细乳液聚合法制备有机/无机纳米复合材料

高党鸽; 梁志扬; 吕斌; 马建中

doi:10.7536/PC160139

化学进展 ›› 2016, Vol. 28 ›› Issue (7) :1076-1083 DOI: 10.7536/PC160139

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细乳液聚合法制备有机/无机纳米复合材料

高党鸽*, 梁志扬, 吕斌, 马建中

作者信息 +

Organic/Inorganic Nanocomposites Prepared by Miniemulsion Polymerization

Gao Dangge*, Liang Zhiyang, Lyu Bin, Ma Jianzhong

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文章历史 +

摘要

无机纳米粒子的引入可以使聚合物材料获得抗菌、导电和防紫外等诸多特性，但无机纳米粒子在聚合物基质中易团聚、引入量少，难以充分发挥其优点。细乳液聚合法基于其独特的成核方式——液滴成核，能够提高无机纳米粒子在聚合物基中的分散性和引入量，且复合材料的形貌易于控制，是目前制备特殊形貌有机/无机纳米复合材料的一种有效手段。本文介绍了有机/无机复合纳米材料的细乳液制备过程，综述了近年来不同无机纳米粒子与有机基质复合的研究进展，例如：纳米SiO₂、纳米ZnO、金属纳米粒子、纳米氧化石墨烯等。最后就其发展现状提出了几点建议。

Abstract

The introduction of inorganic nanoparticles can make the polymer materials many characteristics, such as antibacterial, conductive, anti-ultraviolet. However, the inorganic nanoparticles are easy to agglomerate and less content of nanoparticles is introduced in polymer, so it is difficult to demonstrate advantage of nano material. Based on its unique droplet nucleation mechanism, miniemulsion polymerization can improve the inorganic nanoparticles’ dispersity and amount of introduction in polymer matrix, and control the morphology of the composites easily. It is an effective method to obtain the special morphology of organic/inorganic nanocomposites. This paper introduces the preparation process of organic/inorganic nanocomposite miniemulsion, and reviews the recent progress of different inorganic nanoparticles with organic matrix composites, such as nano-SiO₂, nano-ZnO, metal nanoparticles, nano-graphene oxide, etc. At last, some suggestions on the present development situation are given.

Contents
1 Introduction
2 Preparation and polymerization of organic/inorganic composite miniemulsion
3 The composite of different inorganic nanoparticles and organic matrix
3.1 The composite of nano-SiO₂ with organic matrix
3.2 The composite of nano-ZnO with organic matrix
3.3 The composite of metal nanoparticles with organic matrix
3.4 The composite of GO with organic matrix
3.5 The composite of other inorganic nanoparticles with organic matrix
4 Conclusion

Graphical abstract

关键词

细乳液 / 聚合 / 无机纳米粒子 / 纳米复合材料

Key words

miniemulsion / polymerization / inorganic nanoparticles / nanocomposites

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高党鸽, 梁志扬, 吕斌, 马建中. 细乳液聚合法制备有机/无机纳米复合材料[J]. 化学进展, 2016, 28(7): 1076-1083 DOI:10.7536/PC160139

Gao Dangge, Liang Zhiyang, Lyu Bin, Ma Jianzhong. Organic/Inorganic Nanocomposites Prepared by Miniemulsion Polymerization[J]. Progress in Chemistry, 2016, 28(7): 1076-1083 DOI:10.7536/PC160139

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