石墨烯/纤维素复合材料的制备及应用

高玉荣; 黄培; 孙佩佩; 吴敏; 黄勇

doi:10.7536/PC151110

化学进展 ›› 2016, Vol. 28 ›› Issue (5) :647-656 DOI: 10.7536/PC151110

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石墨烯/纤维素复合材料的制备及应用

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作者信息 +

Preparation and Application of Graphene/Cellulose Composites

Gao Yurong^1,2, Huang Pei¹, Sun Peipei¹, Wu Min^1*, Huang Yong¹

Author information +

文章历史 +

摘要

近年来,石墨烯/纤维素复合材料引起了研究者的广泛关注。该材料在透明导电柔性薄膜、电容器、载药、紫外线防护、传感器、吸附等领域有重要的应用价值。本文在收集、归类研究国内外研究者在石墨烯/纤维素复合材料制备方法、性能以及应用工作的基础上,对石墨烯和纤维素复合材料的混合技术、制备方法及应用进行了综述。

Abstract

Graphene is a one-atom-thick planar sheet of sp²-bonded carbon atoms densely packed together in a honeycomb hexagonal lattice. The exceptional structure endows graphene with excellent electrical, mechanical, thermal, and optical properties. Up to now, considerable efforts have been made to explore its application in varied areas, such as catalyst, battery, sensor and etc. Cellulose, one of the most abundant natural polymer on earth, is featured by non-toxicity, renewability, biodegradability and biocompatibility. The hydrophilicity and hydrophobicity, originated from the enriched O-H and C-H, respectively, have made cellulose an ideal candidate for the fabrication of graphene-based materials. So far, graphene/cellulose composites have shown great potential in the applications of transparent conductive flexible films, supercapacitors, drug delivery, UV-protection, sensors, absorbents and so on. In this review, we study the interaction between cellulose materials and graphene materials. Subsequently, the mixing technics, fabrication methods, and application of the graphene/cellulose composites are summarized. Finally, problems, such as dispersion of graphene in cellulose and production efficiency, hampering its up-scale application, have been pointed out.

Contents
1 Introduction
2 Interactions between graphene and cellulose
3 Mixing methods of graphene/cellulose composite
3.1 Solution mixing
3.2 Melting mixing
3.3 Others
4 Processing of graphene/cellulose composite
4.1 Regeneration of cellulose gel
4.2 Vacuum filtration
4.3 Solution coating
4.4 Dip and dry
4.5 Film transfer
4.6 Aerogel through freeze drying
5 Applications of graphene/cellulose composite
5.1 Thin film materials
5.2 Supercapacitors
5.3 Drug delivery
5.4 UV-protection
5.5 Sensors
5.6 Absorbents
5.7 Others
6 Conclusion

Graphical abstract

关键词

纤维素 / 石墨烯 / 氧化石墨烯 / 复合材料

Key words

cellulose / graphene / graphene oxide / composite

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高玉荣, 黄培, 孙佩佩, 吴敏, 黄勇. 石墨烯/纤维素复合材料的制备及应用[J]. 化学进展, 2016, 28(5): 647-656 DOI:10.7536/PC151110

Gao Yurong, Huang Pei, Sun Peipei, Wu Min, Huang Yong. Preparation and Application of Graphene/Cellulose Composites[J]. Progress in Chemistry, 2016, 28(5): 647-656 DOI:10.7536/PC151110

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