, Chen J, Xu S, Tian P, Yang X, Li B, Wang J, Liu Z M. ACS Catal., 2014, 5 (2): 661.
[75] Sassi A, Wildman M A, Ahn H J, Prasad P, Nicholas J B, Haw J F. J. Phys. Chem. B, 2002, 106 (9): 2294.
[76] Chu Y, Ji P, Yi X, Li S, Wu P, Zheng A, Deng F. Catal. Sci. Technol., 2015, 5: 3675.
[77] Fernández A, Lezcano-Gonzalez I, Boronat M, Blasco T, Corma A. J. Catal., 2007, 249 (1): 116.
[78] Chu Y, Sun X, Yi X, Ding L, Zheng A, Deng F. Catal. Sci. Technol., 2015, 5: 3507.
[79] Teketel S, Svelle S, Lillerud K P, Olsbye U. ChemCatChem, 2009, 1 (1): 78.
[80] Teketel S, Skistad W, Benard S, Olsbye U, Lillerud K P, Beato P, Svelle S. ACS Catal., 2011, 2 (1): 26.
[81] Lu T, Goldfield E M, Gray S K. J. Phys. Chem. C, 2008, 112 (7): 2654.
[82] Halls M D, Schlegel H B. J. Phys. Chem. B, 2002, 106 (8): 1921.
[83] Santiso E E, Nardelli M B, Gubbins K E. J. Chem. Phys., 2008, 128 (3): 034704.
[84] Chen W, Fan Z, Pan X, Bao X. J. Am. Chem. Soc., 2008, 130 (29): 9414.
[85] Chen W, Pan X, Bao X. J. Am. Chem. Soc., 2007, 129 (23): 7421.
[86] Chen W, Pan X, Willinger M G, Su D S, Bao X. J. Am. Chem. Soc., 2006, 128 (10): 3136.
[87] Pan X, Fan Z, Chen W, Ding Y, Luo H, Bao X. Nat. Mater., 2007, 6 (7): 507.
[88] Yang H, Song S, Rao R, Wang X, Yu Q, Zhang A. J. Mol. Catal. A: Chem., 2010, 323 (1): 33.
[89] Kondratyuk P, Wang Y, Liu J, Johnson J K, Yates J T. J. Phys. Chem. C, 2007, 111 (12): 4578.
[90] Castillejos E, Debouttière P J, Roiban L, Solhy A, Martinez V, Kihn Y, Ersen O, Philippot K, Chaudret B, Serp P. Angew. Chem. Int. Ed., 2009, 48 (14): 2529.
[91] 包信和 (Bao X H). 中国科学:化学 (Science China Chemistry), 2012, 42 (4): 355.
[92] GråNä S E, Andersen M, Arman M A, Gerber T, Hammer B, Schnadt J, Andersen J N, Michely T, Knudsen J. J. Phys. Chem. C, 2013, 117 (32): 16438.
[93] Jin L, Fu Q, Dong A, Ning Y, Wang Z, Bluhm H, Bao X. J. Phys. Chem. C, 2014, 118 (23): 12391.
[94] Feng X, Maier S, Salmeron M. J. Am. Chem. Soc., 2012, 134 (12): 5662.
[95] Jin L, Fu Q, Yang Y, Bao X. Surf. Sci., 2013, 617: 81.
[96] Zhang X, Wang L, Xin J, Yakobson B I, Ding F. J. Am. Chem. Soc., 2014, 136 (8): 3040.
[97] Hsieh Y P, Hofmann M, Chang K W, Jhu J G, Li Y Y, Chen K Y, Yang C C, Chang W S, Chen L C. ACS Nano, 2013, 8 (1): 443.
[98] Zhang Y, Fu Q, Cui Y, Mu R, Jin L, Bao X. Phys. Chem. Chem. Phys., 2013, 15 (43): 19042.
[99] Batzill M. Surf. Sci. Rep., 2012, 67 (3): 83.
[100] Wintterlin J, Bocquet M L. Surf. Sci., 2009, 603 (10): 1841.
[101] Yao Y, Fu Q, Zhang Y, Weng X, Li H, Chen M, Jin L, Dong A, Mu R, Jiang P. Proc. Natl. Acad. Sci., 2014, 111 (48): 17023.