上/下转换材料在染料敏化太阳电池中的应用进展

姜玲; 阙亚萍; 丁勇; 胡林华; 张昌能; 戴松元

doi:10.7536/PC151136

化学进展 ›› 2016, Vol. 28 ›› Issue (5) :637-646 DOI: 10.7536/PC151136

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上/下转换材料在染料敏化太阳电池中的应用进展

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Applications of the Up and Down Conversion in Dye Sensitized Solar Cells

Jiang Ling^1,2, Que Yaping¹, Ding Yong¹, Hu Linhua¹, Zhang Changneng^1*, Dai Songyuan^1,3*

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摘要

上/下转换技术能将红外光和紫外光能量转换成与工作电池匹配的光谱范围内能量,解决了由于光谱不匹配造成的能量损失,实现拓宽电池的吸收光谱,提高电池的光利用率和转换效率,降低紫外光对电池稳定性的影响。稀土离子由于特殊的能级结构且发光效率高,常作为上/下转换发光材料的中心离子。近年来上转换发光中心主要集中在Er³⁺,Tm³⁺等三价离子,敏化中心则为具有特殊能级结构和较长激发态寿命的Yb³⁺离子。Tb³⁺,Eu³⁺,Sm³⁺等离子由于在紫外光区具有电荷迁移吸收带,易被高能紫外光子激发,量子效率接近100%且发射谱线主要位于可见光区,常被用作下转换发光中心。发光基质多选择声子能量低、透光范围广、易于掺杂的氟化物,并通过水热法制备出结晶度高、粒径小且分布均匀的粉体材料。目前,上/下转换技术应用于DSC的研究越来越受到人们的重视,本文将对上转换和下转换技术在DSC中的应用进行详细阐述,主要介绍上/下转换技术的发展背景,在太阳电池中的应用和方法,详细综述近几年来各类上转换和下转换材料在太阳电池中应用的研究进展,最后对其未来的发展方向进行了展望。

Abstract

The up and down conversion technology can convert the infrared and ultraviolet light into the visible light in the range of 300~800 nm, which can solve the energy loss caused by spectral mismatch, and the absorption spectrum of the cell can be expanded to improve the light utilization and conversion efficiency. The rare earth ion is often used as the center ion of the up and down conversion materials because of the special structure of the energy level and the high luminous efficiency. In recent years, the center ion of up conversion is mainly Er³⁺, Tm³⁺and the sensitization center is Yb³⁺ with longer excited state lifetime. Tb³⁺, Eu³⁺ and Sm³⁺ have charge transfer absorption band in the ultraviolet region, which can be easily excited by ultraviolet light and the emission spectrum mainly located in the visible region, so they are often used as the center ion of down conversion.The host is usually fluoride and the materials with high crystallinity, small particle size and uniform distribution were prepared by hydrothermal method. At present, the research on up and down conversion applied to DSC is getting more and more important. In this paper, we mainly discuss the application of up and down conversion in DSC, and prospect the future development direction.

Contents
1 Introduction
2 Up and down conversion technology
2.1 Luminescence mechanism of up and down conversion
2.2 Host of up and down conversion luminescent materials
2.3 Preparation method of luminescent materials
3 Application of up and down conversion in dye sensitized solar cells
3.1 Energy loss in solar cells
3.2 Application modeling of up and down conversion in solar cell
3.3 Application of up and down conversion luminescent materials in DSC
4 Conclusion and outlook

关键词

发光材料 / 上转换 / 下转换 / 稀土 / 太阳电池

Key words

luminescence materials / up-conversion / down-conversion / rare earth / solar cell

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姜玲, 阙亚萍, 丁勇, 胡林华, 张昌能, 戴松元. 上/下转换材料在染料敏化太阳电池中的应用进展[J]. 化学进展, 2016, 28(5): 637-646 DOI:10.7536/PC151136

Jiang Ling, Que Yaping, Ding Yong, Hu Linhua, Zhang Changneng, Dai Songyuan. Applications of the Up and Down Conversion in Dye Sensitized Solar Cells[J]. Progress in Chemistry, 2016, 28(5): 637-646 DOI:10.7536/PC151136

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Received	Published	Revised
2015-11-01	2016-05-15	2016-01-01
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2016-03-25

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