改性聚苯胺及其衍生物涂层的防腐性能

胡传波, 厉英, 孔亚州, 丁玉石

doi:10.7536/PC160105

化学进展 ›› 2016, Vol. 28 ›› Issue (8) :1238-1250 DOI: 10.7536/PC160105

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改性聚苯胺及其衍生物涂层的防腐性能

胡传波, 厉英, 孔亚州, 丁玉石

作者信息 +

Anticorrosion Properties of Modified Polyanilines and Its Derivatives Coatings

Hu Chuanbo, Li Ying, Kong Yazhou, Ding Yushi

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摘要

导电聚合物作为一种新型高分子材料，由于具有可逆的氧化还原特性，在金属腐蚀防护领域具有潜在的应用前景。在众多的导电聚合物中，聚苯胺因其具有独特的抗点蚀、抗划伤和防止海洋生物附着等特殊性能，被广泛应用于金属材料、化学工业和航海航天等领域，逐渐成为防腐涂料领域的研究热点。本文通过对单一聚苯胺涂层防腐性能不足的分析，系统总结了近年来改性聚苯胺涂层在金属腐蚀防护领域的研究进展，包括单一环取代聚苯胺涂层和N取代聚苯胺涂层、改性聚苯胺复合涂层和改性聚苯胺复合材料/树脂共混复合涂层；通过各种腐蚀测试手段比较了改性聚苯胺涂层与未改性聚苯胺涂层之间防腐性能的优劣，进一步证明了供电子取代基（如烷基、烷氧基和氨基等）能够提高聚苯胺涂层的防腐性能，复合改性或与树脂共混也能够提高聚苯胺及其衍生物涂层的防腐性能；同时展望了聚苯胺及其衍生物涂料未来发展的新趋势。

Abstract

Conducting polymers represent a promising application prospect in the field of metal corrosion protection as a new polymer material since its reversible redox properties. Among the conducting polymers, polyaniline has become the focus in the anticorrosion coating field and has been widely applied in many fields like metal materials, chemistry industry, navigation and spaceflight because of its unique resistance to pitting corrosion and scratch and its inhibition to adhesion of marine organisms. In this paper, through the analysis of the deficient anticorrosion properties of the single polyaniline coatings, the research progress of modified polyaniline coatings in the field of metal corrosion protection in recent years are summarized, including a single ring substituted polyaniline coatings and N-substituted polyaniline coatings, modified polyaniline composite coatings and modified polyaniline composite materials/resin blending hybrid coatings. The anticorrosion properties of the modified polyaniline coatings and the unmodified polyaniline coatings are compared by various corrosion test methods, further proving that the electron-donating substituents (e.g., alkyl, alkoxy, amino, etc.) can improve the anticorrosion properties of polyaniline coatings, composite modification or blended with resin can also improve the anticorrosion properties of polyaniline and its derivatives. Meanwhile, the future study and development trend of polyaniline and its derivatives are prospected.

Contents
1 Introduction
2 Anticorrosion properties of substituted polyaniline derivatives
2.1 Ring substituted polyaniline derivatives
2.2 N-substituted polyaniline derivatives
3 Anticorrosion properties of polyaniline and its derivatives' composites
3.1 Polyaniline/inorganic composites
3.2 Polyaniline/polymer composites
3.3 Substituted polyaniline composites
3.4 Polyaniline and its derivatives composites/resin hybrid composites
4 Conclusion and outlook

Graphical abstract

关键词

导电聚合物 / 聚苯胺 / 防腐性能 / 供电子取代基 / 复合改性

Key words

conducting polymers / polyaniline / anticorrosion properties / the electron-donating substituents / composite modification

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胡传波, 厉英, 孔亚州, 丁玉石. 改性聚苯胺及其衍生物涂层的防腐性能[J]. 化学进展, 2016, 28(8): 1238-1250 DOI:10.7536/PC160105

Hu Chuanbo, Li Ying, Kong Yazhou, Ding Yushi. Anticorrosion Properties of Modified Polyanilines and Its Derivatives Coatings[J]. Progress in Chemistry, 2016, 28(8): 1238-1250 DOI:10.7536/PC160105

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