基于主-客体作用的超分子聚合物的构筑和调控进展

黄文忠; 占田广; 林沨; 赵新

doi:10.7536/PC151125

化学进展 ›› 2016, Vol. 28 ›› Issue (2/3) :165-183 DOI: 10.7536/PC151125

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基于主-客体作用的超分子聚合物的构筑和调控进展

^1*

^2*

作者信息 +

Recent Progress in the Construction and Regulation of Supramolecular Polymers Based on Host-Guest Interactions

Huang Wenzhong^1*, Zhan Tianguang², Lin Feng², Zhao Xin^2*

Author information +

文章历史 +

摘要

超分子聚合物是超分子化学与高分子科学交叉而产生的一个新的研究领域。在超分子聚合物中单体之间主要依靠非共价作用如氢键、金属配位、主-客体作用等来连接。这其中,利用主-客体作用驱动组装的超分子聚合物是这一领域的重要代表。本文在简要介绍超分子聚合物的概念和历史的基础上,着重总结了近几年来基于主-客体化学构筑超分子聚合物的一些代表性进展,根据主体分子结构的不同分为基于冠醚/穴醚、环糊精、杯芳烃、葫芦脲和柱芳烃的超分子聚合物五个部分,最后对该领域目前的研究现状以及今后的主要发展方向进行了总结和展望。

Abstract

Supramolecular polymer is a new interdiscipline of supramolecular chemistry and polymer science. In supramolecularly polymeric structures the monomers are connected by noncovalent bonds such as hydrogen bonds, metal-organic coordinations, and host-guest interactions and so on. Supramolecular polymers constructed on the basis of host-guest interactions constitute of a main branch of the whole family of supramolecular polymers. In this review, some representative progress on the construction of supramolecular polymers based on host-guest interactions has been summarized, after a brief introduction of the concept and history of supramolecular polymer. It has been divided into five parts according to the different structures of the host molecules. In the last part, the challenges and prospective tendency of this subject have also been discussed.

Contents
1 Introduction
2 Crown ether and cryptand based supramolecular polymers
3 Cyclodextrin based supramolecular polymers
4 Calixarenes based supramolecular polymers
5 Cucurbiturils based supramolecular polymers
6 Pillararene based supramolecular polymers
7 Conclusion and outlook

Graphical abstract

关键词

主-客体作用 / 超分子聚合物 / 大环 / 自组装

Key words

host-guest interactions / supramolecular polymers / macrocycles / self-assembly

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黄文忠, 占田广, 林沨, 赵新. 基于主-客体作用的超分子聚合物的构筑和调控进展[J]. 化学进展, 2016, 28(2/3): 165-183 DOI:10.7536/PC151125

Huang Wenzhong, Zhan Tianguang, Lin Feng, Zhao Xin. Recent Progress in the Construction and Regulation of Supramolecular Polymers Based on Host-Guest Interactions[J]. Progress in Chemistry, 2016, 28(2/3): 165-183 DOI:10.7536/PC151125

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